Microstructure and Tribological Behavior of Plasma Sprayed (Ti,Cr)C-Ni Composite Coatings

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Thermally sprayed cermet coatings are widely used in many engineering applications to protect against wear and corrosion. In this study, three kinds of (Ti,Cr)C-based powders with 18, 25, 33 wt.% content of Ni binder were deposited onto stainless steel substrates by plasma spraying technique. The microstructure and dry sliding wear resistance of the (Ti,Cr)C-Ni coatings were investigated. The (Ti,Cr)C-Ni coatings have a heterogeneous structure composed of (Ti,Cr)C particles and Ni binder. Fracture and partial dissolution of the (Ti,Cr)C particles were found to occur during the plasma spray process. Among all the tested coatings, (Ti,Cr)C-33wt.%Ni coating exhibits lower wear rates and friction coefficients under all conditions. Worn surfaces of the coatings were analyzed using SEM to investigate the wear mechanism. With the increase in Ni content from 18 up to 33wt.%Ni wear mechanism of the (Ti,Cr)C-Ni coatings changes from abrasive to tribo-oxidation.

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Solid State Phenomena (Volume 355)

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77-84

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February 2024

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© 2024 Trans Tech Publications Ltd. All Rights Reserved

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[1] L. Pawlowski, The science and engineering of thermal spray coatings, Wiley, Chichester 1995.

Google Scholar

[2] B.G. Mellor, Surface coatings for protection against wear, Woodhead Publishing Limited, Cambridge, 2006.

Google Scholar

[3] L.M. Berger, Application of hardmetals as thermal spray coatings, International Journal of Refractory Metals and Hard Materials 49 (2015) 350–364.

DOI: 10.1016/j.ijrmhm.2014.09.029

Google Scholar

[4] H.M. Ortner, P. Ettmayer, H. Kolaska, The history of the technological progress of hardmetals, International Journal of Refractory Metals and Hard Materials 44 (2014) 148–159.

DOI: 10.1016/j.ijrmhm.2013.07.014

Google Scholar

[5] G. Bolelli, L.M. Berger, M. Bonetti, L. Lusvarghi, Comparative study of the dry sliding wear behaviour of HVOF-sprayed WC–(W,Cr)2C–Ni and WC–CoCr hardmetal coatings, Wear 309 (2014) 96–111.

DOI: 10.1016/j.wear.2013.11.001

Google Scholar

[6] A.H. Tkaczyk, A. Bartl, A. Amato, V. Lapkovskis, M. Petranikova, Sustainability evaluation of essential critical raw materials: cobalt, niobium, tungsten and rare earth elements, J. Phys. D. Appl. Phys. 51 (2018) 203001.

DOI: 10.1088/1361-6463/aaba99

Google Scholar

[7] M. Suh, C.M. Thompson, G.P. Brorby, L. Mittal, D.M. Proctor, Inhalation cancer risk assessment of cobalt metal, Regul. Toxicol. Pharmacol. 79 (2016) 74–82.

DOI: 10.1016/j.yrtph.2016.05.009

Google Scholar

[8] G. Bolelli, A. Colella, L. Lusvarghi, S. Morelli, P. Puddu, E. Righetti, P. Sassatelli, V. Testa, TiC–NiCr thermal spray coatings as an alternative to WC-CoCr and Cr3C2–NiCr, Wear 450–451 (2020) 203273.

DOI: 10.1016/j.wear.2020.203273

Google Scholar

[9] R. A. Govande, A. Chandak, B. R. Sunil, R. Dumpala, Carbide-based thermal spray coatings: A review on performance characteristics and post-treatment, International Journal of Refractory Metals and Hard Materials 103 (2022) 105772.

DOI: 10.1016/j.ijrmhm.2021.105772

Google Scholar

[10] V. Testa, S. Morelli, G. Bolelli, F. Bosi, P. Puddu, A. Colella, T. Manfredini, L. Lusvarghi, Corrosion and wear performances of alternative TiC-based thermal spray coatings, Surface and Coatings Technology 438 (2022) 128400.

DOI: 10.1016/j.surfcoat.2022.128400

Google Scholar

[11] G.N. Komratov, Kinetics of oxidation SHS of titanium carbide and titanium and chromium double carbide powders in air. Powder Metall. Met. Ceram. 32 (1993) 509–511.

DOI: 10.1007/bf00560730

Google Scholar

[12] A.P. Umanskii, V.P. Konoval, A.D. Panasyuk, et al. Plasma coatings of (TiCrC)-(FeCr) composite powder alloys: Structure and properties, Powder Metall Met Ceram. 46 (2007)133–138.

DOI: 10.1007/s11106-007-0022-8

Google Scholar

[13] O. Umanskyi, M. Storozhenko, M., Baglyuk, G. et al. Structure and Wear Resistance of Plasma-Sprayed NiCrBSiC–TiCrC Composite Powder Coatings, Powder Metall. Met. Ceram. 59 (2020) 434–444.

DOI: 10.1007/s11106-020-00177-y

Google Scholar

[14] I.N. Gorbatov, N. S. Il'chenko, A. S. Terent'ev, et al. Effect of cladding double titanium-chrome carbide on the properties of plasma-sprayed coatings, Fiz. Khim. Obrab. Mater. (in Russian) 3 (1991) 69–73.

Google Scholar

[15] V.B. Raitses, Litvin, V.M., Rutberg, V.P. et al. Wear-resistant plasma coatings based on a double carbide of titanium and chromium. Powder Metall. Met. Ceram. 25 (1986) 827–828.

DOI: 10.1007/bf00801430

Google Scholar

[16] O. Umanskyi, M. Storozhenko, T. Chevychelova, V. Varchenko, V. Brazhevsky, O. Chernyshov, O. Terentiev, I. Martsenyuk, K. Haltsov, O. Bondarenko, Structure and wear-behavior of (Ti,Cr)C-Ni thermal-sprayed coatings, Solid State Phenomena 331 (2022) 151–156.

DOI: 10.4028/p-t1o0v1

Google Scholar

[17] Y.S. Borisov, A.L. Borisova; M.V. Kolomytsev, O.P. Masyuchok, I.I. Timofeeva; M.A. Vasilkovskaya, High-velocity air plasma spraying of (Ti, Cr)C–32 wt.% Ni clad powder. Powder Metall. Met. Ceram. 56 (2017) 305–315.

DOI: 10.1007/s11106-017-9898-0

Google Scholar

[18] Wei Su, Yexi Sun, Jue Liu, Jiao Feng, Jianming Ruan, Effects of Ni on the microstructures and properties of WC–6Co cemented carbides fabricated by WC–6(Co, Ni) composite powders, Ceramics International, 41 (2015) 3169–3177.

DOI: 10.1016/j.ceramint.2014.10.165

Google Scholar

[19] O.P. Umanskyi, O.Ye. Terentiev, M.S. Storozhenko, G.A. Baglyuk, V.B. Muratov, O. O. Vasiliev, V.Ye. Sheludko, Wetting and interfacial interaction in TiCrC−Ni system, Functional materials 3 (2021) 1–6.

Google Scholar

[20] M.S. Storozhenko, O.P. Umanskyi, G.A. Baglyuk, V.P. Brazhevskyi, O.O. Chernyshov, O.A. Bondarenko, I.S. Martsenyuk, Clad TiCrC(Ni) Composite powders for thermal spraying of coatings, Powder Metall. Met. Ceram. 60 (2021). P. 1–6.

DOI: 10.1007/s11106-021-00209-1

Google Scholar

[21] O.Р. Umanskyi, O.Ye. Terentiev, M.S. Storozhenko, O. Yu. Koval, Yu.V. Gubin, V.P. Brazhevskyi, O.O. Chernyshov, Effect of plasma spraying parameters on the properties of (Ti, Cr)C–Ni composite coatings, Powder Metall. Met. Ceram. 68 (2023). P. 1–6.

DOI: 10.1007/s11106-023-00348-7

Google Scholar