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Online since: August 2014
Authors: Jing Song Wang, Zheng Wei Xiong, Ping Sun, Sen Lu
Introduction
Porous silica gel is a three-dimensional nano network structure consisting of high-permeability pores and a nano framework, featuring high porosity, low density, high thermal stability and strong acid resistance.
Journal of Molecular Structure, 140-145(2009), p.919
Journal of Polymer Science: Part A: Polymer Chemistry, 5678-5686(2004), p.42
Chemistry. 11-15(1991),p.10.
Journal of Molecular Structure, 140-145(2009), p.919
Journal of Polymer Science: Part A: Polymer Chemistry, 5678-5686(2004), p.42
Chemistry. 11-15(1991),p.10.
Online since: September 2013
Authors: Yong Wei, Kun Zou, Nian Yu Huang, Jian Feng Chen, Cheng Qiao Cao, Zhang Shuang Deng
Synthesis and Anti-inflammatory Activity of 3-Aryloxylindolizine Derivatives via Sonogashira Coupling/5-endo-trig Cycloisomerization Domino Strategy
Yong Wei1, a, Chengqiao Cao1, b, Jianfeng Chen1, c, Kun Zou1, d, *,
Zhangshuang Deng1, e and Nianyu Huang1, f, *
1Hubei Key Laboratory of Natural Products Research and Development, College of Chemistry and Life Sciences, China Three Gorges University, Yichang, Hubei 443002, China
awei520yong@126.com, bcaochengqiao@yahoo.cn, cchenjianfeng2003@yahoo.com.cn, dkzou@ctgu.edu.cn, ed.zhangshuang@gmail.com, fhny115@126.com
Keywords: Anti-inflammatory agents, 3-aryloxylindolizine, IL-6 inhibitory effect, synthesis, 5-endo-trig
Abstract.
Results and Discussion 2.1 Chemistry Recently, the Cu(I)-mediated cycloisomerization of alkynyl pyridines become growing interest in the synthesis of indolizine derivatives.
With the aim to obtain potentially anti-inflammatory indolizine and study their structure-activity relationship (SAR), a series of 3-aryloxylindolizine were synthesized through the Sonogashira coupling/5-endo-trig cycloisomerization domino strategy (Scheme 1).
The future studies on the structure-activity relationship of the indolizine derivatives and their anti-inflammatory activity were under way in our research group.
Results and Discussion 2.1 Chemistry Recently, the Cu(I)-mediated cycloisomerization of alkynyl pyridines become growing interest in the synthesis of indolizine derivatives.
With the aim to obtain potentially anti-inflammatory indolizine and study their structure-activity relationship (SAR), a series of 3-aryloxylindolizine were synthesized through the Sonogashira coupling/5-endo-trig cycloisomerization domino strategy (Scheme 1).
The future studies on the structure-activity relationship of the indolizine derivatives and their anti-inflammatory activity were under way in our research group.
Online since: January 2022
Authors: Norliza Dzakaria, Azizul Hakim Lahuri, Mohd Ambar Yarmo, Maratun Najiha Abu Tahari
AMBAR Yarmo2,b,
MARATUN NAJIHA Abu Tahari3,b and NORLIZA Dzakaria4,c
1*Department of Science and Technology, Universiti Putra Malaysia Bintulu Campus, P.O Box 396, Nyabau Road, 97008 Bintulu, Sarawak, Malaysia
2,3Department of Chemical Sciences, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor, Malaysia
4School of Chemistry and Environment, Faculty of Applied Sciences, Universiti Teknologi MARA, Cawangan Negeri Sembilan, Kampus Kuala Pilah, Pekan Parit Tinggi, 72000 Kuala Pilah, Negeri Sembilan, Malaysia
a*azizulhakim@upm.edu.my, bambar@ukm.edu.my, cmaratunnajiha@gmail.com, dnorliza864@uitm.edu.my,
Keywords: Adsorption isotherm, barium oxide, CO2 capture, iron(III) oxide
Abstract.
The crystal structures were verified by recording the 2θ diffraction angle from 10⁰ to 80⁰ at a wavelength, λ = 0.154 nm.
However, the mesopore structure generated better for BaO/Fe2O3400 at calcination temperature of 400 °C with mesopore surface area (SMeso) of 9.6 m2/g.
Burghaus, Surface chemistry of CO2 – Adsorption of carbon dioxide on clean surfaces at ultrahigh vacuum, Prog.
The crystal structures were verified by recording the 2θ diffraction angle from 10⁰ to 80⁰ at a wavelength, λ = 0.154 nm.
However, the mesopore structure generated better for BaO/Fe2O3400 at calcination temperature of 400 °C with mesopore surface area (SMeso) of 9.6 m2/g.
Burghaus, Surface chemistry of CO2 – Adsorption of carbon dioxide on clean surfaces at ultrahigh vacuum, Prog.
Online since: July 2020
Authors: Ameen Hadi Mohammed, Tamador Ali Mahmood, Selvana Adwar Yousif, Aminu Musa, Nerodh Nasser Dally
Synthesis, Characterization and Reactivity Ratios of Poly Phenyl Acrylamide-Co-Methyl Methacrylate
Ameen Hadi Mohammed1,a*, Tamador Ali Mahmood2,b,
Selvana Adwar Yousif3,c, Aminu Musa4,d and Nerodh Nasser Dally5,e
1,2,3,5Department of Chemistry, College of Science for Women, University of Baghdad, 10071 Al Jadria, Baghdad, Iraq
4Department of Pure and Industrial Chemistry, Faculty of Natural and Applied Sciences, Umaru Musa Yar’adua University, Katsina, Dutsin-Ma Road, P.M.B 2218, Katsina 820001, Nigeria
aameenhadi80@yahoo.com, btamadhor_mahmaud@yahoo.com, cSilvanaedwer@yahoo.com, daminu.musa@umyu.edu.ng, enerodhnasser@yahoo.com
Keywords: Phenyl acrylamide, methyl methacrylate, reactivity ratios, sequence distribution.
The basic explorations of structure property correlations and the variety of commercial and biological applications all attest to the fact that copolymerisation is highly useful [5].
The structure of synthesized copolymer was confirmed by FT-IR technique.
The basic explorations of structure property correlations and the variety of commercial and biological applications all attest to the fact that copolymerisation is highly useful [5].
The structure of synthesized copolymer was confirmed by FT-IR technique.
Online since: August 2023
Authors: Yasa Sampurno, Fritz Redeker, Jason J. Keleher, Ara Philipossian, Kiana A. Cahue
On the other hand, Flucto-CMP applies electromagnetic waves that result in BTA forming a much softer and less dense Cu(II) structure (Figure 2) which causes high removal rates at less mechanically-aggressive conditions.
Figure 2: Dense and rugged passivation layer formed during conventional Cu CMP (top), and softer and less dense Cu(II) structure during Cu polishing with Flucto-CMP® (bottom).
For example, polishing SiC involves the use of aggressive redox chemistries (i.e., KMnO4) and harsh polishing conditions such as high nanoparticle loading and shear force), which lead to an increase in removal but have the potential to increase surface defects.
Exploiting the synergistic relationship between the slurry additive and an H2O2-based formulation has shown that SiC removal is highly dependent on the formation of a modified surface complexation layer produced by the interaction of the substrate with the slurry additives, creating an electrophilic chemistry-nanoparticle macroenvironment.
Figure 2: Dense and rugged passivation layer formed during conventional Cu CMP (top), and softer and less dense Cu(II) structure during Cu polishing with Flucto-CMP® (bottom).
For example, polishing SiC involves the use of aggressive redox chemistries (i.e., KMnO4) and harsh polishing conditions such as high nanoparticle loading and shear force), which lead to an increase in removal but have the potential to increase surface defects.
Exploiting the synergistic relationship between the slurry additive and an H2O2-based formulation has shown that SiC removal is highly dependent on the formation of a modified surface complexation layer produced by the interaction of the substrate with the slurry additives, creating an electrophilic chemistry-nanoparticle macroenvironment.
Online since: March 2016
Authors: Sheikh Ahmad Izaddin Sheikh Mohd Ghazali, Siti Halimah Sarijo, Mohd Zobir Hussein
One of the most important properties of the anionic clays is their high anionic exchange capacity that is related to their lamellae structure, this allows the exchange of their original anions with those present in an aqueous solution [4-7].
ZADX prepared by using 0.1 M 3,4D produced sharp, symmetrical with high intensity peaks especially for the 003 reflection with basal spacing of 19.0 Å can be clearly observed indicates that pure phased nanolayered structure was obtained.
O’Hare, Intercalation chemistry of layered double hydroxides: recent developments and applications, J.
Chemistry of layered double hydroxides.
ZADX prepared by using 0.1 M 3,4D produced sharp, symmetrical with high intensity peaks especially for the 003 reflection with basal spacing of 19.0 Å can be clearly observed indicates that pure phased nanolayered structure was obtained.
O’Hare, Intercalation chemistry of layered double hydroxides: recent developments and applications, J.
Chemistry of layered double hydroxides.
Online since: March 2012
Authors: Dong Mei Huang, Yao Li, Bin Nong, Yan Ping Lei
Experimental equipments
In this study, the reactor of photocatalysis bleaching is self-designed, the structure is shown in Figure 1.
Figure 1 Structure of photocatalysis bleaching reactor a—oxygen inlet b—quartz cold trap’s cooling water inlet c—quartz cold trap’s cooling water outlet d—reactor’s cooling water outlet e—reactor’s cooling water inlet ①stainless steel oxygen tube ②quartz cold trap ③stainless steel jacketed reactor ④reactor bracket ⑤agitator drive device ⑥stirrer ⑦medium pressure mercury lamp ⑧reactor cover ⑨mercury lamp wiring The content of metal ions in the pulp are determined by the atomic absorption spectrophotometer.
[2] Marine EvnaDer,Journal of Wood Chemistry and Technology,1996,16(2):155-167
[3] Zhu ShengYu, Zhou Yongjia, Shen Yangwen, A Short Course on Coordination Chemistry[M], Tianjin Science and Technology Press, 1990
Figure 1 Structure of photocatalysis bleaching reactor a—oxygen inlet b—quartz cold trap’s cooling water inlet c—quartz cold trap’s cooling water outlet d—reactor’s cooling water outlet e—reactor’s cooling water inlet ①stainless steel oxygen tube ②quartz cold trap ③stainless steel jacketed reactor ④reactor bracket ⑤agitator drive device ⑥stirrer ⑦medium pressure mercury lamp ⑧reactor cover ⑨mercury lamp wiring The content of metal ions in the pulp are determined by the atomic absorption spectrophotometer.
[2] Marine EvnaDer,Journal of Wood Chemistry and Technology,1996,16(2):155-167
[3] Zhu ShengYu, Zhou Yongjia, Shen Yangwen, A Short Course on Coordination Chemistry[M], Tianjin Science and Technology Press, 1990
Online since: January 2024
Authors: Khairunisak Abdul Razak, Noorhashimah Mohamad Nor, Nurul Hidayah Ramli, Liew Xian Yun
All peaks were well defined and could be indexed to the Rhombohedral structure Bi crystal system of the R-3m space group (ICDD card no. 00-005-0519).
ACS Sustainable Chemistry and Engineering, 2013. 1(7): p. 713-723
Chemistry Letters, 2013. 42(2): p. 150-152
[25] Piella, J., et al., Characterizing Nanoparticles Reactivity: Structure-Photocatalytic Activity Relationship.
ACS Sustainable Chemistry and Engineering, 2013. 1(7): p. 713-723
Chemistry Letters, 2013. 42(2): p. 150-152
[25] Piella, J., et al., Characterizing Nanoparticles Reactivity: Structure-Photocatalytic Activity Relationship.
Online since: August 2016
Authors: Peng Cao, Muhammad Dilawer Hayat
The reason of this higher interaction lies in the chemistry of castor oil [11].
PEG is a crystalline polymer (chemical structure: HO-[CH2-CH2-O]n-H) with an open helical structure.
Edmonds, Debinding behaviour of a water soluble PEG/PMMA binder for Ti metal injection moulding, Materials Chemistry and Physics 139 (2013) 557-65
PEG is a crystalline polymer (chemical structure: HO-[CH2-CH2-O]n-H) with an open helical structure.
Edmonds, Debinding behaviour of a water soluble PEG/PMMA binder for Ti metal injection moulding, Materials Chemistry and Physics 139 (2013) 557-65
Online since: May 2011
Authors: Quan Wen Liu, Hui Xu, Shuli Gao, Jian Nong Chen
Improved detection of Hg2+ in aqueous solution with high sensitivity and selectivity by using mercury-specific DNA, Sybr Green I and gold nanoparticles
Hui Xu1,a *, Shuli Gao1,b, Jiannong Chen2,c and Quanwen Liu1,d
1School of Chemistry and Material Sciences, Ludong University, Yantai 264025, China
2Department of Physics, Ludong University, Yantai 264025, China
a xuhui235@yahoo.com.cn, b shuli0049@126.com, c jnchen1963@yahoo.com.cn, d ldu_lqw@163.com
Keywords: Sybr Green I; Hg2+; K+; Gold nanoparticle
Abstract.
Four protocols have been reported for detection of Hg2+ using a mercury specific DNA (MSD) based on T-Hg2+-T (T=thymine) chemistry because T-T mismatch shows high selectivity to Hg2+ against many other metal ions [33].
It forms a hairpin structure in the presence of Hg2+, and presents a random coil form in the absence of Hg2+.
K+ led to significant fluorescence increase which suggested that the PSO folded into G-quartet structure and being intercalated by SG.
Four protocols have been reported for detection of Hg2+ using a mercury specific DNA (MSD) based on T-Hg2+-T (T=thymine) chemistry because T-T mismatch shows high selectivity to Hg2+ against many other metal ions [33].
It forms a hairpin structure in the presence of Hg2+, and presents a random coil form in the absence of Hg2+.
K+ led to significant fluorescence increase which suggested that the PSO folded into G-quartet structure and being intercalated by SG.