Luminescence Emission in Borotellurite Glass Containing Manganese Nanoparticles Doped Eu3+ Ions

Siti Maisarah Aziz; M.R. Sahar

doi:10.4028/www.scientific.net/SSP.268.106

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Luminescence Emission in Borotellurite Glass Containing Manganese Nanoparticles Doped Eu³⁺ Ions

Abstract:

A series of europium doped magnesium borotellurite glasses embedded with manganese nanoparticles (Mn₃O₄NPs) of composition (59-x)TeO₂-30B₂O₃-10MgO-x1Eu₂O₃-1Mn₃O₄with 0.5 ≤ x ≤ 1.5 mol % are prepared using melt quenching technique. The existence of broad hump in X-ray diffraction (XRD) pattern verifies the amorphous nature of glasses. The presence of Mn₃O₄ NPs with average diameter of ~11 nm and (1 0 3) lattice plane having 0.276 nm spacing in the glass matrix is confirmed by high resolution transmission electron microscope (HRTEM) image. The glass samples are excited under 390 nm excitation wavelength and the emission spectra are found to consist of four emission peaks centred at 587 nm, 610 nm, 651 nm and 700 nm assigned to the transition from ⁵D₀ →⁷F_J (J = 1, 2, 3, 4) states. The schematic energy level diagram is proposed. All results will be discussed with respect to the composition of Eu³⁺ ion.

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Periodical:

Solid State Phenomena (Volume 268)

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106-110

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https://doi.org/10.4028/www.scientific.net/SSP.268.106

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October 2017

Authors:

Siti Maisarah Aziz, M.R. Sahar*

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Borotellurite Glass, HRTEM, Luminescence, Nanoparticles

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