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Online since: October 2008
Authors: Marcos Zayat, David Levy
A
strong argument for using the Sol-Gel chemistry is found in the high flexibility of the method and
the large choice of commercially available "dopants" that can be incorporated in the solid matrices,
that might have a specific activity or reactivity to an external signal (i.e. light, magnetic, electrical,
etc).
The rapidly developing sol-gel process has been used for the preparation of materials for a wide range of fields, adapting the chemistry and the novel synthetic routes to the specific systems, in order to achieve complicated developments oriented to nanotechnology applications.
Introduction In the last 20 years, the Sol-Gel chemistry has gained a large number of researchers, which developed interesting and sophisticated novel synthetic methods, offering a variety of approaches to new systems preparation, overcoming many of the synthesis difficulties of the past.
The rapidly developing sol-gel process has been used for the preparation of materials for a wide range of fields, adapting the chemistry and the novel synthetic routes to the specific systems, in order to achieve complicated developments oriented to nanotechnology applications.
Figure 4: Schematic representation of a pore structure in silica and ormosil matrices The ormosil used for preparation of the GDLC samples, especially the nature of the nonhydrolysable organic functional group on the alkoxide precursor, plays also an important role in the formation of the LC droplets.
The rapidly developing sol-gel process has been used for the preparation of materials for a wide range of fields, adapting the chemistry and the novel synthetic routes to the specific systems, in order to achieve complicated developments oriented to nanotechnology applications.
Introduction In the last 20 years, the Sol-Gel chemistry has gained a large number of researchers, which developed interesting and sophisticated novel synthetic methods, offering a variety of approaches to new systems preparation, overcoming many of the synthesis difficulties of the past.
The rapidly developing sol-gel process has been used for the preparation of materials for a wide range of fields, adapting the chemistry and the novel synthetic routes to the specific systems, in order to achieve complicated developments oriented to nanotechnology applications.
Figure 4: Schematic representation of a pore structure in silica and ormosil matrices The ormosil used for preparation of the GDLC samples, especially the nature of the nonhydrolysable organic functional group on the alkoxide precursor, plays also an important role in the formation of the LC droplets.
Online since: April 2023
Authors: Jasim Ibrahim Humadi, Ghassan Hassan Abdul Razzaq, Khaleel I. Hamad
Ullmann's encyclopedia of industrial chemistry, 2000
Chemistry–A European Journal, 2007. 13(15): p. 4334-4341
Arabian journal of chemistry, 2010. 3(3): p. 135-140
Inorganic and Nano-Metal Chemistry, 2022. 52(1): p. 1-19
Biointerface research in applied chemistry, 2018. 8(4): p. 3449-3456
Chemistry–A European Journal, 2007. 13(15): p. 4334-4341
Arabian journal of chemistry, 2010. 3(3): p. 135-140
Inorganic and Nano-Metal Chemistry, 2022. 52(1): p. 1-19
Biointerface research in applied chemistry, 2018. 8(4): p. 3449-3456
Online since: August 2008
Authors: Y. Srisuwan, W. Simchuer, N. Kotsaeng, N. Narkkong, Yodthong Baimark
However, the surface chemistry of these polyesters does not fully promote
cell adhesion and proliferation due to its hydrophobic nature [3].
The spectrum of SF in Fig. 1(a) shows carbonyl of amide (amide I) absorption band at 1637 cm-1 indicated to β-sheet structure of the SF due to acetone treatment.
It is indicated that SF with β-sheet and random coil structures coexist in the nanocomposite microparticles.
The FTIR results suggested that interactions between PDLL and SF were occurred due to the conformational transition of SF from β-sheet structure to random coil structure can be induced by nanocompositing with PDLL microparticle matrix.
Acknowledgment This work was supported by the Research Development and Support Unit, Mahasarakham University, fiscal year 2008 and the Center for Innovation in Chemistry: Postgraduate Education and Research Program in Chemistry (PERCH-CIC), Commission on Higher Education, Ministry of Education, Thailand.
The spectrum of SF in Fig. 1(a) shows carbonyl of amide (amide I) absorption band at 1637 cm-1 indicated to β-sheet structure of the SF due to acetone treatment.
It is indicated that SF with β-sheet and random coil structures coexist in the nanocomposite microparticles.
The FTIR results suggested that interactions between PDLL and SF were occurred due to the conformational transition of SF from β-sheet structure to random coil structure can be induced by nanocompositing with PDLL microparticle matrix.
Acknowledgment This work was supported by the Research Development and Support Unit, Mahasarakham University, fiscal year 2008 and the Center for Innovation in Chemistry: Postgraduate Education and Research Program in Chemistry (PERCH-CIC), Commission on Higher Education, Ministry of Education, Thailand.
Online since: May 2013
Authors: He Yang, Xue Fei Lei, Xiang Xin Xue
For the photocatalytic reduction of Cr(VI), the photocatalytic activities of STBBFS catalysts were found to be strongly dependent of absorbance in UV-visible region, adsorption capacity and surface acidity, and STBBFS prepared by dry-process showed a higher photocatalytic activity compared to that prepared by hydro-chemistry method.
The crystal structure identification of STBBFSx catalysts were obtained by using Philips X’pert X-ray diffractormeter with Cu Kα radiation.
The different light absorption capacity might be attributed to the difference in the preparation method, composition, surface microstructure and phase structure in STBBFSx [11]. 2.3 Microstructure Figure 3 (a-c) show the SEM images of STBBFSx catalysts prepared at different method.
It was generally thought that the photocatalytic performance depended on the phase structure, the absorbance, and the adsorption capacity of photocatalyst[12, 13].
In our experiments, the phase structure of all photocatalysts was almost the same, so the different phtocatalytic activity should depend on the latter two factors.
The crystal structure identification of STBBFSx catalysts were obtained by using Philips X’pert X-ray diffractormeter with Cu Kα radiation.
The different light absorption capacity might be attributed to the difference in the preparation method, composition, surface microstructure and phase structure in STBBFSx [11]. 2.3 Microstructure Figure 3 (a-c) show the SEM images of STBBFSx catalysts prepared at different method.
It was generally thought that the photocatalytic performance depended on the phase structure, the absorbance, and the adsorption capacity of photocatalyst[12, 13].
In our experiments, the phase structure of all photocatalysts was almost the same, so the different phtocatalytic activity should depend on the latter two factors.
Online since: January 2013
Authors: Liu Ting Yan, Wen Gui Duan, Rong Huan Qin, Yan Yang
Synthesis and Crystal Structure
of the Lead(II) Complex with 5-Hydroxyisophthalic Acid
Yan YANG1,2,a*, Liu-Ting YAN2,b, Rong-Huan QIN1,c,
Wen-Gui DUAN2,d
1 School of Chemistry and Material, Yulin Normal University, Yulin 537000, People's Republic of China
2 School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, People's Republic of China
ayy135175@163.com, bYLT.7801084@163.com, chuan-2000@126.com, dwgduan@gxu.edu.cn.
Keywords: Lead(II) Complex, 5-Hydroxyisophthalic Acid, Crystal Structure Abstract.
Simplified topology structure of 1.
Fig. 1 - 4 illustrate the structure of 1.
SHELXL-97, Program for Crystal Structure Refinement, University of Göttingen, Göttingen (Germany 1997)
Keywords: Lead(II) Complex, 5-Hydroxyisophthalic Acid, Crystal Structure Abstract.
Simplified topology structure of 1.
Fig. 1 - 4 illustrate the structure of 1.
SHELXL-97, Program for Crystal Structure Refinement, University of Göttingen, Göttingen (Germany 1997)
Online since: November 2011
Authors: Zhi Hong Zhang, Feng Xue
Introduction
The heteropoly compounds ( including heteropoly acid and heteropoly salt), especially with Keggin structure, have been used in organic synthesis[1], pharmaceutical chemistry[2] and other fields for their unique structure and the excellent catalytic performance, and were used to treat wastewater as the photocatalyst by many experts.
The character peak of the heteropoly salts with Keggin structure appears fingerprint region at the range of the 700-1100cm-1[4].
Combined with FT-IR and UV spectra, it was sure that Na5[Fe(ZrMo11)O39]•19H2O possessed Keggin structure.
The results showed it possessed Keggin structure, regular crystal and had a good thermostability.
Transition Matal Chemistry.29,900-903(2004)(In Chinese )
The character peak of the heteropoly salts with Keggin structure appears fingerprint region at the range of the 700-1100cm-1[4].
Combined with FT-IR and UV spectra, it was sure that Na5[Fe(ZrMo11)O39]•19H2O possessed Keggin structure.
The results showed it possessed Keggin structure, regular crystal and had a good thermostability.
Transition Matal Chemistry.29,900-903(2004)(In Chinese )
Online since: July 2014
Authors: Joon Woo Park, Sung In Hong, Ki Yong Ann, Hee Jun Yang, Thamara Tofeti Lima
Taylor.in“Cement chemistry”Academic Press London, (1990), in press
Hewlett, Lea’s Chemistry of Cement and Concrete, chapter 10, Butterworth Heinemann (2008) [11] W.K.W.
Jennings, Pore solution chemistry of alkali-activated ground granulated blast furnace slag,CemConcr Res Vol. 29 (1999), p. 159-170 [19] K.Kalliopi, and Aligizaki.in: “Pore Structure of cement-based materials testing, interpretation and requirements”, Modern Concrete Technology 12, chapter, 3CRC Press (2006) [20] F.
Short, Pore solution chemistry of the hydrated sustemtricalcium silicate, sodium chloride and water, CemConcre Res Vol. 15(4), (1985), p. 675-680 [23] H.
Illston, Capillary pore structure and permeability of hardened cement paste, in Proceedings of the Seventh International Congress on the Chemistry of Cement, Paris Vol. 3, (1980),p.181-186
Hewlett, Lea’s Chemistry of Cement and Concrete, chapter 10, Butterworth Heinemann (2008) [11] W.K.W.
Jennings, Pore solution chemistry of alkali-activated ground granulated blast furnace slag,CemConcr Res Vol. 29 (1999), p. 159-170 [19] K.Kalliopi, and Aligizaki.in: “Pore Structure of cement-based materials testing, interpretation and requirements”, Modern Concrete Technology 12, chapter, 3CRC Press (2006) [20] F.
Short, Pore solution chemistry of the hydrated sustemtricalcium silicate, sodium chloride and water, CemConcre Res Vol. 15(4), (1985), p. 675-680 [23] H.
Illston, Capillary pore structure and permeability of hardened cement paste, in Proceedings of the Seventh International Congress on the Chemistry of Cement, Paris Vol. 3, (1980),p.181-186
Online since: August 2012
Authors: Li Ye Zhang, Li Juan Dong, Xue Dong Guo
In this article, using the Monte-Carlo method to analyze the bridge structure reliability.
Were considered bridge structure component with geometrical parameters uncertainty, material properties uncertainty, bridge structure constant load probability model, vehicle load probability model.Study the influence of the structure reliability.
Respectively choose the deflection and stress as the bridge structure safety control index, set up 2 each function, that is, consider the structure of the two failure mode.
Jónsson, in: Theoretical Methods in Condencsed Phase Chemistry, edited by S.D.
Schwartz, volume 5 of Progress in Theoretical Chemistry and Physics, chapter, 10, Kluwer Academic Publishers (2000)
Were considered bridge structure component with geometrical parameters uncertainty, material properties uncertainty, bridge structure constant load probability model, vehicle load probability model.Study the influence of the structure reliability.
Respectively choose the deflection and stress as the bridge structure safety control index, set up 2 each function, that is, consider the structure of the two failure mode.
Jónsson, in: Theoretical Methods in Condencsed Phase Chemistry, edited by S.D.
Schwartz, volume 5 of Progress in Theoretical Chemistry and Physics, chapter, 10, Kluwer Academic Publishers (2000)
Online since: March 2011
Authors: Olof Kordina, Anne Henry, Erik Janzén, Sven Andersson, Henrik Pedersen, Franziska Christine Beyer, Stefano Leone, Yuan Chih Lin
Methyltrichlorosilane, added with silane, ethylene and hydrogen chloride were employed as precursors to perform epitaxial growths resulting in very low background doping concentration and high quality material, which could be employed for power devices structure on basal-plane-dislocation-free epitaxial layers.
Si-rich conditions were usually preferred to grow on on-axis substrates, yet thanks to Si-rich preparation of the surface C/Si ratios up to 1 were used without any occurrence of 3C inclusions, for Si/H2 = 0.45 % and a growth rate of 60 µm/h, for the SiH4 + C2H4 + HCl chemistry.
In case of the MTS chemistry ratios of 3 or 5 already ensured a 100 % polytype replica of the epilayer even at a Si/H2 ratio of 0.66 %, while in case of the SiH4 + C2H4 + HCl chemistry better results were gained by lowering the Cl/Si ratio from 5 to 1.
In case of the SiH4 + C2H4 + HCl chemistry a growth rate of 80 μm/h was achieved when C/Si = 0.8 and Cl/Si = 1 , yet 3C-SiC inclusions were still formed on the epilayer (Fig. 3a).
MTS was proved to be more efficient in terms of growth rate and polytype replication, compared to the SiH4 + C2H4 + HCl chemistry, yet the latter although suffering of lower growth rate led to better thickness uniformity along the susceptor.
Si-rich conditions were usually preferred to grow on on-axis substrates, yet thanks to Si-rich preparation of the surface C/Si ratios up to 1 were used without any occurrence of 3C inclusions, for Si/H2 = 0.45 % and a growth rate of 60 µm/h, for the SiH4 + C2H4 + HCl chemistry.
In case of the MTS chemistry ratios of 3 or 5 already ensured a 100 % polytype replica of the epilayer even at a Si/H2 ratio of 0.66 %, while in case of the SiH4 + C2H4 + HCl chemistry better results were gained by lowering the Cl/Si ratio from 5 to 1.
In case of the SiH4 + C2H4 + HCl chemistry a growth rate of 80 μm/h was achieved when C/Si = 0.8 and Cl/Si = 1 , yet 3C-SiC inclusions were still formed on the epilayer (Fig. 3a).
MTS was proved to be more efficient in terms of growth rate and polytype replication, compared to the SiH4 + C2H4 + HCl chemistry, yet the latter although suffering of lower growth rate led to better thickness uniformity along the susceptor.
Online since: December 2013
Authors: Xin Wang, Li Wu Qian, Rui Xia Wang
Zang: Chemistry- A European Journal,Vol 13(2007), p.746
Qiu: Journal of Physical Chemistry C, 2008, 112, 11929
Wang: Journal of Physical Chemistry C, Vol 111(2007), p.14689
Huo: Materials Chemistry and Physics, Vol 121(2010), p.291
Tang: Journal of Physical Chemistry C, Vol 112(2008), p.6620.
Qiu: Journal of Physical Chemistry C, 2008, 112, 11929
Wang: Journal of Physical Chemistry C, Vol 111(2007), p.14689
Huo: Materials Chemistry and Physics, Vol 121(2010), p.291
Tang: Journal of Physical Chemistry C, Vol 112(2008), p.6620.