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Online since: December 2013
Authors: Qian Qian Gao, Song Wang Yang, Lei Lei
In 1991, Gratzel et al[1] employed porous nanocrystalline TiO2 films as the photoanode, chelate of Ru as the sensitizer, and invented a new structure solar cells, dye-sensitized solar cells (DSSCs). 7.1% of photoelectric conversion efficiency was obtained at one sun (AM1.5, 100mW·cm-2).
Smits: Journal of Physical Chemistry B, vol. 110, p. 19191-19197, (2006) [4] H.
Smits: Journal of Physical Chemistry B, vol. 110, p. 19191-19197, (2006) [4] H.
Online since: September 2013
Authors: Dominik Gazdič
Moore Physical Chemistry, Praha, SNTL 1979
[2] URL: < http://database.iem.ac.ru/mincryst/>
[3] VAVŘÍN, F Binders, Brno, SNTL 1987 (in Czech)
[4] DUDA, W.H., Cement-data-book, Bauverlag GmbH - Wiesbaden and Berlin, ISBN 3-7625-0180-7, Berlin, 1976
Cracow, Poland, Institute of building materials and structures. 2007. p. 146 - 152.
Cracow, Poland, Institute of building materials and structures. 2007. p. 146 - 152.
Online since: May 2015
Authors: Xu Lu, Li Ni
There are different types of polymer nanofiber crossed together in the hybrid nanofiber membrane, where strong action due to different functional groups in different molecules occurred; after heat treatment some PEO nanofibers in the hybrid nanofiber membrane were melted, it can further enhance the combination at the crossing point and form the consolidated crossing structure.
Progress in Chemistry, 2009, 21(1): 210-216
Progress in Chemistry, 2009, 21(1): 210-216
Online since: August 2013
Authors: Jian Min Zhang, Gao Peng Zhang, Ya Wei Li, Ting Cao, Pan Wang
Study on Supercapacity properties of manganese dioxide active material by the Cation Concentration Change on the Electrode Surface
Jian Min Zhanga, Pan Wangb , Gao Peng Zhangc, Ya Wei Lid, Ting Caoe
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, China, 450001
azhjm@zzu.edu.cn, bpwang@qq.com, cgpzhang@qq.com, dlywclark@126.com, etcao@126.com
Keywords: supercapacitor, Charge-discharge mechanism, Manganese dioxide
Abstract.
Considering the tunnel structure of manganese dioxide, some researchers [7,8] proposed the capacitive charge storage mechanism of manganese dioxide in the K2SO4 solution expressed as: MnO2 +δK+ +δe- Û KδMnO2 (1) This process involves the reversible intercalation/detercalation of potassium ion and variation of manganese valence between Mn(IV) and Mn(III).
Considering the tunnel structure of manganese dioxide, some researchers [7,8] proposed the capacitive charge storage mechanism of manganese dioxide in the K2SO4 solution expressed as: MnO2 +δK+ +δe- Û KδMnO2 (1) This process involves the reversible intercalation/detercalation of potassium ion and variation of manganese valence between Mn(IV) and Mn(III).
Online since: July 2014
Authors: Gang Liu, Jun Jie Song
Research on Photochromic Compounds with Efficient Synthesis and Photochromic Properties of 1-(2-methyl-5-phenyl-3-thienyl)-2-[2-methyl-5-(4-pentylphenyl)-3-thienyl]perfluorocyclopentene
Junjie Song and Gang Liu*
Jiangxi Key Lab of Organic Chemistry, Jiangxi Science and Technology Normal University Nanchang 330013, China
liugang0926@163.com
Keywords: Phenyl; Diarylethene; Photochromism; Fluorescence
Abstract.
The structures of diarylethenes 1a were confirmed by 1H NMR (400 MHz, CDCl3, TMS): δ 0.80-0.91 (m, 3H), 1.16-1.25 (m, 4H), 1.35-1.54 (m, 2H), 2.35-2.37 (t, 6H),2.54-2.67 (m, 2H) 7.01-7.18 (d, 2H), 7.21-7.24 (d, 1H), 7.26-7.43 (d, 2H), 7.46-7.52 (t, 2H), 7.71-7.74 (d, 4H) Scheme 2.
The structures of diarylethenes 1a were confirmed by 1H NMR (400 MHz, CDCl3, TMS): δ 0.80-0.91 (m, 3H), 1.16-1.25 (m, 4H), 1.35-1.54 (m, 2H), 2.35-2.37 (t, 6H),2.54-2.67 (m, 2H) 7.01-7.18 (d, 2H), 7.21-7.24 (d, 1H), 7.26-7.43 (d, 2H), 7.46-7.52 (t, 2H), 7.71-7.74 (d, 4H) Scheme 2.
Online since: August 2017
Authors: Denise Bevilaqua, Assis Vicente Benedetti, Fabiana Antonia Arena Delfino
EIS Studies of Chalcopyrite Involving Iron(II) Ions
Fabiana Antonia Arena Delfino1,a, Denise Bevilaqua1,b
and Assis Vicente Benedetti1,c*
1São Paulo State University UNESP, Institute of Chemistry, Post Box 355,
14801-970, Araraquara, SP, Brazil
afantoniaarena@gmail.com, bdenise@iq.unesp.br, cbenedeti@iq.unesp.br
Keywords: chalcopyrite, redox potential, bioleaching, electrochemical impedance spectroscopy.
These phases also can be formed when a potential imposed to the system causes the reduction of chalcopyrite, which allows the extraction of iron from the crystalline structure, forming copper sulfides that are more susceptible to oxidative leaching.
These phases also can be formed when a potential imposed to the system causes the reduction of chalcopyrite, which allows the extraction of iron from the crystalline structure, forming copper sulfides that are more susceptible to oxidative leaching.
Online since: December 2008
Authors: Do Kyung Kim, Seung Jun Lee
Oxidation of three samples at 1500 °C for 30 min in air produced structures that consist of three
layers: (1) surface silica-rich layer, (2) a SiC-depleted layer, and (3) un-reacted layer.
Vogel: Glass Chemistry (Springer-Verlag, NewTock, 1994) [8] A.
Vogel: Glass Chemistry (Springer-Verlag, NewTock, 1994) [8] A.
Online since: January 2004
Authors: Yukio Toya, Yasushi Kino, Hiroshi Kudo
Journal Citation (to be inserted by the publisher)
Copyright by Trans Tech Publications
Positron Annihilation in Resonant States of the He2+
+ e + e
+ System
Yukio TOYA
1,2
, Yasushi KINO1 and Hiroshi KUDO
1
1
Department of Chemistry, Tohoku University, Sendai 980-8578, Japan
2
Advanced Photon Research Center, JAERI, Kizu 619-0215, Japan
Keywords: Resonant state, positron annihilation, positronic atom, few-body calculation.
The annihilation rate in au is given by 4�� 3 �� 4.89 ×10 6� for the singlet spin state of positron-electron system, and 16(� 2 9)� 4 � 9 � 4.39×10 9� for the triplet spin state, where �� 1 137 is the fine structure constant and 1 au ?
The annihilation rate in au is given by 4�� 3 �� 4.89 ×10 6� for the singlet spin state of positron-electron system, and 16(� 2 9)� 4 � 9 � 4.39×10 9� for the triplet spin state, where �� 1 137 is the fine structure constant and 1 au ?
Online since: January 2013
Authors: Peng Li, Xin Min Huang, Yu Cheng Wu, Wei Zhang, Yong Jiu Zhao, Guang Qing Xu, Kang Xu, Peng Jie Zhang
Reported that the Au NWs depends not on the pore diameter of the template,but on the electrodeposition conditions[7].The regular hexagonally of AAO template and the fine structure of the NWs are clearly visible in the high-magnification.
Materials Chemistry and Physics. 91 (2005) 417 [17] Jiewu Cui, Yucheng Wu.
Materials Chemistry and Physics. 91 (2005) 417 [17] Jiewu Cui, Yucheng Wu.