Paper Titles

Kurgan Clays in the Production of Ceramic Materials
p.3

Activity of Zinc Oxide Based Spinels Catalytic
p.8

Peculiarities of Heat and Mass Transfer in Porous Moistened Mediums at High Thermal Loads
p.14

Mathematical Modeling of High-Energy Pressing Process of Graphite-Plastic Composition
p.20

Improving Construction Engineering Properties of Soils Stabilized by a Cement Binder with Techno-Genic Products
p.26

Improvement of Strength Parameters of Foam Ceramics for Energy-Efficient Enclosing Structures
p.32

Modeling of the Transition Layer in Ceramic Matrix Composites from Coal Wastes and Clay
p.37

Determination of Rational Technological Parameters of Co-Extrusion Processing of Secondary Polymeric Materials by the Method of Physical Modeling
p.43

HomeSolid State PhenomenaSolid State Phenomena Vol. 299Activity of Zinc Oxide Based Spinels Catalytic

Activity of Zinc Oxide Based Spinels Catalytic

Article Preview

Abstract:

Comparative assessment of phase formation in the system ZnO-CeO₂-Fe₂O₃-Cr₂O₃_, obtained using a number of technological methods, is carried out. Spinel phase formation is established for all materials studied, except ZnO-CeO₂. Synthesized materials are examined with X-ray phase analysis, low-temperature nitrogen adsorption, and scanning electron microscopy. It is shown that the synthesis in the presence of an organic precursor allows obtaining fine spinel samples. High catalytic activity of the synthesized materials, containing the spinel phase, is established in the process of methyl orange oxidative destruction in the presence of hydrogen peroxide. It is proved that with an increase in the number of chromium cations in the sample, the catalytic activity of the materials also increases. Zinc ferrite, despite the considerably more developed surface, and ZnO /CeO₂ are not very effective in this process. The data obtained is useful for the development of materials for wastewater treatment at industrial enterprises, which use organic dyes in their production cycles.

You might also be interested in these eBooks

Technologies of Water and Wastewater Treatment. Section I

Materials Engineering and Technologies for Production and Processing V

Info:

Periodical:

Solid State Phenomena (Volume 299)

Pages:

8-13

DOI:

https://doi.org/10.4028/www.scientific.net/SSP.299.8

Citation:

Cite this paper

Online since:

January 2020

Authors:

N.P. Shabelskaya*, V.V. Semchenko, A.S. Deeva

Keywords:

Chromites of Zinc, Fenton Catalyst, Ferrites of Zinc, Oxidative Degradation, Spinel, Synthesis

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2020 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Yu. Yao, Ji. Qin, H. Chen, F. Wei, X. Liu, Ji. Wang, S. Wang, One-pot approach for synthesis of N-doped TiO2/ZnFe2O4 hybrid as an efficient photocatalyst for degradation of aqueous organic pollutants, J. of Hazardous Mat. 291 (2015) 28-37.

DOI: 10.1016/j.jhazmat.2015.02.042

[2] Jin R. Jin, H. Liu, Ya. Guan, Ju. Zhou, G. Chen, ZnFe2O4/C nano discs as high performance anode material for lithium-ion batteries, Mat. Lett. 158 (2015) 218-221.

DOI: 10.1016/j.matlet.2015.06.030

[3] X. Zhou, Ji. Liu, C. Wang, P. Sun, X. Hu, X. Li, K. Shimanoe, N. Yamazoe, G. Lu, Highly sensitive acetone gas sensor based on porous ZnFe2O4 nanospheres, Sensors and Actuators B. 206 (2015) 577-583.

DOI: 10.1016/j.snb.2014.09.080

[4] T. Ono, D. Oharu, S. Kobayashi, H. Yamada, S. Takita, M. Maeda, K. Takase, Y. Takano, T. Watanabe, Element substitution effects on magnetic properties of spin-frustrated spinel Znb2O4 (B = Cr and Fe), Solid State Phenomena 257 (2017) 111-114.

DOI: 10.4028/www.scientific.net/ssp.257.111

[5] M.R.M. Shafiee, M. Sadeghian, M. Kargar, ZnFe2O4-Fe2O3-CeO2 composite nanopowder: Preparation, magnetic properties, and 4-chlorophenol removal characterizations, Ceramics International 43, Issue 16 (2017) 14068-14073.

DOI: 10.1016/j.ceramint.2017.07.142

[6] Z. Krysieki, T. Lubanska, Effect of the presintering process on the microstructure and initial permeability of Mn–Zn ferrite, J. Magn. and Magn. Mater. 1-3 (1980) 107-108.

[7] M. Ajmal, A. Maqsood, Influence of zinc substitution on structural and electrical properties of Ni1-xZnxFe2O4 ferrites, Mat. Science and Engineering B. 139 (2007) 164–170.

DOI: 10.1016/j.mseb.2007.02.004

[8] S.S. Kumbhar, M.A. Mahadik, S.S. Shinde, K.Y. Rajpure, C.H. Bhosale, Fabrication of ZnFe2O4 films and its application in photoelectrocatalytic degradation of salicylic acid, J. of Photochemistry and Photobiology B: Biology. 142 (2015) 118–123.

DOI: 10.1016/j.jphotobiol.2014.12.002

[9] Z. Xu, S. Gu, S. Huang, K. Tang, Ji. Ye, S. Zhu, M. Xu, Yo Zheng, Structure and properties of Fe3O4 films grown on ZnO template via metal organic chemical vapor deposition. J. of Magnetism and Magnetic Mat. 385 (2015) 257–264.

DOI: 10.1016/j.jmmm.2015.03.018

[10] P. Priyadharsini, A. Pradeep, G. Chandrasekaran, Novel combustion route of synthesis and characterization of nanocrystalline mixed ferrites of Ni–Zn, J. of Magnetism and Magnetic Mat. 321 (2009) 1898-1903.

DOI: 10.1016/j.jmmm.2008.12.005

[11] Ja,Y. Patil, D.Y. Nadargi, Jy.L. Gurav, I.S. Mulla, S.S. Suryavanshi, Glycine combusted ZnFe2O4 gas sensor: Evaluation of structural morphological and gas response properties, Cer. Intern. 40 (2014) 10607-10613.

DOI: 10.1016/j.ceramint.2014.03.041

[12] S.M. Masoudpanah, S.A.S. Ebrahimi, M. Derakhshani, S.M. Mirkazemi, Structure and magnetic properties of La substituted ZnFe2O4 nanoparticles synthesized by sol–gel autocombustion method, J. of Magnetism and Magnetic Mat. 370 (2014) 122-126.

DOI: 10.1016/j.jmmm.2014.06.062

[13] S.A. Hosseini, M.C. Alvarez-Galvan, J.L.G. Fierro, A. Niaei, D. Salari, MCr2O4 (M=Co, Cu and Zn) nanospinels for 2-propanol combustion: Correlation of structural properties with catalytic performance and stability, Cer. Intern. 39 (2013) 9253-9261.

DOI: 10.1016/j.ceramint.2013.05.033

[14] E.R. Kumar, T. Arunkumar, T. Prakash, Heat treatment effects on structural and dielectric properties of Mn substituted CuFe2O4 and ZnFe2O4 nanoparticles, Superlattices and Microstructures. 85 (2015) 530-535.

DOI: 10.1016/j.spmi.2015.06.016

[15] X. Zhu, F. Zhang, M. Wang, Ji. Ding, S. Sun, Ju.Bao, C. Gao, Facile synthesis, structure and visible light photocatalytic activityof recyclable ZnFe2O4/TiO2, Applied Surface Science. 319 (2014) 83-89.

DOI: 10.1016/j.apsusc.2014.07.051

[16] R. Zhang, X. Yang, D. Zhang, H. Qiu, Q. Fu, H. Na, Z. Guo, F. Du, G. Chen, Yi. Wei, Water soluble styrene butadiene rubber and sodium carboxyl methyl cellulose binder for ZnFe2O4 anode electrodes in lithium ion batteries, J. of Power Sources. 285 (2015) 227-234.

DOI: 10.1016/j.jpowsour.2015.03.100

[17] A. Shanmugavani, R. KalaiSelvan, S. Layek, C. Sanjeeviraja, Size dependent electrical and magnetic properties of ZnFe2O4 nanoparticles synth esized by the combustion method: Comparison between aspartic acid and glycine as fuel, J. of Magnetism and Magnetic Mat. 354 (2014) 363-371.

DOI: 10.1016/j.jmmm.2013.11.018

[18] M. Zhao, S. Fan, Ji.Liang, Yi. Liun, Yi. Li, Ji. Chen, S. Chen, Synthesis of mesoporous grooved ZnFe2O4 nano belts as peroxidase mimetics for improved enzymatic biosensor, Cer. Intern. 41 (2015) 10400-10405.

DOI: 10.1016/j.ceramint.2015.04.080

[19] F. Mueller, D. Bresser, E. Paillard, M. Winter, S. Passerini, Influence of the carbonaceous conductive network on the electrochemical performance of ZnFe2O4 nanoparticles, J. of Power Sources. 236 (2013) 87-94.

DOI: 10.1016/j.jpowsour.2013.02.051

[20] A. Esmaeili, N.A. Hadad, Preparation of ZnFe2O4–chitosan-doxorubicin hydrochloride nanoparticles and investigation of their hyperthermic heat-generating characteristics, Cer. Intern. 41 (2015) 7529-7535.

DOI: 10.1016/j.ceramint.2015.02.075

[21] N. Kumari, V. Kumar, S.K. Singh, Effect of Cr3+ substitution on properties of nano-ZnFe2O4, J. of Alloys and Compounds. 622 (2015) 628-634.

DOI: 10.1016/j.jallcom.2014.10.083

[22] O.V. Yelenich, S.O. Solopan, T.V. Kolodiazhnyi, V.V. Dzyublyuk, A.I. Tovstolytkin, A.G. Belous, Magnetic properties and high heating efficiency of ZnFe2O4 nanoparticles, Mat. Chem. and Physics. 146 (2014) 129-135.

DOI: 10.1016/j.matchemphys.2014.03.010

[23] L. Liu, A. Han, M. Ye, W. Feng, , The evaluation of thermal performance of cool coatings colored with high near-infrared reflective nano-brown inorganic pigments: Magnesium doped ZnFe2O4 compounds, Solar Energy. 113 (2015) 48-56.

DOI: 10.1016/j.solener.2014.12.034

[24] N.P. Shabel'skaya, V.V. Ivanov, V.M. Talanov, L.A. Reznichenko, M.V Talanov, A.K. Ul'yanov, Synthesis and phase formation in the system NiO-CuO-Fe2O3-Cr2O3, Glass and Ceramics. 71 (2014), Nos. 1-2, 18-22.

DOI: 10.1007/s10717-014-9607-0

[25] V.M. Chernyshev, N.P. Shabelskaya, Comparative analysis of catalytic activity in complex NiO-CuO-Fe2O3-Cr2O3 oxide system of different production technologies, Materials Science Forum. 870 (2016) 118-122.

DOI: 10.4028/www.scientific.net/msf.870.118

[26] N.P. Shabelskaya, Synthesis and Properties of Binary Spinels in a NiO-CuO-Fe2O3-Cr2O3 System, Glass Physics and Chemistry. 43 (2017), Is. 1, 240-245.

DOI: 10.1134/s1087659617030129

[27] N.P. Shabel'skaya, Phase Formation Processes in the NiO – CuO – Fe2O3 – Cr2O3 System upon Salt Decomposition, Inorganic Mat. 50 (2014), No. 11, 1114-1118.

DOI: 10.1134/s002016851411017x