Investigation of the Influence of Technological Regimes of High-Temperature Firing on the Structure and Properties of Silicate-Enamel Coatings for Carbon Steels

Abstract:

The silicate-enamel coating becomes the actual coating as a result of firing, which is a process of heating steel products coated with a “biscuit” dried slip layer, until completely melted, and a continuous coating is obtained on a metal substrate. With the constantly increasing requirements for the technical and operational properties of enameled products in the production of steel pipelines, it is advisable to use single-layer enameling, which saves raw materials and energy, due to the reduction in the number of layers and firing cycles of products. Its use for large-sized products, such as pipelines, eliminates their warping that occurs during repeated firing. In addition, the use of single-layer coatings makes it possible to obtain a better surface of products, since with a decrease in the resulting coating thickness it becomes more elastic and impact-resistant. All of the above is predetermined both by the structure of the glass coating itself and the generally formed steel - enamel composition. Therefore, knowledge of the structure, as well as of the physicochemical processes that occur during the firing of the enameled product, is necessary to solve technological issues successfully.

• Periodical: Solid State Phenomena (Volume 316)
• Pages: 752-757
• DOI: https://doi.org/10.4028/www.scientific.net/SSP.316.752
• Online since: April 2021
• Authors: A.V. Ryabova*, Lyudmila V. Klimova, D.A. Golovko
• Keywords: Carbon Steels, High Temperature Firing, Silicate-Enamel Coatings, Steel Protection, Structure and Properties of Coatings

References

[1] Smirnov L.A. Enamel and steel // Metals of Eurasia. 2002. Vol. 5. pp.38-39.

[2] Koch G. H., Brongers M. P. H. et al. Corrosion - a natural but controllable process // In "Corrosion Costs and Preventive Strategies in the United States. Publication No. FHWA-RD-01-156. 2010. pp.3-4.

[3] Revie R.W., Uhlig H. H. Corrosion and Corrosion Control: An Introduction to Corrosion Science and Engineering, Fourth Edition John Wiley & Sons, Inc., Hoboken New Jersey. (2008).

[4] Tang F., Chen G., Brow R. K. et al, Corrosion Resistance and Mechanism of Steel Rebar Coated with Three Types of Enamel // Corrosion Science. 2012. Vol. 59. p.157–168.

DOI: 10.1016/j.corsci.2012.02.024

[5] Berdzenishvili I. G. Synthesis of Low-Melting Pipe Enamel Coatings and Their Chemical Durability // American Journal of Materials Science. 2016. Vol. 6 (2). pp.45-48.

[6] Schweitzer P.A. Corrosion-Resistant Piping Systems. CRC Press, Boca Raton, 1994.193 p.

[7] Rossi S., Parziani N., Zanella C. Abrasion Resistance of Vitreous Enamel Coatings in Function of Frit Composition and Particles Presence // Wear. 2015. Vol. 332. p.702–709.

DOI: 10.1016/j.wear.2015.01.058

[8] Lazutkina O. R., Kostenko M. G., Komarova S. A., Kazak A. K. Highly Reliable Energy-Efficient Glass Coatings for Pipes Transporting Energy Carriers, Liquids, and Gases // Glass and Ceramics. 2007. Vol. 64. Iss. 3-4. p.93–95.

DOI: 10.1007/s10717-007-0024-5

[9] Kozlova A. P., Guba N. I., Drobot I. A. Comparative Testing of One-Coat Enamels for Pipes // Glass and Ceramics. 2001. Vol. 5. Iss.1-2. p.72–74.

[10] Ryabova A. V., Yatsenko E. A., Klimova L. V., Goltsman B. M., Fanda A. Yu. Protection of steel pipelines with glass-enamel coatings based on silica-containing raw materials of the far east of Russia // International Journal of Mechanical Engineering and Technology (IJMET). 2018. Vol. 9. Iss. 10. p.769–774.

DOI: 10.4028/www.scientific.net/msf.945.46

[11] Yatsenko E. A., Ryabova A. V., Klimova L. V. et al. The study of chemical processes that ensure the adhesion of glass enamel coatings to steel pipelines // Butlerov Communications. 2018. No. 11, Vol. 56. pp.122-127.

[12] Technology of enamel and protective coatings: Textbook / Ed. L.L. Bragina, A.P. Zubekhin - Kharkov: NTU KhPI,; Novocherkassk: SRSTU (NPI). 2003.448 p.

[13] Liu H. H., Shueh Y., Yang F. S., Shen P. Microstructure of the Enamel-Steel Interface: Cross-Sectional TEM and Metallographic Studies // Materials Science Engineering A. 1992. 149(2). p.217–224.

DOI: 10.1016/0921-5093(92)90382-b

[14] Yang X., Jha A., Brydson R., Cochrane R. C. An Analysis of the Microstructure and Interfacial Chemistry of Steel-Enamel Interface, Thin Solid Films, 2003, 443(1), p.33–45.

DOI: 10.1016/s0040-6090(03)00973-8

[15] Yatsenko E. A., Goltsman B. M., Ryabova A. V. Complex Protection of Pipelines Using Silicate Materials Based on Local Raw Materials of the Far East // Materials Science Forum. 2019. Vol. 945. pp.46-52.

DOI: 10.4028/www.scientific.net/msf.945.46

[16] Yatsenko E. A., Goltsman B. M., Ryabova A. V., Smoliy V. A. Peculiarities of the use of siliceous raw materials of the Russian Far East in the integrated pipeline protection // MATEC Web of Conferences. 2018. Vol. 242. # 01016.

DOI: 10.1051/matecconf/201824201016

[17] Petzold A., Peshman G. Enamel and enameling // Metallurgy. (1990).

[18] Gazprom: Eastern Gas Program. Access Mode: http://www.gazprom.ru/about/production/projects/east-program/.

[19] Yatsenko E.A. The phase composition and structure of the contact layer of the metal-silicate coating system. Rostov n / a: SKNTs VSh. (2007).

[20] Yatsenko E. A., Ryabova A. V., Klimova L. V., Fanda A. Yu., Kerimova V. V., Yatsenko L. A., Chumakov A. A. Investigation of chemical processes that provide adhesion strength glass enamel coating with steel pipelines. Butlerov messages. 2018.V. 56. No. 11.

DOI: 10.1134/s1087659619010085