Synthesis of Fatty Imidazoline from Oleic Acid with Ethylenediamine and its Characterization

Abstract:

In this work, imidazoline-oleic derivative had been successfully synthesized by reacting ethylenediamine (EDA) with oleic acid (OA). The synthesis process was performed with MAOS (Microwave Assisted Organic Synthesis) and the conventional method (reflux with Dean-Stark) using xylene as a solvent was also performed as comparisons. The percentage yield of EDA-OA imidazoline was obtained from Reflux with Dean-Stark at 5 hours (90 %), and MAOS at 10 min (68,2 %). EDA-OA imidazoline then was identified by using thin-layer chromatography, and the separation method by KVC with eluent CHCl₃: MeOH (9:1) with ammonium solution followed by characterization using Fourier Transform Infrared (FTIR), UV-Vis, Proton Nuclear Magnetic Resonance (¹H-NMR). This study provides information regarding the comparison method for imidazoline derivative synthesis. For further research, EDA-OA imidazoline can be used as a corrosion inhibitor towards carbon steel.

• Periodical: Solid State Phenomena (Volume 340)
• Pages: 33-45
• DOI: https://doi.org/10.4028/p-x7bzhy
• Online since: December 2022
• Authors: Nila Tanyela Berghuis*, Zulfikar Fauzan Ali
• Keywords: Corrosion, Ethylenediamine, Fatty Imidazoline, Inhibitors, Oleic Acid

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