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Online since: April 2014
Authors: Da Wei Fang, Shu Liang Zang, Wei Jun Shan, Qiang Yan, Du Li
Ultrasonic Synthesis of Ag2Se Nanocrystal in Perrhenate Solution
Wei-jun Shan, Qiang Yan, Du Li, Da-wei Fang*, Shu-liang Zang
Key laboratory of Rare and Scattered Elements Liaoning Province, College of Chemistry, Liaoning University, Shenyang 110036, P.
Ultrasound chemistry is an edge interdisciplinary emerging in recent years that has been used in the preparation of the special structure and properties of nano materials.
F12-265-4-00 References [1] Y L Yan, X F Qian, H J Xu, J Yin, Z K Zhu, A novel solid-liquid route for the preparation of Cu3Se2 and Ag2Se nano crystals, INORGANIC CHEMISTRY COMMUNICATIONS 6 (2003) 34-37
[2] H L Su, Y Xie, B Li, Y T Qian, Simple, convenient, mild hydrothermal route to nano crystalline CuSe and Ag2Se, MATERIALS RESEARCH BULLETIN 35 ( 2000) 465-469 [3] M V Busch, T G Van, P Monnoyer, J B Nagy, Structural characterization of colloidal Ag2Se nano crystals LANGMUIR 14 (1998) 1528-1531 [4] R Z Chen, D S Xu, G L Guo, L L Gui, Silver selenide nano-wires by electro-deposition JOURNAL OF THE ELECTROCHEMICAL SOCIETY 150 (2003)183-186 [5] Y J Glanville, D G Narehood, P E Sokol, A Amma, T Mallouk Preparation and synthesis of Ag2Se nano wires produced by template directed synthesis, JOURNAL OF MATERIALS CHEMISTRY, 12 (2002) 2433-2434
[6] Y Jiang, B Xie, J Wu, S W Yuan, Y Wu, H Huang, Y T Qian, Room-temperature synthesis of copper and silver, nano crystalline chalcogenides in mixed solvents, JOURNAL OF SOLID STATE CHEMISTRY 167 (2002) 28-33
Ultrasound chemistry is an edge interdisciplinary emerging in recent years that has been used in the preparation of the special structure and properties of nano materials.
F12-265-4-00 References [1] Y L Yan, X F Qian, H J Xu, J Yin, Z K Zhu, A novel solid-liquid route for the preparation of Cu3Se2 and Ag2Se nano crystals, INORGANIC CHEMISTRY COMMUNICATIONS 6 (2003) 34-37
[2] H L Su, Y Xie, B Li, Y T Qian, Simple, convenient, mild hydrothermal route to nano crystalline CuSe and Ag2Se, MATERIALS RESEARCH BULLETIN 35 ( 2000) 465-469 [3] M V Busch, T G Van, P Monnoyer, J B Nagy, Structural characterization of colloidal Ag2Se nano crystals LANGMUIR 14 (1998) 1528-1531 [4] R Z Chen, D S Xu, G L Guo, L L Gui, Silver selenide nano-wires by electro-deposition JOURNAL OF THE ELECTROCHEMICAL SOCIETY 150 (2003)183-186 [5] Y J Glanville, D G Narehood, P E Sokol, A Amma, T Mallouk Preparation and synthesis of Ag2Se nano wires produced by template directed synthesis, JOURNAL OF MATERIALS CHEMISTRY, 12 (2002) 2433-2434
[6] Y Jiang, B Xie, J Wu, S W Yuan, Y Wu, H Huang, Y T Qian, Room-temperature synthesis of copper and silver, nano crystalline chalcogenides in mixed solvents, JOURNAL OF SOLID STATE CHEMISTRY 167 (2002) 28-33
Online since: May 2019
Authors: Alfred A. Christy, Natthaya Siangdee, Peraya Hiranmartsuwan
Christy2,c
1Department of Chemistry, Faculty of Science and Technology, Thammasat University,
Pathumthani 12120, Thailand
2Department of Science, Faculty of Engineering and Science, University of Agder, Sericeboks 422, Kristiansand 4604, Norway
aperaya.ph@gmail.com, bnatthaya.sci.tu@gmail.com, calfred.christy@uia.no
Keywords: Aluminium (III) Oxide nanoparticle, Near Infrared Spectroscopy, Second derivative, Water adsorption
Abstract.
The second derivative spectra were used to understand the chemistry of adsorption of water molecules.
These authors reported hydrogen bonding between water molecules and hydroxyl groups on aluminium (III) oxide surface and showed hexagonal structure of water molecules on the surface.
Willians, Ullmann’s Encyclopedia of Industrial Chemistry Vol 2. (2000), p. 607-645
Kimmel, The Journal of Physical Chemistry C Vol. 122 (17). (2018), p. 9540–9551
The second derivative spectra were used to understand the chemistry of adsorption of water molecules.
These authors reported hydrogen bonding between water molecules and hydroxyl groups on aluminium (III) oxide surface and showed hexagonal structure of water molecules on the surface.
Willians, Ullmann’s Encyclopedia of Industrial Chemistry Vol 2. (2000), p. 607-645
Kimmel, The Journal of Physical Chemistry C Vol. 122 (17). (2018), p. 9540–9551
Online since: January 2013
Authors: Yan Ru Liang, Zhen Bin Gong, Wen Quan Li
The structure of cypermethrin and products B, C are shown in fig.2.
Pesticide Environmental Chemistry, Chemical Industry Press, BingJing, 2005
[7]L.O.Ruzo, J.E.Casida: submitted to Journal of Chemistry Society (London) Perkin I. (1980)
[8]L.O.Ruzo, J.E.Casida: submitted to Journal of Agricultural and Food Chemistry(1981)
[13]Gang Bi, Shizhong Tian, Zigang Feng: submitted to Environmental Chemistry(1995)
Pesticide Environmental Chemistry, Chemical Industry Press, BingJing, 2005
[7]L.O.Ruzo, J.E.Casida: submitted to Journal of Chemistry Society (London) Perkin I. (1980)
[8]L.O.Ruzo, J.E.Casida: submitted to Journal of Agricultural and Food Chemistry(1981)
[13]Gang Bi, Shizhong Tian, Zigang Feng: submitted to Environmental Chemistry(1995)
Online since: May 2013
Authors: Shui Jin Yang, Li Yu, Li Jiao Deng
H3PW6Mo6O40, a kind of oxygen bridge polynuclear complexes, has Keggin structure of the heteropoly acid.
As shown in Fig.1, pure H3PW6Mo6O40 gives peaks due to the Keggin structure at 1077 cm-1, 975 cm-1, 878 cm-1, 783 cm-1 and 513 cm-1.
Liu: Chinese Journal of Applied Chemistry, Vol.23(2006)No.1.p. 26(In Chinese)
Bai: Chinese Journal of Organic Chemistry, Vol.26(2006)No.2.p. 207(In Chinese)
Chinese Journal of Applied Chemistry, Vol.23 (2006) No.11.p.1249(In Chinese)
As shown in Fig.1, pure H3PW6Mo6O40 gives peaks due to the Keggin structure at 1077 cm-1, 975 cm-1, 878 cm-1, 783 cm-1 and 513 cm-1.
Liu: Chinese Journal of Applied Chemistry, Vol.23(2006)No.1.p. 26(In Chinese)
Bai: Chinese Journal of Organic Chemistry, Vol.26(2006)No.2.p. 207(In Chinese)
Chinese Journal of Applied Chemistry, Vol.23 (2006) No.11.p.1249(In Chinese)
Online since: April 2014
Authors: M.J.J. van Megen, W. Olthuis, A. van den Berg
Analytical Chemistry, 62(5):447-452, 1990. 80
[3] A.
Analytical Chemistry, 58(11):2321-2331, 1986. 80[4] K.
Analytical Chemistry, 80(4):972-977, 2008. 80 [10] M.
Analytical Chemistry, 81(19):8203-8212, 2009
Analytical Chemistry, 82(20):8502-9, 2010. 80 [16] S.
Analytical Chemistry, 58(11):2321-2331, 1986. 80[4] K.
Analytical Chemistry, 80(4):972-977, 2008. 80 [10] M.
Analytical Chemistry, 81(19):8203-8212, 2009
Analytical Chemistry, 82(20):8502-9, 2010. 80 [16] S.
Online since: May 2011
Authors: Jin Yu Yang, Yu Chang Su, Zhuo Chen, Xue Ying Liu
Among these, a number of works have been carried out on investigation of the crystal chemistry and luminescence properties of compounds having pyrochlore structure [2-3].
Usually the presence of the reflections from the crystallographic planes (111), (331) and (511) is considered as evidence of the pyrochlore structure distinguished form the defect fluorite structure.
The result confirmed that sample c possess cubic pyrochlore structure with space group of Fd-3m (227).
Lide: CRC Handbook of Chemistry and Physics (Taylor and Francis, Boca Raton 2007) [15] A.R.
West: Solid state chemistry and its applications (Wiley, New Delhi 1984) [16] L.Q.
Usually the presence of the reflections from the crystallographic planes (111), (331) and (511) is considered as evidence of the pyrochlore structure distinguished form the defect fluorite structure.
The result confirmed that sample c possess cubic pyrochlore structure with space group of Fd-3m (227).
Lide: CRC Handbook of Chemistry and Physics (Taylor and Francis, Boca Raton 2007) [15] A.R.
West: Solid state chemistry and its applications (Wiley, New Delhi 1984) [16] L.Q.
Online since: October 2008
Authors: Jin Sheng Liang, Li Jun Han
At the same time we explained the curves of infrared absorption
analysis of natural black tourmalines at room temperature are simillar despite of their diversification
in chemistry component and producing area, and they have high infrared emissivity from the theory
point of view.
The chemistry components of tourmalines are different according to their producing area and diggninigs among which the ferric oxide influences the infrared radiation emissivity significantly.
Some academician consider that its crystal structure belonging to c3v result in the emissivity, others consider that the emissivity due to the exsistence of alive bond[8].
It is similar with hydrogen in structure.The Schro&& dinger equation of this system is as follows: ( ) ( )21 21 , ,ˆ rrErrH rrrr Ψ=Ψ (1) among which ( )rV H +∇−∇−= 2 2 2 2 2 1 1 2 22 ˆ µµ hh (2) Making use of coordinates transform we obtained: −= + + = 21 21 2211 rrr rr R rrr rrr µµ µµ (3) ( )21,rr rr Ψ changes into ( )rR rr,Ψ ∇−∇ + =∇ ∇+∇ + =∇ rR rR 21 2 2 21 1 1 µµµ µµµ (4) )( 2 2 ˆ 2 21 2 2 2 2 21 1 1 2 rV H rR rR + ∇−∇ + − ∇+∇ + −= µµµ µ µµµ µ h h (5) ( ) ( )rVr R +∇−∇ + −= 2 2 2 21 2 2 2 µ µµ h h among which 21 21 µµ µµ µ + = = Hem µ 2 1 2 1 ≈ − , it is called conversion quality.
The curves of infrared absorption analysis of natural black tourmalines at room temperature are simillar and the absorb peaks are stabilizated despite of their diversification in chemistry component and producing area and difference in thermoelectricity[11].
The chemistry components of tourmalines are different according to their producing area and diggninigs among which the ferric oxide influences the infrared radiation emissivity significantly.
Some academician consider that its crystal structure belonging to c3v result in the emissivity, others consider that the emissivity due to the exsistence of alive bond[8].
It is similar with hydrogen in structure.The Schro&& dinger equation of this system is as follows: ( ) ( )21 21 , ,ˆ rrErrH rrrr Ψ=Ψ (1) among which ( )rV H +∇−∇−= 2 2 2 2 2 1 1 2 22 ˆ µµ hh (2) Making use of coordinates transform we obtained: −= + + = 21 21 2211 rrr rr R rrr rrr µµ µµ (3) ( )21,rr rr Ψ changes into ( )rR rr,Ψ ∇−∇ + =∇ ∇+∇ + =∇ rR rR 21 2 2 21 1 1 µµµ µµµ (4) )( 2 2 ˆ 2 21 2 2 2 2 21 1 1 2 rV H rR rR + ∇−∇ + − ∇+∇ + −= µµµ µ µµµ µ h h (5) ( ) ( )rVr R +∇−∇ + −= 2 2 2 21 2 2 2 µ µµ h h among which 21 21 µµ µµ µ + = = Hem µ 2 1 2 1 ≈ − , it is called conversion quality.
The curves of infrared absorption analysis of natural black tourmalines at room temperature are simillar and the absorb peaks are stabilizated despite of their diversification in chemistry component and producing area and difference in thermoelectricity[11].
Online since: November 2013
Authors: Maryam Rasoolzadeh, Reihaneh Zolfaghari, Shahram Ghanbari Pakdehi
The first reaction, i.e., the hydrazine decomposition, is a structure insensitive reaction, i.e., is independent of the particles size.
However, the ammonia decomposition is a structure sensitive reaction depending on the average size or diameter of the dispersed active metal.
So, the second reaction, ammonia decomposition, is a structure sensitive reaction depending on the average size or diameter of the dispersed active metal.
Ogg, The Chemistry of Hydrazine, JohnWiley & Sons, New York, 1951
Gimeno-Fabra, MOCVD OF Ir-Al2O3 Protective Coatings, Institute of Inorganic Chemistry of Siberian Brunch of Russian Academy of Sciences, Lavrentiev ave. 3, Novosibirsk, 630090, Russia, EADS Germany GmbH, Metallic Structures Department
However, the ammonia decomposition is a structure sensitive reaction depending on the average size or diameter of the dispersed active metal.
So, the second reaction, ammonia decomposition, is a structure sensitive reaction depending on the average size or diameter of the dispersed active metal.
Ogg, The Chemistry of Hydrazine, JohnWiley & Sons, New York, 1951
Gimeno-Fabra, MOCVD OF Ir-Al2O3 Protective Coatings, Institute of Inorganic Chemistry of Siberian Brunch of Russian Academy of Sciences, Lavrentiev ave. 3, Novosibirsk, 630090, Russia, EADS Germany GmbH, Metallic Structures Department
Online since: October 2015
Authors: Ludmila N. Shiyan, Elena N. Gryaznova, Olga I. Sidorova, Sergey Galanov
. % contains in its structure a thermodynamically and thermally stable α-Al2O3 phase.
Popov, Tin-containing systems as catalysts for deep oxidation of hydrocarbons, Russian Journal of Applied Chemistry, V. 75, 10 (2002) 1643-1645
Sidorova, Combined conversion of methane into syngas on Ni/MgO-Cr2O3 catalysts, Russian Journal of Applied Chemistry, V.87, 10 (2014) 143-1441
Boil, Organic Chemistry, Allyn and Bacon, Inc., Boston, 1970
Lunin, NiO and ZrO2-based catalysts in the reaction of complete methane oxidation, Russian Journal of Physical Chemistry A, V. 87, 11 (2013) 1804-1808
Popov, Tin-containing systems as catalysts for deep oxidation of hydrocarbons, Russian Journal of Applied Chemistry, V. 75, 10 (2002) 1643-1645
Sidorova, Combined conversion of methane into syngas on Ni/MgO-Cr2O3 catalysts, Russian Journal of Applied Chemistry, V.87, 10 (2014) 143-1441
Boil, Organic Chemistry, Allyn and Bacon, Inc., Boston, 1970
Lunin, NiO and ZrO2-based catalysts in the reaction of complete methane oxidation, Russian Journal of Physical Chemistry A, V. 87, 11 (2013) 1804-1808
Online since: September 2013
Authors: Hai Jin Zheng, Zhen Xin Zhao, Bu Wei Ma
Preparation and Application of Modified Polyacrylonitrile fiber as a Adsorbent for Precious Metals
Zhenxin ZHAO1,a, Buwei MA1,b, Haijin ZHENG1
1 College of Chemistry and Materials Engineering, Henan University of Urban Construction, Pingdingshan, Henan, China
azzx@hncj.edu.cn, bmbw519@hncj.edu.cn
Keywords: Modified Polypropylene Fiber; Precious Metal; Preparation; Adsorption
Abstract.
The structure of modified polyacrylonitrile fiber was characterized by the means of IR, EA, TG and gravimetric analysis, etc., meanwhile, the preparation conditions as well as adsorption property of the fiber for precious metal ions were researched.
The paper investigated the effect produced by solvent, molar ratio of reagent, reaction time, pH, etc. on reaction products, meanwhile the structure and property of the functional fiber were characterized by the means of IR, EA, TG, gravimetric analysis[8], etc..
Then the treated PANF was heated in DMF solvent for a long time but without dissolving showed all the three kinds of crosslinking agent can make PANF form reticular cross-linked structure.
Ion Exchange and Adsorption, 1998,14:388~396 [8] Handbook of Analytical Chemistry compiled by Teaching and Research section of Analytical Chemistry, Chemistry Department, Hangzhou University( The second Volume- Chemical Analysis) [M].Beijing: Chemical Industry Press, 1984.52,408,424 [9] Y.Z.Chen.Chelatometric Titration[M].Beijing:Science Press,1986 [10] H.M.Zeng, Z.D.Xu,Y.Lu.
The structure of modified polyacrylonitrile fiber was characterized by the means of IR, EA, TG and gravimetric analysis, etc., meanwhile, the preparation conditions as well as adsorption property of the fiber for precious metal ions were researched.
The paper investigated the effect produced by solvent, molar ratio of reagent, reaction time, pH, etc. on reaction products, meanwhile the structure and property of the functional fiber were characterized by the means of IR, EA, TG, gravimetric analysis[8], etc..
Then the treated PANF was heated in DMF solvent for a long time but without dissolving showed all the three kinds of crosslinking agent can make PANF form reticular cross-linked structure.
Ion Exchange and Adsorption, 1998,14:388~396 [8] Handbook of Analytical Chemistry compiled by Teaching and Research section of Analytical Chemistry, Chemistry Department, Hangzhou University( The second Volume- Chemical Analysis) [M].Beijing: Chemical Industry Press, 1984.52,408,424 [9] Y.Z.Chen.Chelatometric Titration[M].Beijing:Science Press,1986 [10] H.M.Zeng, Z.D.Xu,Y.Lu.