Improving the Bio-Resistance of Cement Concretes by Means of Fungicidal Poly-Functional Modifiers

Article Preview

Abstract:

The research findings of physical and chemical properties of heavy and light concretes, contaminated with water suspension of mold fungi spores, are presented. It is noted that the concretes’ funginertness (resistance to fungi) is significantly influenced by their age, porosity and the alkalinity of medium. In the course of time the strength of concrete decreases, which is conditioned by the activation of mold fungi growth processes, as a result of de-alkalization of concrete, due to carbonization of cement stone and release of organic acids into the material. To improve the concrete’s resistance in biologically aggressive media, it is suggested to modify concrete with a new poly-functional fungicidal modifier, obtained on the basis of resorcine production waste. It has been demonstrated that the addition of resorcinol-formaldehyde oligomers to concrete mix completely inhibits mold fungi growth and allows obtaining concretes with the increased density and strength, which can be used in conditions of biologically aggressive media. The strength characteristics of the cement stone with the researched modifiers are not reduced at mold fungi spores’ contamination, but, on the contrary, slightly increase, due to the increase of cement paste fluidity, decrease of W/C ratio, reduction of micro-cracks in concrete and compaction of its structure, due to the peptizing action of the modifier.

You might also be interested in these eBooks

Info:

Periodical:

Solid State Phenomena (Volume 299)

Pages:

143-149

Citation:

Online since:

January 2020

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2020 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] А.А. Chikichev, S.А. Belykh, А.I. Kudyakov, Hydrophobic-fungicidal admixture and dry plaster mix on its basis, Bulletin of MSUCE, Vol. 12. 6 (105) 661-668.

DOI: 10.22227/1997-0935.2017.6.661-668

Google Scholar

[2] L.Yu. Ogrel, V.I. Pavlenko, М.М. Kosukhin, I.V. Shapovalov, Bioresistant cement concretes with polyfunctional modifiers, Building materials. 11 (2003) 48-49.

Google Scholar

[3] V.F. Smirnov, А.V. Dergunova, Е.V. Zavalitin, Improving the bioresistance of building materials and products by means of their porous structure impregnation, News of KazSACU. 2 (14) (2010) 218-222.

Google Scholar

[4] M. M. Kosukhin, A. M. Kosukhin, K. S. Komarova, Increasing of the energy efficiency in civilian buildings applying fixed type of facade systems, International Conference on Energy Systems-2007 (ICES 2017), Journal of Physics: Conf. Series. 1066 (2018) 012012.

DOI: 10.1088/1742-6596/1066/1/012012

Google Scholar

[5] K.V. Sazanova, I.L. Kuzikova, N.G. Medvedeva, The influence of fungicides on the production of acids by fungi of Aspergillus and Penicillium genera, Mycology and phytopathology, Vol. 50. 2 (2016) 124-129.

Google Scholar

[6] Е.N. Goncharova, М.М. Kosukhin, О.S. Belolapotkova, S.V. Tkachenko, Research of bioresistance of concretes, in: Ecology – education, science and industry: Collection of research papers of International research and methodological conference, BelSTABM, Belgorod, (2002) 137-141.

Google Scholar

[7] I.V. Shapovalov, L.Yu. Ogrel, М.М. Kosukhin, Fungicidal modifier of mineral building compositions, in: Problems and ways of creating composite materials and technologies on the basis of secondary mineral resources: Collection of research papers of Research and practice seminar, SibSIU, Novokuznetsk, (2003) 242-246.

Google Scholar

[8] M.M. Kosukhin, I.V. Starostina, A.M. Kosukhin, Reclamation of chemical wastes for the production of efficient concrete modifiers, International Journal of Engineering and Technology (UAE). 7(2) (2018) 34-37.

Google Scholar

[9] М.М. Kosukhin, N.А. Shapovalov, А.М. Kosukhin, А.А. Babin, Superplasticizer for concretes based on light pyrolysis resin, Building materials. 7 (2008) 44.

Google Scholar

[10] V.А. Poluektova, М.М. Kosukhin, V.М. Malinovker, N.А. Shapovalov, Polyfunctional super-plasticizer for concretes based on pyrocatechin production waste, Fundamental research. 1 (2013) 718-722.

Google Scholar

[11] N.А. Shapovalov, А.А. Slyusar, М.М. Kosukhin, О.V. Mukhachev, Superplasticizer SB-5 as a modifier for obtaining low water demand binders and concretes on their basis, Concrete and reinforced concrete. 6 (2001) 2-4.

Google Scholar

[12] М.M. Kosukhin, N.A. Shapovalov, A.M. Kosukhin, Colloid-Chemical Bases on Creation of Multifunctional Modifiers of Concrete Mix and Concrete, in: Solid State Phenomena, Vol. 265, Trans Tech Publications, Switzerland, (2017) 331-336.

DOI: 10.4028/www.scientific.net/ssp.265.331

Google Scholar

[13] GOST 9.048 – 91 Methods of laboratory tests for mould resistance.

Google Scholar

[14] А.V. Ferronskaya, V.P. Tokareva, Improving bioresistance of concretes based on gypsum binders, Building materials. 4 (1992) 18-20.

Google Scholar

[15] Е.I. Andreyuk, V.I. Bilay, E.Z. Koval, Microbial corrosion and its causative agents, Naukova Dumka, Kyiv, (1980).

Google Scholar

[16] Recommendations for hydraulic concretes production with biocidal admixtures, CRCRI, Moscow, (1981).

Google Scholar

[17] Yu.V. Denisova, А.V. Popova, М.М, Kosukhin, N.А. Shapovalov, The influence of fungicidal PFM on biodeterioration processes in cement concretes, in: Problems and achievements of building materials science: Book of reports of International research and practice online conference, BSTU named after V.G. Shukhov, Belgorod, (2005) 41-43.

Google Scholar

[18] I.V. Shapovalov, L.Yu. Ogrel, М.М. Kosukhin, Improving fungi-resistance of wood-filler cement composites, in: Ecology – education, science and industry: Collection of research papers of International research and methodological conference, BelSTABM, Belgorod, (2002) 271-273.

Google Scholar

[19] М.М. Kosukhin, N.А. Shapovalov, V.А. Lomachenko, Modified bioresistant concretes for hot and humid climate conditions, Proceedings of Higher Educational Institutions: Construction. 5 (2005) 46-48.

Google Scholar

[20] М.М. Kosukhin, А.М. Kosukhin, The mechanism of action of a polyfunctional modifier made of hydrocarbons production waste in mineral suspensions based on fine-ground cements, in: Solid State Phenomena, Vol. 284, Trans Tech Publications, Switzerland, 2018, pp.885-892.

DOI: 10.4028/www.scientific.net/ssp.284.885

Google Scholar

[21] М.М. Kosukhin, А.М. Kosukhin, N.А. Shapovalov, Composite binder for highly cold-resistant road concretes, Bulletin of BSTU named after V.G. Shukhov. 1 (2010) 51–53.

Google Scholar