Judd-Ofelt Parameters of Erbium Doped Zinc Phosphate Glass Containing Natural Ferrite Oxide Nanoparticles

Puzi Anigrahawti Buchori; M.R. Sahar; Sib Krishna Ghoshal

doi:10.4028/www.scientific.net/SSP.290.41

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HomeSolid State PhenomenaSolid State Phenomena Vol. 290Judd-Ofelt Parameters of Erbium Doped Zinc...

Judd-Ofelt Parameters of Erbium Doped Zinc Phosphate Glass Containing Natural Ferrite Oxide Nanoparticles

Abstract:

Erbium ions (Er³⁺) doped zinc phosphate glass system with varying contents of natural ferrite (Fe₃O₄) nanoparticles were prepared using melt quenching method. The glass is characterized by x-ray diffraction (XRD) and UV-VIS NIR spectrometer. It is observed that the amorphous nature of the glass is confirmed by x-ray diffraction. The absorption spectra of the glass are recorded in the UV-Visible in the range of 400-1600 nm. The UV-VIS NIR spectra reveal ten absorption peaks centered at 376, 406, 420, 486, 522, 546, 652, 798, 976 and 1534 nm, correspond to the transitions from the ground state ⁴I_15/2to higher ⁴I_13/2,⁴I_11/2, ⁴I_9/2, ⁴F_9/2, ⁴S_3/2,²H_11/2, ⁴F_7/2, ⁴F_3/2, ²H_9/2, ⁴G_11/2 levels, respectively. Effects of natural ferrite oxide nanoparticles on the absorption and emission properties of the synthesized glasses were analyzed via Judd-Ofelt (J-O) theory. The J-O intensity-parameters (W₂, W₄, W₆) analysis demonstrate a significant increase of spectroscopic quality factors.Keywords: Fe₃O₄ NPs, Absorption, Judd-Ofelt.

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Solid State Phenomena (Volume 290)

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41-45

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https://doi.org/10.4028/www.scientific.net/SSP.290.41

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April 2019

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Puzi Anigrahawti Buchori, M.R. Sahar*, Sib Krishna Ghoshal

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Absorption, Fe₃O₄ NPs, Judd-Ofelt

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