The Phonon Mediated Anomalies of Thermal Expansion in Transition-Metal Componds and Emergent Nanostructures

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Abstract. The negative expansion observed at low temperatures in specific crystallographic directions of complex structures with anisotropic interactions is explained by microscopic analysis within the tight-binding, quasi-harmonic approximation of lattice dynamics. The results agree with measurements on multilayer sandwiches of transition-metal dichalcogenides, high-temperature superconductors and relevant nanostructures including the carbon-based nanotubes.

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Solid State Phenomena (Volume 257)

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81-85

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October 2016

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© 2017 Trans Tech Publications Ltd. All Rights Reserved

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