The Hydrogen Evolution Reaction on Ni Electrode Material Modified with Molybdenum(IV) Oxide and Chromium(III) Oxide Powders

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The Ni+MoO2 and Ni+Cr2O3 composite coatings were prepared by the electrodeposition under the galvanostatic conditions (jdep = -200 mA cm-2) from the nickel bath containing powder of MoO2 or Cr2O3. Studies of hydrogen evolution reaction (HER) in 5 M KOH solution at room temperature were conducted using steady-state polarization and electrochemical impedance spectroscopy (EIS) methods. It was ascertained that the HER rate is higher for the Ni+MoO2 composite electrode in comparison with the Ni+Cr2O3 composite electrode due to the presence of Mo in the nickel matrix.

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Solid State Phenomena (Volume 228)

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273-276

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March 2015

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© 2015 Trans Tech Publications Ltd. All Rights Reserved

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[1] A. Lasia: Hydrogen Evolution Reaction, in: Handbook of Fuel Cells – Fundamentals, Technology and Applications, W. Vielstich, H.A. Gasteiger, A. Lamm (Eds. ), Vol. 2: Electrocatalysis, John Wiley & Sons, Ltd., Chichester, 2003, pp.416-440.

Google Scholar

[2] B. Łosiewicz: Current Challenges of Hydrogen Energy, in: Fuelling the Future: Advances in Science and Technologies for Energy Generation, Transmission and Storage, A. Mendez-Vilos (Ed. ), BrownWalker Press, 2012, pp.312-316.

Google Scholar

[3] B. Łosiewicz: Przem. Chem. Vol. 91 (2012), p.1362.

Google Scholar

[4] B. Łosiewicz: Mater. Chem. Phys. Vol. 128 (2011), p.442.

Google Scholar

[5] I. Napłoszek-Bilnik, A. Budniok, B. Łosiewicz, L. Pająk, E. Łągiewka: Thin Solid Films Vol. 474 (2005), p.146.

DOI: 10.1016/j.tsf.2004.08.175

Google Scholar

[6] B. Łosiewicz, A. Budniok, E. Rówiński, E. Łągiewka, A. Lasia: Int. J. Hydrogen Energ. Vol. 29 (2004), p.145.

Google Scholar

[7] B. Łosiewicz, A. Budniok, A. Lasia, E. Łągiewka: Pol. J. Chem. Vol. 78 (2004), p.1457.

Google Scholar

[8] B. Łosiewicz, A. Budniok, E. Rówiński, E. Łągiewka, A. Lasia: J. Appl. Electrochem. Vol. 34 (2004), p.507.

Google Scholar

[9] B. Łosiewicz, A. Stępień, D. Gierlotka, A. Budniok: Thin Solid Films Vol. 349 (1999), p.43.

DOI: 10.1016/s0040-6090(99)00175-3

Google Scholar

[10] M. Popczyk, A. Budniok, A. Lasia: Int. J. Hydrogen Energ. Vol. 30 (2005), p.265.

Google Scholar

[11] J.M. Jakšić, M.V. Vojnović, N.V. Krstajić: Electrochim. Acta Vol. 45 (2000), p.4151.

Google Scholar

[12] R.K. Shervedani, A. Lasia: J. Electrochem. Soc. Vol. 144 (1997), p.2652.

Google Scholar