Composite Calcium Phosphate Coatings on Mg Alloy for Medicine

Article Preview

Abstract:

The high-tech method of creating anticorrosion calcium phosphate coating on the magnesium alloy MA8 (MgMnCe) has been developed. As was demonstrated by the volumetry method the sealing of the layer formed on the surface of Mg alloy using plasma electrolytic oxidation by superdispersed polytetrafluoroethylene substantially reduced the rate of the corrosion process. Here, the surface of the calcium phosphate layer containing hydroxyapatite (Ca/P = 1.61) remains biologically active. Studies of architectonics of the surface of innate immune cells have been performed in vitro.

You might also be interested in these eBooks

Info:

Periodical:

Solid State Phenomena (Volume 245)

Pages:

159-165

Citation:

Online since:

October 2015

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2016 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] F. Witte, The history of biodegradable magnesium implants: A review / Acta Biomater. 6 (2010) 1680-1692.

Google Scholar

[2] P. Zhou, HR. Gong, Phase stability, mechanical property, and electronic structure of an Mg–Ca system, J. Mech. Behav. Biomed. 8 (2012) 154–164.

Google Scholar

[3] V.V. Troitskii, D.N. Tsitrin, The resorbing metallic alloy Osteosinthezit, as material for fastening broken bone. Khirurgiia. 8 (1944) 41–44.

Google Scholar

[4] E.D. McBride, Absorbable metal in bone surgery. J. Am. Med. Assoc. 111 (1938) 2464–7.

Google Scholar

[5] F. Witte, V. Kaese, H. Haferkamp, E. Switzer, A. Meyer-Lindenberg, C.J. Wirth, et al. In vivo corrosion of four magnesium alloys and the associated bone response, Biomaterials. 26 (2005) 3557–63.

DOI: 10.1016/j.biomaterials.2004.09.049

Google Scholar

[6] H.R. Bakhsheshi-Rad, M.H. Idris, M.R. Abdul-Kadir, A. Ourdjini, M. Medraj, M. Daroonparvar, E. Hamzah, Mechanical and bio-corrosion properties of quaternary Mg–Ca Mn–Zn alloys compared with binary Mg–Ca alloys, Mater. Des. 53 (2014) 283-292.

DOI: 10.1016/j.matdes.2013.06.055

Google Scholar

[7] Z. Li, X. Gu, S. Lou, Y. Zheng, The development of binary Mg–Ca alloys for use as biodegradable materials within bone, Biomaterials. 29 (2008) 1329-1344.

DOI: 10.1016/j.biomaterials.2007.12.021

Google Scholar

[8] H.R. Bakhsheshi-Rad, M.H. Idris, M.R. Abdul-Kadir, S. Farahany, Microstructure analysis and corrosion behavior of biodegradable Mg–Ca implant alloys, Mater. Des. 33 (2012) 88-97.

DOI: 10.1016/j.matdes.2011.06.057

Google Scholar

[9] S. Hiromoto, A. Yamamoto, Control of degradation rate of bioabsorbable magnesium by anodization and steam treatment, Mater. Sci. Eng. 30 (2010) 1085– 1093.

DOI: 10.1016/j.msec.2010.06.001

Google Scholar

[10] P.B. Srinivasan, J. Liang, C. Blawert, M. Stormer, W. Dietzel, A preliminary study of calcium containing plasma electrolytic oxidation coatings on AM50 magnesium alloy, J. Mater. Sci. 45 (2010) 1406–1410.

DOI: 10.1007/s10853-009-4093-4

Google Scholar

[11] J. Gao, X. Shi, B. Yang, S. Hou, E. Meng, F. Guan, S. Guan, Fabrication and characterization of bioactive composite coatings on Mg–Zn–Ca alloy by MAO/sol–gel J. Mater. Sci. Mater. Med. 22 (2011) 1681–1687.

DOI: 10.1007/s10856-011-4349-9

Google Scholar

[12] L. Ignatieva, V. Kuryaviy, A. Tsvetnikov, S. Pyatov, S. Polyshchuk, V. Bouznik, The structures of polytetrafluoroethylene forms modified by various methods, J.P.C.S. 68 (2007) 1106-1111.

DOI: 10.1016/j.jpcs.2007.02.004

Google Scholar

[13] V.M. Bouznik, S.D. Kirik, L.A. Solovyov, A.K. Tsvetnikov, A crystal structure of ultra-dispersed form of polytetrafluoroethylene based on X-ray powder diffraction data, Powder Diffr. (19) 2004 219–224.

DOI: 10.1154/1.1707037

Google Scholar

[14] L.N. Ignatieva, A.K. Tsvetnikov, O.N. Gorbenko, T.A. Kaidalova, V.M. Buznik, Spectroscopic investigation of sublimated products of ultradisperse polytetrafluoroethylene, J. Struct. Chem. 45 (2004) 786–792.

DOI: 10.1007/s10947-005-0059-9

Google Scholar

[15] L.M. Somova, N.V. Krylova, G.N. Leonova, I.N. Lyapun, I.S. Smirnov, Biochemical markers of virus cytopathogenicity in macrophages, Appl. Biochem. and Microbiol. 49 (2013) 64-73.

DOI: 10.1134/s0003683813010158

Google Scholar

[16] Yu.A. Rovensky, Raster electron microscopy of normal and tumor cells, Meditsina, Moscow, 1979. 180 p. [In Russian].

Google Scholar

[17] S.V. Dorozhkin, M. Epple, Biological and medical significance of calcium phosphates, Angew. Chem. 114 (2002) 3260–3277.

Google Scholar

[18] S.V. Gnedenkov, S.L. Sinebryukhov, D.V. Mashtalyar, V.S. Egorkin, M.V. Sidorova, A.S. Gnedenkov, Composite polymer-containing protective coatings on magnesium alloy MA8, Corros. Sci. 85 (2014) 52–59.

DOI: 10.1016/j.corsci.2014.03.035

Google Scholar

[19] S.V. Gnedenkov, Yu.P. Scharkeev, S.L. Sinebryukhov, O.A. Khrisanfova, E.V. Legostaeva, A.G. Zavidnaya, A.V. Puz', I.A. Khlusov, Formation and properties of bioactive surface layers on titanium, Inor. Mater. App. Res. 2 (2011) 474–481.

DOI: 10.1134/s2075113311050133

Google Scholar

[20] A.G. Rakoch, I.V. Bardin, Corrosion- and thermal-resistant materials: corrosion resistance of light construction alloys in diferent media, MISiS, Moscow, 2011. 78 p. [In Russian].

Google Scholar

[21] S.V. Gnedenkov, S.L. Sinebryukhov, A.G. Zavidnaya, V.S. Egorkin, A.V. Puz', D.V. Mashtalyar, V.I. Sergienko, A.L. Yerokhin, A. Matthews, Composite hydroxyapatite-PTFE coatings on Mg-Mn-Ce alloy for resorbable implant applications via a plasma electrolytic oxidation-based route, J. Taiwan Inst. Chem. Eng. 45 (2014).

DOI: 10.1016/j.jtice.2014.03.022

Google Scholar