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Online since: October 2010
Authors: Nina Orlovskaya, Daniel Haynes, Nicholas Miller, Harry Abernathy, David Tucker, Randall Gemmen, Yan Chen
The Sr doped La2Zr2O7 powders in pure pyrochlore structure were produced using this approach.
Hence, with the proper control of its localized structure formation, pyrochlore phases can offer improved performance of fuel cell systems.
Finally, another application of the LZO structure includes using the LZO as a solid electrolyte in the proton conducting membranes of SOFC’s.
An X-pert Pro X-ray Diffraction (XRD) System (Panalytical, Netherlands) was used to characterize the crystal structure of the synthesized powder.
Koshy: Journal of Solid State Chemistry.
Hence, with the proper control of its localized structure formation, pyrochlore phases can offer improved performance of fuel cell systems.
Finally, another application of the LZO structure includes using the LZO as a solid electrolyte in the proton conducting membranes of SOFC’s.
An X-pert Pro X-ray Diffraction (XRD) System (Panalytical, Netherlands) was used to characterize the crystal structure of the synthesized powder.
Koshy: Journal of Solid State Chemistry.
Online since: January 2013
Authors: Yu Quan Wen, Guang Tao Li, Nan Yan, Li Ma
By selecting the same surfactant triblock copolymer Pluronic F127 (EO106-PO70-EO106) as structure-directing agent, films with different pore structure and similar aperture size were synthesized under different conditions.
The results clearly showed that pore structure control of mesoporous film was an effective way to improve sensor performance.
After 60 s, the quenching percent show: 40.52, 57.39, 52.72, 2 D hexagonal films couldn’t catch up with the 3 D pore structure films; After 120 s to 1200 s, the 3 D order cubic structure film shows higher and higher quenching intensity than the other two films.
Sizeable films with 3D order cubic channel structure exhibited a rapid response to explosives.
Feng, et al., Continuous mesoporous silica films with highly ordered large pore structures, Adv.
The results clearly showed that pore structure control of mesoporous film was an effective way to improve sensor performance.
After 60 s, the quenching percent show: 40.52, 57.39, 52.72, 2 D hexagonal films couldn’t catch up with the 3 D pore structure films; After 120 s to 1200 s, the 3 D order cubic structure film shows higher and higher quenching intensity than the other two films.
Sizeable films with 3D order cubic channel structure exhibited a rapid response to explosives.
Feng, et al., Continuous mesoporous silica films with highly ordered large pore structures, Adv.
Online since: October 2025
Authors: Ahmed Raad Al-Adhadh, Aya Abbas Shaher, Noor A. Al-Ali, Zainab Jawad Kadhim
Many studies have indicated that developing a porous structure in biomaterials is a strategic feature for successful bone restoration [17–19].
Elemental analysis of the surface chemistry of the prepared samples (C0, C1, Z1, and CZ) was conducted using EDX, as demonstrated in Figure 2.
This means that supplied titanium substrate possesses an extraordinarily high degree of cleanliness and purity, and that the manufacturing process didn’t alter its surface chemistry.
Engineered wettability-gradient porous structure enabling efficient water manipulation in regenerative fuel cells.
Journal of Materials Chemistry B, 12(19), 4613-4628
Elemental analysis of the surface chemistry of the prepared samples (C0, C1, Z1, and CZ) was conducted using EDX, as demonstrated in Figure 2.
This means that supplied titanium substrate possesses an extraordinarily high degree of cleanliness and purity, and that the manufacturing process didn’t alter its surface chemistry.
Engineered wettability-gradient porous structure enabling efficient water manipulation in regenerative fuel cells.
Journal of Materials Chemistry B, 12(19), 4613-4628
Online since: September 2015
Authors: Joby V. Thomas, C.R. Anoop, K. Thomas Tharian, P. Chakravarthy
The joints display a wide variation in chemistry and phases present in the fusion zone as well as the ‘Heat Affected Zone’(HAZ) having significant influence on the properties and structural integrity of the weld joints.
The microstructure of the welded specimen sectioned at 20mm away from weld centre is comparable to that of the base metal structure.
The joint with ER630 filler wire had solidified in the ferrite form and during subsequent cooling attained the austenite –martensite structure [9].
This structure caused the reduction in hardness of the weld bead (~200HV) as compared to the wrought condition of 15-5PH (~365HV).
Higher hardness in the HAZ on both sides could be attributed to a recrystallised structure.
The microstructure of the welded specimen sectioned at 20mm away from weld centre is comparable to that of the base metal structure.
The joint with ER630 filler wire had solidified in the ferrite form and during subsequent cooling attained the austenite –martensite structure [9].
This structure caused the reduction in hardness of the weld bead (~200HV) as compared to the wrought condition of 15-5PH (~365HV).
Higher hardness in the HAZ on both sides could be attributed to a recrystallised structure.
Online since: February 2008
Authors: Ramaseshan Ramakrishnan, Ying Jun Liu, Sundarrajan Subramanian, Seeram Ramakrishna
Electrospinning was chosen as the fabrication method because it is a
simple traditional technique that is capable of manufacturing nano sized structures in a
large scale.
Incorporation of electrospun nanofibers into functional structures, Kristine Grahams, Mark Gogins and Heidi Schreuder Gibson, INTC, MD, USA, 2003. 9.
Processing and Structure Relationships in Electrospinning of Ceramic Fiber Systems, Wolfgang Sigmund et al, Journal of American Ceramic Society, 89 (2), pp395-407, 2006 15.
Rapid nucleophilic/oxidative decontamination of the chemical warfare agents, George Wagner and Yu-Chu Yang, Industrial engineering chemistry research, 45, pp 1925-1928, 2002 17.
Reductive destruction of chemical warfare agent simulants in water, Kiddle J and Mezyk Journal of Physical Chemistry B, 108, pp 9568-9570, 2004 23.
Incorporation of electrospun nanofibers into functional structures, Kristine Grahams, Mark Gogins and Heidi Schreuder Gibson, INTC, MD, USA, 2003. 9.
Processing and Structure Relationships in Electrospinning of Ceramic Fiber Systems, Wolfgang Sigmund et al, Journal of American Ceramic Society, 89 (2), pp395-407, 2006 15.
Rapid nucleophilic/oxidative decontamination of the chemical warfare agents, George Wagner and Yu-Chu Yang, Industrial engineering chemistry research, 45, pp 1925-1928, 2002 17.
Reductive destruction of chemical warfare agent simulants in water, Kiddle J and Mezyk Journal of Physical Chemistry B, 108, pp 9568-9570, 2004 23.
Online since: February 2014
Authors: Zheng Yi Jiang, Xiao Feng He, Liang Luo, Dong Bin Wei
The structure and chemical components distribution of the coating can be controlled by process parameters and the general quality of coating is good.
Coatings on Ti substrate generally have a porous structure and the coating process is highly efficient.
Covalent attachment, such as silane chemistry, self-assembled monolayers and plasma treatment, bonds biomolecules to the Ti surface via covalent bonds.
Bandyopadhyay: Low Stiffness Porous Ti Structures for Load-Bearing Implants, Acta Biomaterialia, vol. 3 (2007) pp. 997-1006
Soares: Mechanical Properties of Titania Films Used as Biomaterials, Materials Chemistry and Physics, vol. 102 (2007) pp. 92-97
Coatings on Ti substrate generally have a porous structure and the coating process is highly efficient.
Covalent attachment, such as silane chemistry, self-assembled monolayers and plasma treatment, bonds biomolecules to the Ti surface via covalent bonds.
Bandyopadhyay: Low Stiffness Porous Ti Structures for Load-Bearing Implants, Acta Biomaterialia, vol. 3 (2007) pp. 997-1006
Soares: Mechanical Properties of Titania Films Used as Biomaterials, Materials Chemistry and Physics, vol. 102 (2007) pp. 92-97
Online since: April 2021
Authors: Ruslan V. Chkalov, Dmitry A. Kochuev, Darya G. Chkalova
Granules larger than 100 nm are visible in the resulting composite structure.
Ilin, Femtosecond laser-induced periodic surface structures formation on molybdenum in air and liquid nitrogen, Proc. of intern. conf. on new trends in quantum and mesoscopic physics. (2018) 54-56
He, Spherical silica micro/nanomaterials with hierarchical structures: Synthesis and applications, Nanoscale. 3 (2011) 3984-4002
De Giacomo, et al., Cavitation dynamics of laser ablation of bulk and wire-shaped metals in water during nanoparticles production, Physical Chemistry Chemical Physics. 15 (2013) 3083-3092
Gordon, et al., Stability of micron-sized spheres formed by pulsed laser ablation of metals in superfluid helium and water, High Energy Chemistry. 48 (2014) 206-212
Ilin, Femtosecond laser-induced periodic surface structures formation on molybdenum in air and liquid nitrogen, Proc. of intern. conf. on new trends in quantum and mesoscopic physics. (2018) 54-56
He, Spherical silica micro/nanomaterials with hierarchical structures: Synthesis and applications, Nanoscale. 3 (2011) 3984-4002
De Giacomo, et al., Cavitation dynamics of laser ablation of bulk and wire-shaped metals in water during nanoparticles production, Physical Chemistry Chemical Physics. 15 (2013) 3083-3092
Gordon, et al., Stability of micron-sized spheres formed by pulsed laser ablation of metals in superfluid helium and water, High Energy Chemistry. 48 (2014) 206-212
Online since: January 2010
Authors: Yan He, Yang Lv, Lu Han
Synthesis and Adsorption Property of Mesoporous Molecular Sieve
MCM-41 from Iron Ore Tailings
Yan HE
1, a
Yang LV
2, b
Lu HAN
3, c
1, 2, 3 College of Environment and Chemistry Engineering, Shenyang Li gong University, Shenyang
110168, China
a
hy464@hotmail.com,
b
lvyang_lvyang@126.com, chanlu_72@hotmail.com
Keywords: Iron ore tailings; hydrothermal synthesis; MCM-41; adsorption
Abstract: The mesoporous molecular sieve MCM-41 was synthesized by hydrothermal synthesis
method with iron ore tailings as starting material, and CTAB as appendage.
The isotherms of nitrogen adsorption-desorption of the samples shown as Fig 4 exhibits a well-expressed hysteresis of loop type IV, which means the samples possess of good mesoporous structure and a narrow pore size distribution, which is in good agreement with the results of TEM.
The pores are parallel to each other and the pore structure is approximately 5-6 nm.
Reference [1] WU Xiuwen, MA Hongwen, LI Jinhong, et al. synthesis and structure Characteristics of aluminosilicate mesoporous sieve with 13X zeoliter Building units in Pore walls [J].
Chemistry engineer, 2005, 112(1): 30-32 [14] Langmuir1.The constitution and fundamental properties of solids and liquids [J].
The isotherms of nitrogen adsorption-desorption of the samples shown as Fig 4 exhibits a well-expressed hysteresis of loop type IV, which means the samples possess of good mesoporous structure and a narrow pore size distribution, which is in good agreement with the results of TEM.
The pores are parallel to each other and the pore structure is approximately 5-6 nm.
Reference [1] WU Xiuwen, MA Hongwen, LI Jinhong, et al. synthesis and structure Characteristics of aluminosilicate mesoporous sieve with 13X zeoliter Building units in Pore walls [J].
Chemistry engineer, 2005, 112(1): 30-32 [14] Langmuir1.The constitution and fundamental properties of solids and liquids [J].
Online since: November 2013
Authors: N.A. Edama, A. Sulaiman, K.H. Ku Hamid, M.N. Muhd Rodhi, Mohibah Musa, S.N. Abd. Rahim
According to Ajayi et. al. (2012), kaolinite clay are negatively charged aluminosilicate crystalline structures consisting of a three dimensional arrangement of SiO2 and AlO4- tetrahedrally linked to each other by a shared oxygen atom.
This result suggests the partial reduction of Al3+ and Fe2+ from the clay structure, in accordance with the changes in chemical composition as previously discussed in Table 2 and in agreement with the literature [16].
The micrographs of 1M and 5M treated clay indicate the disaggregation and decrease in size of clay structure on acid treatment and in agreement with the previous study [11].
Pajares, Passivation of a montmorillonite by the silica created in acid activation, Journal of Material Chemistry 2 (9) (1992) 907-911
Sarikaya, The effect of sulphuric acid activation on crystallinity, surface area, porosity, surface acidity and bleaching power of a bentonite, Food Chemistry, 105 (2007) 156-163
This result suggests the partial reduction of Al3+ and Fe2+ from the clay structure, in accordance with the changes in chemical composition as previously discussed in Table 2 and in agreement with the literature [16].
The micrographs of 1M and 5M treated clay indicate the disaggregation and decrease in size of clay structure on acid treatment and in agreement with the previous study [11].
Pajares, Passivation of a montmorillonite by the silica created in acid activation, Journal of Material Chemistry 2 (9) (1992) 907-911
Sarikaya, The effect of sulphuric acid activation on crystallinity, surface area, porosity, surface acidity and bleaching power of a bentonite, Food Chemistry, 105 (2007) 156-163
Online since: July 2006
Authors: M. Stanković, B. Marković, D. Jovanović, Z. Vuković, P. Banković
Introduction
Nickel supported metal catalysts play an important role in industrial chemistry and have been used
extensively in many industrial processes such as hydrogenations, hydrogenolysis, reforming, gas
shift conversion, etc., due to its ease of obtainment, high activity and low production.
Various aspects must be considered to develop an inner catalyst structure and create the corresponding metal surface [12].
Using the deposition-precipitation technique, porous structure support, metal concentration in the solution, precipitation time and reduction conditions may be some of the factors that are particularly relevant.
The composition and structure of the unreduced catalyst are of major importance for final catalyst characteristics [13].
Anderson: in Structure of Metallic Catalysts (Academic Press, New York 1975)
Various aspects must be considered to develop an inner catalyst structure and create the corresponding metal surface [12].
Using the deposition-precipitation technique, porous structure support, metal concentration in the solution, precipitation time and reduction conditions may be some of the factors that are particularly relevant.
The composition and structure of the unreduced catalyst are of major importance for final catalyst characteristics [13].
Anderson: in Structure of Metallic Catalysts (Academic Press, New York 1975)