The Effect of the Type of Gelling Agent on the Speed of Gelation of Sol-Gels

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This article deals with the selection of a suitable gelling agent for refractory castable with a sol-gel binder system. The goal is to find the optimal ratio between gelation time, content, and concentration of the solution. Various salts (NaCl, NH4Cl, Ca(NO3)2) are investigated as gelling agents. Gelation curves are constructed from gelation time observations. For the design of the formula of refractory castable with a sol-gel bond, it is important to know the behavior of the sol after mixing with the gelling agent. This is the goal of the experiment. In the end, we will obtain initial data for further proposals for the composition of refractory castable with a sol-gel bond.

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Solid State Phenomena (Volume 351)

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47-52

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October 2023

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© 2023 Trans Tech Publications Ltd. All Rights Reserved

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[1] P. Exnar, Metoda sol-gel, Technická univerzita v Liberci, Liberec, 2006.

Google Scholar

[2] J. Pešek, J. Fiala, L. Rybák, B. Korsa, P. Fajfr, J. Hamáček, Žárobetony na bázi SiC s vazbou sol - gel, jejich odolnost vůči korozi struskou z komunálního odpadu.

Google Scholar

[3] J. Pešek, J. Fiala, L. Rybák, B. Korsa, P. Fajfr, J. Hamáček, Bezcementové žárobetony s vazbou sol-gel, jejich výhody a nevýhody.

Google Scholar

[4] S. Ghosh,R. Majumdar, B.K. Sinhamahapatra, R.N. Nandy, M. Mukherjee, S. Mukhopadhyay, Microstructures of refractory castables prepared with sol–gel additives, in: Ceramics International, pp.671-677,2003.

DOI: 10.1016/s0272-8842(02)00216-x

Google Scholar

[5] D.A. Rani, F.D Gnanam, Sol–gel mullite as the self-bonding material for refractory applications, in: Ceramics International, pp.347-350, 2000.

DOI: 10.1016/s0272-8842(99)00062-0

Google Scholar

[6] SK. S. Hossain, P.K. Roy, Waste rice husk ash derived sol: A potential binder in high alumina refractory castables as a replacement of hydraulic binder, in: Journal of Alloys and Compounds, 2020.

DOI: 10.1016/j.jallcom.2019.152806

Google Scholar

[7] A.Kr. Singh, Study on the effect of different sols on high alumina castable refractory, 2017.

Google Scholar

[8] S. Mukhopadhyay, S. Mahapatra, P. Mukherjee, T. Dasgupta, S. K. Das, Effect of Alumina Sol in No-Cement Refractory Castables, in: Transactions of the Indian Ceramic Society, pp.63-67, 2001.

DOI: 10.1080/0371750x.2001.10799968

Google Scholar

[9] M. Nouri-Khezrabad, M.A.L. Braulio, V.C. Pandolfelli, F. Golestani-Fard, H.R. Rezaie, Nano-bonded refractory castables, in: Ceramics International, pp.3479-3497, 2013.

DOI: 10.1016/j.ceramint.2012.11.028

Google Scholar

[10] R. Sarkar, Binders for Refractory Castables: An Overview, in: Interceram - International Ceramic Review, pp.44-53, 2020.

DOI: 10.1007/s42411-020-0112-x

Google Scholar

[11] Y. Pivinskii, Cement-Free Refractory Concretes, Part 4: Refractory Concretes based on Silica Sol Binders, in: Refractories and Industrial Ceramics, pp.150-158, 2020.

DOI: 10.1007/s11148-020-00447-7

Google Scholar

[12] S.H. Badiee, S. Otroj, Non-cement refractory castables containing nano-silica: Performance, microstructure, properties, in Ceramics, pp.297-302, 2009.

Google Scholar

[13] Ibrahim M.I. Bayoumi, Emad M.M. Ewais, Ahmed A.M. El-Amir, Rheology of refractory concrete: An article review, in: Boletín de la Sociedad Española de Cerámica y Vidrio, 2021.

DOI: 10.1016/j.bsecv.2021.03.003

Google Scholar

[14] S. Mukhopadhyay, S. Ghosh, M.K. Mahapatra, R. Mazumder, P. Barick, S. Gupta, S. Chakraborty, Easy-to-use mullite and spinel sols as bonding agents in a high-alumina based ultra low cement castable, in. Ceramics International, pp.719-729, 2002.

DOI: 10.1016/s0272-8842(02)00034-2

Google Scholar