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Online since: October 2013
Authors: Jian Jun Yang, Zhi Lai Jin, Jia Nan Zhang, Qing Yun Wu, Ming Yuan Wu
Synthesis and Characterization of Alcohol Soluble Acrylate-Polyurethane Adhesive for Low Surface Energy Substrate
Jianjun Yanga, Zhilai Jinb , Jianan Zhangc, Qingyun Wud and Mingyuan Wue
School of Chemistry and Chemical Engineering of Anhui University & the Key Laboratory of Environment-friendly Polymer Materials of Anhui Province, Hefei 230601, China
a andayjj@163.com, b jinzl@163.com, c jianan@mail.ustc.edu.cn,
d wuqingyun1978@yahoo.com.cn, e wumy2003@sina.com
Keywords: Alcohol-soluble, Acrylate, Polyurethane, Adhesive.
In free radical polymerization, the properties and structure of polymer can be affected by reaction temperature, so it is very important to select a proper reaction temperature.
Structure of the PU and PUA.
This behavior can be attributed to the presence of stronger interactions between the PU and the acrylic chain such as H-bonds and the cross-linking structure which can improve the decomposition temperature in low temperature area.
The structure was determined by IR.
In free radical polymerization, the properties and structure of polymer can be affected by reaction temperature, so it is very important to select a proper reaction temperature.
Structure of the PU and PUA.
This behavior can be attributed to the presence of stronger interactions between the PU and the acrylic chain such as H-bonds and the cross-linking structure which can improve the decomposition temperature in low temperature area.
The structure was determined by IR.
Online since: October 2010
Authors: Maurizio Vedani, Stefano P. Trasatti, Dario Gastaldi, Valentina Sassi, Lorenza Petrini, Francesco Migliavacca
Continuum damage model for biodegradable Magnesium alloy stent
Dario Gastaldi1, a, Valentina Sassi1, Lorenza Petrini1, Maurizio Vedani2,
Stefano Trasatti3, Francesco Migliavacca1
1
Laboratory of Biological Structure Mechanics (LaBS) Department of Structural Engineering,
Politecnico di Milano piazza Leonardo da Vinci 32, 20133, Milano, Italy.
2
Dept. of Mechanical Engineering, Politecnico di Milano, Italy
3
Dept. of Physical Chemistry and Electrochemistry, University of Milan, Italy
a
dario.gastaldi@polimi.it
Keywords: Bioresorbable stent, damage model, Magnesium alloy, Metallic biomaterials.
A biodegradable device structure is simulated using ABAQUS/Explicit with the aim of showing the capabilities of the developed corrosion model.
The results show that, when increasing the R value, the complete damage for the structure is reached for lower specific mass loss (i.e. a more localized corrosive attack).
[5] Bolotin V.V., Shipkov A.A. 2001, Mechanical aspects of corrosion fatigue and stress corrosion cracking, International Journal of Solids and Structures, 38, 7297-7318
A biodegradable device structure is simulated using ABAQUS/Explicit with the aim of showing the capabilities of the developed corrosion model.
The results show that, when increasing the R value, the complete damage for the structure is reached for lower specific mass loss (i.e. a more localized corrosive attack).
[5] Bolotin V.V., Shipkov A.A. 2001, Mechanical aspects of corrosion fatigue and stress corrosion cracking, International Journal of Solids and Structures, 38, 7297-7318
Online since: October 2013
Authors: Sheng Qin, Hong Zhou Zhang, Xiao Jiang Cai, Shu Han, Ming Chen, Qing Long An
As one of the most used composite materials, carbon fiber reinforced plastics (CFRP) has advantages like low density, high strength, high stiffness, great resistance to corrosion, etc.[1, 2], which makes it an excellent structural material to fabricate components in fields such as aircraft, aerospace, chemistry equipments, marine and sports [1-4].
In order to assemble composite laminates together or with other metal structures, making holes by various drilling processes on CFRP accounts for the main machining tasks.
Except for coatings, the two tools are of the same structure and geometry parameters.
Cong: Composite Structures. 94 (2012), p 1265-1279
Ahmadi: Composite Structures. 98 (2013) 59-68
In order to assemble composite laminates together or with other metal structures, making holes by various drilling processes on CFRP accounts for the main machining tasks.
Except for coatings, the two tools are of the same structure and geometry parameters.
Cong: Composite Structures. 94 (2012), p 1265-1279
Ahmadi: Composite Structures. 98 (2013) 59-68
Online since: July 2020
Authors: Zheng Gu, Guo Jun Song, Pei Yao Li, Huan Peng Liu, Li Wang
Charaterization and Preparation of PA6/EPDM-g-MAH/OMMT Polymer Alloys Nanocomposites
Huanpeng Liu1,2,a, Peiyao Li3,b, Zheng Gu1,2*, Li Wang2, GuoJun Song3,c
1School of Chemistry and Chemical Engineering, Qingdao University, Shandong, China 266071
2Weihai Innovation Institute, Qingdao University, Shandong, China 264200
3School of Materials Science and Engineering, Qingdao University, Shandong, China 266071
a2307419422@qq.com, bpolymerlpy@163.com, csongguojunqdu@126.com, *guzheng596@163.com
Keywords: PA6; EPDM; OMMT; Nanocomposites; Mechanical Properties
Abstract.
It was the materials’ structure defects and made the tensile property declines.
The reason for the increase of the flexural strength and flexural modulus was that OMMT layers dispersed in the polymer matrix and montmorillonite’s special layer structure had the ability of supporting the space.
The reason was that the OMMT layer was a kind of high intensity inorganic layer structure which had great resistance to effected of heat compared with organic polymer.
The crystallite on the structure was not completed and its melting point and density was low that restrained the crystallization and made the crystallinity declined.
It was the materials’ structure defects and made the tensile property declines.
The reason for the increase of the flexural strength and flexural modulus was that OMMT layers dispersed in the polymer matrix and montmorillonite’s special layer structure had the ability of supporting the space.
The reason was that the OMMT layer was a kind of high intensity inorganic layer structure which had great resistance to effected of heat compared with organic polymer.
The crystallite on the structure was not completed and its melting point and density was low that restrained the crystallization and made the crystallinity declined.
Online since: March 2017
Authors: Shi Su, Li Tao Sun, Jiang Ling Li, Heng Chang Bi, Shu Wan, Lei Zhou, Qing Ma
In the first step a ladder structure was formed; therefore, the chain scission and relaxation could be avoided during the subsequent carbonization step [17].
Comparing with recent report, the PAN nanofiber membrane has a better performance on filtration efficiency because of its uniform morphology, consistent diameter distribution and ordered structure in a thin layer [9].
For future investigations, a deposition on fabric materials will be a feasible approach to provide a sustain structure, and then for large area coverage applications.
Future research will focus on its combination with sustain structures, as well as other advanced materials.
Zheng, The ion chemistry and the source of PM2.5 aerosol in Beijing, Atmos.
Comparing with recent report, the PAN nanofiber membrane has a better performance on filtration efficiency because of its uniform morphology, consistent diameter distribution and ordered structure in a thin layer [9].
For future investigations, a deposition on fabric materials will be a feasible approach to provide a sustain structure, and then for large area coverage applications.
Future research will focus on its combination with sustain structures, as well as other advanced materials.
Zheng, The ion chemistry and the source of PM2.5 aerosol in Beijing, Atmos.
Online since: March 2024
Authors: Persia Ada N. de Yro, Rohit C. Tilwani, Kirsten Noelle Anastasia K. Calimon
In recent years, there has been growing interest in the development of hydrogels with improved qualities and functionalities by incorporating nanomaterials into their structure.
Morphological Structure Analysis.
The BCF from corn husk has a structure that resembles cotton, and as a result, it produced a white suspension of cellulose nanospheres.
Since cellulose II has a thermally stable crystal structure [3], eliminating amorphous areas would increase cellulose's resistance to heat.
Materials Today Chemistry, 23, 100746. https://doi.org/10.1016/j.mtchem.2021.100746 [3] Romruen, O.; Kaewprachu, P.; Karbowiak, T.; Rawdkuen, S.
Morphological Structure Analysis.
The BCF from corn husk has a structure that resembles cotton, and as a result, it produced a white suspension of cellulose nanospheres.
Since cellulose II has a thermally stable crystal structure [3], eliminating amorphous areas would increase cellulose's resistance to heat.
Materials Today Chemistry, 23, 100746. https://doi.org/10.1016/j.mtchem.2021.100746 [3] Romruen, O.; Kaewprachu, P.; Karbowiak, T.; Rawdkuen, S.
Online since: April 2014
Authors: Dmytro Ostroushko, Eva Mazancová
The studied bimetal could find application in heavy chemistry, energetics and also in geothermal one with possible hydrogen appearance.
The total CSR parameters are approximately at the same level and the worst level showed 99.5% reserve. 50 mm Fig. 4 Bimetal interface after the HIC exposition a) general view (Ti above), b) in detail Fig. 4 shows the chosen micro-structure of the welded 304 SS steel with Ti after exposition in corrosion solution.
On the contrary, a lot of deformation bands and ultrafine grains of both micro-structures in the vicinity of the interface as a consequence of strong deformation caused by explosive welding represent numerous potential traps for more uniform hydrogen redistribution and so better conditions for the more favourable hydrogen resistance [5, 6, 10].
Madhusudhan, Influence of hot rolling and heat treatmenton structure and properties of HSLA steel explosively clad with austenitic stainless steel, Mater.
Salishczev, Influence of grain size and micro-structure homogeneity on the deformation uniformity of commertiallypure titanium (in Russian), Fiz.
The total CSR parameters are approximately at the same level and the worst level showed 99.5% reserve. 50 mm Fig. 4 Bimetal interface after the HIC exposition a) general view (Ti above), b) in detail Fig. 4 shows the chosen micro-structure of the welded 304 SS steel with Ti after exposition in corrosion solution.
On the contrary, a lot of deformation bands and ultrafine grains of both micro-structures in the vicinity of the interface as a consequence of strong deformation caused by explosive welding represent numerous potential traps for more uniform hydrogen redistribution and so better conditions for the more favourable hydrogen resistance [5, 6, 10].
Madhusudhan, Influence of hot rolling and heat treatmenton structure and properties of HSLA steel explosively clad with austenitic stainless steel, Mater.
Salishczev, Influence of grain size and micro-structure homogeneity on the deformation uniformity of commertiallypure titanium (in Russian), Fiz.
Online since: August 2019
Authors: Zhi Guo Wang, Xiao Li Sun
Single-layer MoS2 is with honeycomb atomic structure, and has been synthesized through different strategies [1-6].
And in past work, we have calculated the Li adsorption and diffusion energy in the structure that nonmetal replace S and metal replace Mo.
(a) shown, the adsorbed Li atom on the pristine MoS2 single-layer do not alter band gap and the band structure near band edge, but the position of Fermi energy level moves into the conduction band.
[3] Lauritsen, J.V., et al., Size-dependent structure of MoS2 nanocrystals.
Theoretical Chemistry Accounts, 2011. 130(2-3): p. 209-213
And in past work, we have calculated the Li adsorption and diffusion energy in the structure that nonmetal replace S and metal replace Mo.
(a) shown, the adsorbed Li atom on the pristine MoS2 single-layer do not alter band gap and the band structure near band edge, but the position of Fermi energy level moves into the conduction band.
[3] Lauritsen, J.V., et al., Size-dependent structure of MoS2 nanocrystals.
Theoretical Chemistry Accounts, 2011. 130(2-3): p. 209-213
Online since: October 2015
Authors: Sergey V. Gnedenkov, Dmitry V. Mashtalyar, Sergey L. Sinebryukhov, Artyom М. Puz', Natalya G. Plekhova
Plekhova2, e
1Institute of Chemistry, Far-Eastern Branch, Russian Academy of Sciences, 159 pr. 100-letiya
Vladivostoka, Vladivostok 690022, Russia
2Pacific State Medical University, pr.
To study the cells structure in the course of their interaction with samples, a complex fixator was used. 1 % solution of OsO4 (Serva) was used for extra fixation, dehydration was carried out in acetone with increasing concentration according to the method of treatment of cell cultures for scanning electron microscopy [16].
Gong, Phase stability, mechanical property, and electronic structure of an Mg–Ca system, J.
Bouznik, The structures of polytetrafluoroethylene forms modified by various methods, J.P.C.S. 68 (2007) 1106-1111
Tsvetnikov, A crystal structure of ultra-dispersed form of polytetrafluoroethylene based on X-ray powder diffraction data, Powder Diffr. (19) 2004 219–224
To study the cells structure in the course of their interaction with samples, a complex fixator was used. 1 % solution of OsO4 (Serva) was used for extra fixation, dehydration was carried out in acetone with increasing concentration according to the method of treatment of cell cultures for scanning electron microscopy [16].
Gong, Phase stability, mechanical property, and electronic structure of an Mg–Ca system, J.
Bouznik, The structures of polytetrafluoroethylene forms modified by various methods, J.P.C.S. 68 (2007) 1106-1111
Tsvetnikov, A crystal structure of ultra-dispersed form of polytetrafluoroethylene based on X-ray powder diffraction data, Powder Diffr. (19) 2004 219–224
Online since: June 2011
Authors: Zhe Yi Meng, Chang Jian Xiong, Zeng Hua Chang, Yue Lin Zhu
The performance study of aviation fuel added with alcohols
Yuelin Zhu1, a, Zheyi Meng1, b, Zenghua Chang1, c and Changjian Xiong2, d
1 Key Laboratory of Aerospace Materials and Performance (Ministry of Education),
School of Materials Science and Engineering, Beihang University, Beijing 100191, China
2 Center of Materials Physics and Chemistry, Beihang University, Beijing 100191,China
aylzhu@buaa.edu.cn, bjeromemeng@126.com, cjiayufly@126.com, dxchj@buaa.edu.cn
Keywords: alcohol; clean jet fuel; compatibility to rubbers; corrosiveness to copper.
In a deeper view from molecular structure, the silicone rubber used in this paper is mainly methyl vinyl silicone rubber, whose chain is mainly composed of Si-O bond (as it shown in Figure 3).
Therefore, the length of the structure unit in silicone-rubber is longer than that of fluorine rubber.
Structure of silicone rubber and fluorine rubber For silicone rubber that after soaking in fuels mixed with ethanol, propanol and n-butanol, the mass changes significantly than that soaked in RP-3 jet kerosene, for the molecules of the three alcohols are relatively small, thus tend to hide in the gaps in the structure of silicone rubber.
In a deeper view from molecular structure, the silicone rubber used in this paper is mainly methyl vinyl silicone rubber, whose chain is mainly composed of Si-O bond (as it shown in Figure 3).
Therefore, the length of the structure unit in silicone-rubber is longer than that of fluorine rubber.
Structure of silicone rubber and fluorine rubber For silicone rubber that after soaking in fuels mixed with ethanol, propanol and n-butanol, the mass changes significantly than that soaked in RP-3 jet kerosene, for the molecules of the three alcohols are relatively small, thus tend to hide in the gaps in the structure of silicone rubber.