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Online since: October 2010
Authors: V. Rumyantsev, Andrey Osmakov, N. Korableva, N. Belykh, L. Stafeckis, S.S. Ordanyan
Ceramics based on nanosized plasma chemistry Si3N4 powder compositions s (30-100 nm) is processed by activated pressureless sintering, hot pressing and hot isostatic pressing.
Activated pressureless sintering of nanosized plasma chemistry Si3N4 powders led to considerable economic advantages in processing Si3N4 spherical rotation bodies for hybrid roller bearings and cutting tools.
Plasma chemistry synthesized (PCS) powders feature enhanced sintering activity, due to the high dispersion level and quenching of reaction products during high-speed travel through plasma flux.
To compare physical and mechanical performances and structures the HP temperature was the same as one used in APS.
Electron microscopy of the consolidated samples showed little effect of the volumetric consolidation approach on fracture surface structure.
Activated pressureless sintering of nanosized plasma chemistry Si3N4 powders led to considerable economic advantages in processing Si3N4 spherical rotation bodies for hybrid roller bearings and cutting tools.
Plasma chemistry synthesized (PCS) powders feature enhanced sintering activity, due to the high dispersion level and quenching of reaction products during high-speed travel through plasma flux.
To compare physical and mechanical performances and structures the HP temperature was the same as one used in APS.
Electron microscopy of the consolidated samples showed little effect of the volumetric consolidation approach on fracture surface structure.
Online since: September 2016
Authors: Robert Bruce, John Papalia, Nathan Marchack, Hiroyuki Miyazoe, Sebastian Engelmann, Eric A. Joseph
The experimental structures used consisted of patterns defined by a 193nm lithography process for 200 nm and 400 nm pitch features and e-beam lithography for small pitch features (<50 nm line/space pitch).
Figure 1: PE-ALE impact of gas chemistry.
Chemistry C (Figure5) was chosen as ideal chemistry to pattern nitride materials.
Figure 5: Etch rates for nitride etch by optimizing discharge chemistry.
The CW process, which utilizes CF4/CHF3 chemistry, is our baseline.
Figure 1: PE-ALE impact of gas chemistry.
Chemistry C (Figure5) was chosen as ideal chemistry to pattern nitride materials.
Figure 5: Etch rates for nitride etch by optimizing discharge chemistry.
The CW process, which utilizes CF4/CHF3 chemistry, is our baseline.
Online since: January 2005
Authors: Jae Moon Lee, Jeong Gon Yoo, Ji Sik Kim, Kee Sun Sohn
An evolutionary optimization process involving a genetic algorithm and combinatorial
chemistry (combi-chem) was tailored exclusively for the development of LED phosphors.
Experimental Procedures The overall process of the combinatorial chemistry system adopted in the present investigation is described in more detail in our previous reports[8].
It was found that this sample had an oxyapatite structure (M10(SiO4)6Oδ, M=Ca, Eu, Mg, Ba, P63/m).
It can be thus deduced that Eu0.14Mg0.18Ca0.07Ba0.12B0.17Si0.32Oδ consists of a major phase, the structure of which is the oxyapatite and a mixture of several minor unknown phases.
The result from the structural analysis showed that the structure of Eu0.14Mg0.18Ca0.07Ba0.12B0.17Si0.32Oδ was an oxyapatite (M10(SiO4)6Oδ, M=Ca, Eu, Mg, Ba) structure, whereas the Tb0.01Gd0.02Ce0.04B0.1Si0.83Oδ was proven to be a glassy phase.
Experimental Procedures The overall process of the combinatorial chemistry system adopted in the present investigation is described in more detail in our previous reports[8].
It was found that this sample had an oxyapatite structure (M10(SiO4)6Oδ, M=Ca, Eu, Mg, Ba, P63/m).
It can be thus deduced that Eu0.14Mg0.18Ca0.07Ba0.12B0.17Si0.32Oδ consists of a major phase, the structure of which is the oxyapatite and a mixture of several minor unknown phases.
The result from the structural analysis showed that the structure of Eu0.14Mg0.18Ca0.07Ba0.12B0.17Si0.32Oδ was an oxyapatite (M10(SiO4)6Oδ, M=Ca, Eu, Mg, Ba) structure, whereas the Tb0.01Gd0.02Ce0.04B0.1Si0.83Oδ was proven to be a glassy phase.
Online since: September 2013
Authors: Hai Xing Liu, Qing Hua Zhang, Zhang Xue Yu, Yang Xu, Xiao Ping Zhang, Quan Hua Fan, Ting Ting Huang
Study on a novel structure of Yttrium complex, C4H10O10Y
Hai-Xing Liua, Qing-Hua Zhangb, Zhang-Xue Yuc, Quan-Hua Fand,
Ting-Ting Huange, Xiao-Ping Zhangf, Yang Xug
Chemistry & Chemical and Environmental Engineering College, Weifang University, Weifang 261061, P.R.
The molecular structure stabilized by the O-H…O hydrogen-bonding interactions.
The crystal data and structure refinement is shown in Table 1.
ZR2010BL025),Open Project of State Key Laboratory of Supramolecular Structure and Materials (No. sklssm201323)(Jilin University), State Key Laboratory of Inorganic Synthesis and Preparative Chemistry (No. 2011-13)(Jilin University).
Pan, Journal of Structural Chemistry, 46, 895(2005)
The molecular structure stabilized by the O-H…O hydrogen-bonding interactions.
The crystal data and structure refinement is shown in Table 1.
ZR2010BL025),Open Project of State Key Laboratory of Supramolecular Structure and Materials (No. sklssm201323)(Jilin University), State Key Laboratory of Inorganic Synthesis and Preparative Chemistry (No. 2011-13)(Jilin University).
Pan, Journal of Structural Chemistry, 46, 895(2005)
Online since: June 2012
Authors: Jae Kyoo Lim, Roma Gurung, Seok Geun Park, Anil Kunwar
Green chemistry approach (hydrothermal process) is utilized for grafting maleic anhydride (MA) into linear low density polyethylene (LLDPE), thereby enhancing the compatiblility of the latter in its blend with polylactic acid (PLA).
Shen et.al. [7] have highlighted the use of hydrothermal process (green chemistry approach) for preparing PE-g-MA.
As per the requirements of green chemistry approach (hydrothermal process), the graft copolymer was prepared in a sealed vessel filled with water as the solvent [7].
Solid Structures, Vol. 29 (1992), p. 1105
[15] N.L.Hancox, in: Impact behavior of fibre-reinforced composite materials and structures, edited by S.R.Reid and G.Zhou, Woodhead Publishing Limited, Cambridge, England (2000).
Shen et.al. [7] have highlighted the use of hydrothermal process (green chemistry approach) for preparing PE-g-MA.
As per the requirements of green chemistry approach (hydrothermal process), the graft copolymer was prepared in a sealed vessel filled with water as the solvent [7].
Solid Structures, Vol. 29 (1992), p. 1105
[15] N.L.Hancox, in: Impact behavior of fibre-reinforced composite materials and structures, edited by S.R.Reid and G.Zhou, Woodhead Publishing Limited, Cambridge, England (2000).
Online since: November 2012
Authors: Chun Xia Wang, Quan Jiu Wang, Zhuang Liang
Chemistry amelioration measure is a means of regulating soil water and salt movement, the paper introduced the method of combined the under-mulch drip irrigation with applying of chemicals, such as PAM, Handilong and Gypsum.
The Field experimental results indicate that the surface soil bulk density reduced degree for applying chemistry matters is higher than without applying chemical farmland (as comparison treatment), the reduced rate shows to reduce one after the other increase with applying increasing.
Handilong is a kind of humic acid, it can ameliorate soil physical structure, regulate soil acid- alkalinity and improve crop enzymatic living and crop output [9-11].
Conclusions Doe to Longevity of ameliorate and the movement of soil salt is also perplexing, so it is unavoidable to have other factors besides the function of chemistry regulatory measures, and the following find a part of primary results.
The reduced degree of bulk density is between 8.55% and 13.09% for applying chemistry matters, and 5.33% without applying chemical farmland, and it shows to reduce one after the other increase with applying chemicals increasing.
The Field experimental results indicate that the surface soil bulk density reduced degree for applying chemistry matters is higher than without applying chemical farmland (as comparison treatment), the reduced rate shows to reduce one after the other increase with applying increasing.
Handilong is a kind of humic acid, it can ameliorate soil physical structure, regulate soil acid- alkalinity and improve crop enzymatic living and crop output [9-11].
Conclusions Doe to Longevity of ameliorate and the movement of soil salt is also perplexing, so it is unavoidable to have other factors besides the function of chemistry regulatory measures, and the following find a part of primary results.
The reduced degree of bulk density is between 8.55% and 13.09% for applying chemistry matters, and 5.33% without applying chemical farmland, and it shows to reduce one after the other increase with applying chemicals increasing.
Online since: June 2013
Authors: Yan Guan, Zhao Man Zhong
In the past few decades, the computer processing of molecular structure has been appreciated extensively and deeply researched, and it becomes one of the important research areas of computer chemistry [1-3].
Some typical database retrieval methods have emerged, such as chemistry server of ISI Company and chemfinder of Britain Cambridge.
Kong, in: Introduction to File Formats for Storage of Chemical Structure and Their Conversion, edited by Computers and Applied Chemistry, vol. 24, pp. 1260-1264 (2007)
Wen, in: A New Algorithm for 2-Dimentional Molecular Structure Searching, edited by Computers and Applied Chemistry, vol. 26, pp. 1539-1542 (2009)
Sun, in: Automatic Extracting Intersection Information of Static Chemical Molecular Structure Images, edited by Computers and Chemistry, vol. 29, pp. 499-502 (2012)
Some typical database retrieval methods have emerged, such as chemistry server of ISI Company and chemfinder of Britain Cambridge.
Kong, in: Introduction to File Formats for Storage of Chemical Structure and Their Conversion, edited by Computers and Applied Chemistry, vol. 24, pp. 1260-1264 (2007)
Wen, in: A New Algorithm for 2-Dimentional Molecular Structure Searching, edited by Computers and Applied Chemistry, vol. 26, pp. 1539-1542 (2009)
Sun, in: Automatic Extracting Intersection Information of Static Chemical Molecular Structure Images, edited by Computers and Chemistry, vol. 29, pp. 499-502 (2012)
Online since: October 2015
Authors: Tatyana G. Cherkasova, Elizaveta V. Cherkasova
The crystal structures are determined by the methods of X-ray diffraction.
Terney, Modern Organic Chemistry, World, Moscow (Mir, Moskva – in Russian), 1981 [13] V.Y.
Chuykova, Organic Chemistry, High School, Moscow (Vysshiya Skola, Moskva – in Russian), 2009
Glick M.D., Bridged Lanthanide (III) Complexes, Journal of Inorganic Chemistry 11(1972) 2818-2826
Kukushkin, Higher order compounds, Chemistry, Leningrad (Khimiya, Leningrad – in Russian) 1991.
Terney, Modern Organic Chemistry, World, Moscow (Mir, Moskva – in Russian), 1981 [13] V.Y.
Chuykova, Organic Chemistry, High School, Moscow (Vysshiya Skola, Moskva – in Russian), 2009
Glick M.D., Bridged Lanthanide (III) Complexes, Journal of Inorganic Chemistry 11(1972) 2818-2826
Kukushkin, Higher order compounds, Chemistry, Leningrad (Khimiya, Leningrad – in Russian) 1991.
Online since: September 2013
Authors: An Bang Chen, Hai Feng Gan, Xin Li, Yang Zhi Zhou, Ling Ling Huang, Zheng Fang, Kai Guo
Flow chemistry, as a rapidly emerging technology, is exploited to provide a safe and scalable route for the pharmaceutically interesting coumarin.
Structure of coumarin Coumarin (Figure 1), which can be found in many plants, such as Dipteryx odorata, Anthoxanthum odoratum, and Galium odoratum, has been used as traditional medicine for thousands of years.
Herein, the flow chemistry methodology for the synthesis of coumarin was studied for the potential scale-up.
[3] a) Microreactor (Eds.: Ehrfeld, W.; Hessel, V.; Lowe, H.), Wiley-VCH, Weinheim, 2000; b) Chemical Micro Process Engineering (Eds.: Hessel, V.; Hardt, S.; Lowe, H.), Wiley-VCH, Weinheim, 2004; c) Microreactors in Organic Synthesis (Ed.: Wirth, T.), Wiley-VCH, Weinheim, 2008; d) Flash Chemistry: Fast Organic Synthesis in Microsystems (Ed.
Majumder; Further Evidence for the Mechanism of Formation of Coumarin by Perkin Reaction from salicylaldehyde and a Novel Synthesis of 1,1-dipheny-2(2’-hydroxyphenyl) ethane from O-α,α-diphenylacetylacetylsalicylaldehyde with Et3N. 11TH international electronic conference on synthetic organic chemistry, Molecules, 2007, a013
Structure of coumarin Coumarin (Figure 1), which can be found in many plants, such as Dipteryx odorata, Anthoxanthum odoratum, and Galium odoratum, has been used as traditional medicine for thousands of years.
Herein, the flow chemistry methodology for the synthesis of coumarin was studied for the potential scale-up.
[3] a) Microreactor (Eds.: Ehrfeld, W.; Hessel, V.; Lowe, H.), Wiley-VCH, Weinheim, 2000; b) Chemical Micro Process Engineering (Eds.: Hessel, V.; Hardt, S.; Lowe, H.), Wiley-VCH, Weinheim, 2004; c) Microreactors in Organic Synthesis (Ed.: Wirth, T.), Wiley-VCH, Weinheim, 2008; d) Flash Chemistry: Fast Organic Synthesis in Microsystems (Ed.
Majumder; Further Evidence for the Mechanism of Formation of Coumarin by Perkin Reaction from salicylaldehyde and a Novel Synthesis of 1,1-dipheny-2(2’-hydroxyphenyl) ethane from O-α,α-diphenylacetylacetylsalicylaldehyde with Et3N. 11TH international electronic conference on synthetic organic chemistry, Molecules, 2007, a013
Online since: July 2012
Authors: Xi Shi Tai, Hui Juan Yue, Guang Zeng, Hai Xing Liu, Qing Zhi Pan, Ting Yan Zhuang
Study on novel structure of Yttrium complex: C4H12K2O22S2Y2
Haixing Liu1,a Tingyan Zhuang1,b Qingzhi Pan2,c Huijuan Yue2,d
Guang Zeng2,e Xishi Tai1,f
1 College of Chemistry and Chemical Engineering, Weifang University, Weifang 261061, P.R.
China 2 State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, P.R.
In this paper, the novel structure of Yttrium complex is reported.
The crystal data and structure refinement is shown in Table 1.
ZR2010BL025),State Key Laboratory of Inorganic Synthesis and Preparative Chemistry (Jilin University)(No. 2011-13), “MOE Key Laboratory of Analytical Chemistry for Life Science (Nanjing University)(No.
China 2 State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, P.R.
In this paper, the novel structure of Yttrium complex is reported.
The crystal data and structure refinement is shown in Table 1.
ZR2010BL025),State Key Laboratory of Inorganic Synthesis and Preparative Chemistry (Jilin University)(No. 2011-13), “MOE Key Laboratory of Analytical Chemistry for Life Science (Nanjing University)(No.