Moisture Absorption Behavior and Morphology of Thermoplastic Starch via Ascorbic Acid Hydrolysis Technique

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Abstract:

The effect of modified thermoplastic starch (TPS) with organic acid was studied. In presence of ascorbic acid (AATPS) and glycerol (GTPS) along with mechanical process, a native starch granule was transform into a continuous phase as shown by scanning electron microscopy (SEM). Reaction of ascorbic acid (AA) with starch induced to the formation of the ester bond, which improved moisture resistivity of TPS was proven by the determination degree of substitution (DS) and moisture absorption test. The formation of ester bond was identified by using FTIR analysis. The DS values were ranging from 0 to 0.052, respectively, with the increase of AA content.

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Solid State Phenomena (Volume 264)

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148-151

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September 2017

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© 2017 Trans Tech Publications Ltd. All Rights Reserved

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[1] J.B. Olivato, A.P. Bilck, F. Yamashita. Effect of organic acids as additives on the performance of thermoplastic starch/polyester blown films. Carbohydrate Polymers, 90, (2012), 159– 164.

DOI: 10.1016/j.carbpol.2012.05.009

Google Scholar

[2] Xiaofei Ma, J. Y. The plastcizers containing amide groups for thermoplastic starch. Carbohydrate Polymers, 57, (2004), 197–203.

DOI: 10.1016/j.carbpol.2004.04.012

Google Scholar

[3] Yachuan Zhang, Thermoplastic Starch Processing and Characteristic-A Review. Food Science and Nutrition 54, (2014), 1353-1370.

Google Scholar

[4] Jiugao, Y., Wang N., Ma X. The Effect of Citric Acid on the Properties of Thermoplastic Starch Plasticized by Glycerol. Starch/Starke, 57, (2005), 494-504.

DOI: 10.1002/star.200500423

Google Scholar

[5] Zuraida, A., Yusliza, Y., Anuar, H., Mohd Khairul Muhaimin, R. The effect of water and citric acid on sago starch bio-plastics. International Food Research Journal, 19(2), (2012), 715-719.

Google Scholar

[6] Zhu, F. Composition, structure, physicochemical properties, and modifications of cassava starch. Carbohydrate Polymers, 122, (2015), 456–480.

DOI: 10.1016/j.carbpol.2014.10.063

Google Scholar

[7] Sudarat. J, Vanee. C, Onanong. N, Ngamtip. P, Modification of cassava starch by esterification and properties of cassava starch ester film. Kasetsart Journal, 40, (2006), 148-157.

Google Scholar

[8] Colussi. R, El Halal. S. L. M, Pinto. V. Z, Bartz. J, Gutkoski. L. C, Zavareza. E. Da Rosa, Dias. A. R. G, Acetylation of rice starch in an aqueous medium for use in food. Food Science and Technology Journal, 62, (2015), 1076-1082.

DOI: 10.1016/j.lwt.2015.01.053

Google Scholar

[9] Paula G.S., Carolina M. J., Fucia F., Silvia G. Biodegradable and non-retrogradable eco-films based on starch-glycerol with citric acid as crosslinking agent. Carbohydrate Polymers, 138, (2016), 66-74.

DOI: 10.1016/j.carbpol.2015.11.041

Google Scholar

[10] J. I. Mora´n, V. P. C., A. Va´zquez. Preparation and Characterization of Three Different Derivatized Potato Starches. Journal of Polymers and the Environment, 21, (2013), 395–404.

Google Scholar

[11] Muhammad B. K. Niazi, M. Z., Antonius A. Broekhuis. Influence of plasticizer with different functional groups on thermoplastic starch. Journal of Applied Polymer Science, (2015), 1 - 12.

DOI: 10.1002/app.42012

Google Scholar

[12] N. Wang, N. Han, S. Bai. Effect of citric acid and processing on the performance of thermoplastic starch/montmorillonite nanocomposites. Carbohydrate Polymers, 76, (2009), 68-73.

DOI: 10.1016/j.carbpol.2008.09.021

Google Scholar

[13] A.W.M. Kahar, I. Hanafi, O. Nadras. Characterization of Citric Acid-Modified Tapioca Starch and its Influence on Thermal Behavior and Water Absorption of High Density Polyethylene /Natural Rubber/Thermoplastic Tapioca Starch Blends. Journal of Polymer-Plastics Tech. & Eng. 50, (2011).

DOI: 10.1080/03602559.2011.551966

Google Scholar