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Online since: February 2026
Authors: Edgar Clyde R. Lopez
Cyclodextrin Covalent-Organic Frameworks: Bridging Host–Guest Chemistry and Porous Materials for Diverse Applications Edgar Clyde R.
Introduction The integration of supramolecular chemistry with porous framework design has created Cyclodextrin Covalent-Organic Frameworks (CD-COFs), a hybrid family that draws from chemistry, nanotechnology, polymer science, and materials engineering.
Modeling supported the enhanced enantioselectivity of the modified structures.
Data-driven modeling and machine learning can reveal structure property trends across composition and linker chemistry, then identify candidates suited for selectivity, capacity, kinetics, or stability under relevant conditions [21, 22].
Yang, "Core-shell structured covalent organic frameworks for the extraction of benzoylurea insecticides," Microchim.
Online since: October 2014
Authors: Jian Zhang, Hong Wei Deng, Chun Fang Dong, Jie Lin Li, Ke Ping Zhou, Wei Gang Tian
In addition, the occurrence of freezing-thawing damages to rocks is closely linked with the water chemistry environment.
In the mechanical properties of rocks under the effect of water chemistry, many foreign and domestic scholars also have conducted studies.
Zhang Jizhou [10] made a circulated freezing-thawing test on three rocks in two water chemistry environments (saturated distilled water, and soaked and corroded with nitric acid solution of 1%), finding the freezing-thawing damage to rocks was more much more severe under the acid condition than that under the pure water chemistry condition.
The freezing-thawing cyclic test Test rock sample and test instrument Red sandstone was chosen in Heze of Shandong, which was hazel and presented with a granular detrital structure.
The quality of the sample was increased after 10 times of freezing-thawing, but the increasing quality amount of the sample in different water chemistry solution was different.
Online since: June 2019
Authors: Qing Li, Yi Wu, Xin Liu, Zi Huang, Xiang Fei He, Xi Yang
Visible Light-Assisted Soft-Chemistry Route to Silver Nanomaterials at Room Temperature Yi Wu1,2, Xin Liu1,2, Zi Huang1,2, Xiangfei He1,2, Xi Yang1,2 and Qing Li1,2,a* 1Key Laboratory of Luminescent and Real-Time Analytical Chemistry, Ministry of Education, School of Materials and Energy, Southwest University, Chongqing, P.R.
China a*qli@swu.edu.cn Keywords: AgNPs, Soft-chemistry, Light-assisted Abstract.
XRD analysis was performed to confirm the crystalline structure of the nanocrystals.
In the XRD pattern, peaks at 2θ of 38, 44, 64 and 77 are indexed as (111), (200), (220) and (311) planes of Ag with cubic structure, which matched with the reported date (JCPDS card No. 04-0783).
Fig. 5 The Fluorescence spectroscopy of AgNPs prepared at different temperatures (T=25 ℃, T=40 ℃, T=90 ℃, T=100 ℃)(λexc = 221 nm) Summary In summary, a light-assisted soft-chemistry method for synthesizing silver nanoparticles by reducing AgNO3 with NaH2PO2·H2O at room temperature was successfully developed.
Online since: April 2005
Authors: Bernd O. Kolbesen, S. Metzger
Kolbesen Institute of Inorganic and Analytical Chemistry, Johann Wolfgang Goethe-Universität Marie-Curie-Str.11, D-60439 Frankfurt am Main, Germany S.Metzger@chemie.uni-frankfurt.de Keywords: HPLC-MS, MS/MS, complexing agent decomposition, single chemistry cleaning Abstract The suitability of high performance liquid chromatography (HPLC) for the direct determination of the concentration of complexing agents for single chemistry cleaning is demonstrated.
These organic compounds often have a limited lifetime, being destroyed by agressive chemicals also contained in the respective wet chemistries.
Methods used hitherto for the evaluation of complexing agent stability in single chemistry cleaning have been indirect.
The unchanged fragmentation pattern proves that no reaction took place at the substituent and that this compound derives from Pyrinan.N N N O N O N N O O O O H H H The structure in Fig. 6 is proposed for the decomposition product with the molecular mass of 540 amu.
Conclusion HPLC-UV/VIS can be used to assess the stability of complexing agents employed in single chemistry cleaning.
Online since: October 2013
Authors: Hai Xing Liu, Hui Juan Yue, Qing Liu, Lin Tong Wang, Yang Xu, Ting Ting Huang, Kai Qi Ye
Study on novel structure of praseodymium complex, C5H13O11Pr Hai-Xing Liu1,a, Qing Liu2,b, Ting-Ting Huang1,c, Yang Xu1,d, Lin-Tong Wang1,e, Hui-Juan Yue3,f and Kai-Qi Ye2,g 1 Chemistry & Chemical and Environmental Engineering College, Weifang University, Weifang 261061, P.R.
China 2 College of Chemistry, State Key Laboratory of Supramolecular Structure and Materials, Jilin University, Changchun 130012, P.R.
China 3 College of Chemistry, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, P.R.
ZR2010BL025), Open Project of State Key Laboratory of Supramolecular Structure and Materials (No. sklssm201323)(Jilin University), State Key Laboratory of Inorganic Synthesis and Preparative Chemistry (No. 2011-13)(Jilin University).
Liu, Journal of Structural Chemistry, 45, 114( 2004).
Online since: August 2018
Authors: Quoc Toan Le, Els Kesters, Yuya Akanishi, Frank Holsteyns, Marleen H. van der Veen, Atsushi Mizutani
Effect of Cleaning Chemistries on Cobalt: Surface Chemistries and Electrical Characterization Q.
This behavior could be caused by a change in the thickness of the surface layer (cobalt oxides) and/or a change in the surface chemistry of that surface layer.
XPS measurements were carried out to have further insight into the surface chemistries.
The schematic of the cross-section of the DD structure after the dielectric patterning using fluorocarbon-based plasma is illustrated in Figure 4(a).
(a) Figure 4: (a) Scheme showing the cross-section of the DD test structure after the dielectric patterning, (b) top-down SEM images of the DD structure obtained after the dielectric patterning, and (c) with subsequent wet cleaning using the formulated mixture at 50 °C for 2 min.
Online since: December 2012
Authors: Nazanin Farhadyar, M.S. Sadjadi, Farzad Farhadyar, Ali Farhadyar
Wet Chemistry Synthesis of Semiconductor Gold/Cu1.96S Nanorod and Study of its Photoluminescence Properties Nazanin Farhadyar1,a,, M.S.
Copper sulfides (Cu2-xS) can vary their band gap and structure with varying stoichiometries.
In both cases, the peaks observed at (004) and (108) planes confirm the orthorhombic structure for the as-prepared nanorods [8].
The XRD pattern (see Fig. 1) corresponds to typical Cu 1.96S (chalcocite) with orthorhombic l structure.
El-sayed, The chemistry and properties of nanocrystals of different shapes, Chem.
Online since: January 1992
Edited by: Zs. Kajcsos, Cs. Szeles
The foreword by Edward Teller and the summaries by Jean-Charles Abbe (Chemistry) and Alfred Seeger (Physics) demonstrate how the field is seen from "outside" and from "inside".
Electronic Structure Studies, Positron Diffusion .
Positron and Positronium Chemistry Liquid, Gaseous Phase Studies, Polymer Studies .
Online since: January 2009
Authors: Carlo Waldfried, Ivan L. Berry, Werner Boullart, G. Mannaert, Denis Shamiryan, S. Luo, L. Witters, K. Han, A. Falepin, R. Sonnemans
This technique allows to asses the effect of the strip chemistry on the geometry of the fin structures with a resolution of 5 Å in the ideal case.
A TEM cross section was made through a resistor structure as shown in fig. 5. 3 nMOS and 3 pMOS wafers have been analyzed.
The width variation in the cross section over the 10 fins in the same resistor structure was too large to draw conclusions.
It shows the necessity of using fluorine-free ash chemistries.
Figure 5: TEM cross section of a) fin resistor structure and b) one single fin.
Online since: April 2013
Authors: Jing Zhong Xiao, Zhang Xue Yu, Guang Zeng, Hai Xing Liu, Ping Yang, Qing Hua Zhang
China 2Department of Physics, University of Coimbra, Coimbra 3004-516, Portugal 3Department of Chemistry and Lift Sciences, Xiangnan University, Chenzhou 423043, People's Republic of China 4State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P.R.
Molecules form O—H…Cl , O—H…O , O—H…N intramolecular and intermolecular hydrogen bonds and stabilized the molecular structure.
The crystal data and structure refinement is shown in Table 1.
Molecules form O—H…Cl , O—H…O , O—H…N intramolecular and intermolecular hydrogen bonds and stabilized the molecular structure.
ZR2010BL025),State Key Laboratory of Inorganic Synthesis and Preparative Chemistry (Jilin University)(No. 2011-13), MOE Key Laboratory of Analytical Chemistry for Life Science (Nanjing University)(No.