Factors Influencing Mullite Formation in Refractory Grog

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Abstract:

The mineral mullite has many outstanding refractory properties. The content of aluminum oxide in the raw material is the basic factor influencing the content of mullite in the final product. Depending on Al2O3 content, silica-alumina materials can be divided into fireclay and high-alumina with the Al2O3 content of 45 % and more. The study describes the influence of raw material, the influence of homogenization of raw material and influence of firing temperature on the mullite formation in fireclay refractory material. Three kinds of refractory clay with different chemical composition were used as raw material for fireclay grog production. Three kinds of homogenization and three different temperatures were studied as factors influencing mullite formation. Powder X-ray diffraction was used to determine mullite content in material. Quantitative phase analysis was conducted by the Rietveld method. Mullite crystals morphology was observed by scanning electron microscopy.

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Solid State Phenomena (Volume 321)

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149-155

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July 2021

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© 2021 Trans Tech Publications Ltd. All Rights Reserved

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[1] H. Schneider, K. Okada, J.A. Pask Mullite and Mullite Ceramics, Chichester, UK (1994) p.251.

Google Scholar

[2] W.E. Lee, W.M. Rainforth Ceramic Microstructures: Property Control by Processing, Chapman and Hall, London, UK (1994), p.580.

Google Scholar

[3] C.J. McConville, W.E. Lee Microstructural development on firing illite and smectite clays compared with that in kaolinite, J. Am. Ceram. Soc., 88 (8) (2005), pp.2267-2276.

DOI: 10.1111/j.1551-2916.2005.00390.x

Google Scholar

[4] C.J. McConville, G.E. Roch, W.E. Lee, M.E. Smith Structural evolution of clay minerals on firing deduced from solid state NMR, XRD and TEM.

Google Scholar

[5] P. Vincenzini, M. Dondi (Eds.), Proceedings of 10th International Ceramics Congress (CIMTEC 2002), Advances in Science and Technology, Vol. 34 Science for New Technology of Silicate Ceramics, Techna, Florence, Italy (2003), pp.97-108.

Google Scholar

[6] Mullite formation in clays and clay-derived vitreous ceramics, W.E. Lee, G.P. Souza, C.J. McConville, T. Tarvornpanich2, Y. Iqbal, Journal of the European Ceramic Society, Volume 28, Issue 2, 2008, Pages 465-471.

DOI: 10.1016/j.jeurceramsoc.2007.03.009

Google Scholar

[7] EN 993-1:1995 Methods of test for dense shaped refractory products. Part 1: Determination of bulk density, apparent porosity and true porosity.

DOI: 10.3403/30347806

Google Scholar