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Online since: June 2015
Authors: Ana Cristina Figueiredo de Melo Costa, Polyana T.A. Santos, Pascally M.A.G. Araújo, Patrícia T.A. Santos
The obtained hybrid films Qs/NPs were analyzed about structure by X-ray diffraction (XRD) in equipment LAB X-ray Difractometer 6000 Shimadzu with scanning of 5 to 75° 2θ, using a speed of 2°.min-1 and radiation CuKα (λ = 1.5418 Å), with voltage and current of 35 kV and 15 mA, respectively.
These groups are linked to the methylenes radicals of the structure Qs and they indicate that Qs is not 100% deacetylated, but also bands (C-H) are related to the methylene groups (CH2) of the silane agent.
And for the hybrid films NPs/Qs besides the charge transfer from Al3+ to O2- it may also involve the broad band to the transitions of the Qs as well as to defects present in the spinel structure of ZnAl2O4.
Zhai: Journal of Physics and Chemistry of Solids Vol. 74 (2013), p. 1131
These groups are linked to the methylenes radicals of the structure Qs and they indicate that Qs is not 100% deacetylated, but also bands (C-H) are related to the methylene groups (CH2) of the silane agent.
And for the hybrid films NPs/Qs besides the charge transfer from Al3+ to O2- it may also involve the broad band to the transitions of the Qs as well as to defects present in the spinel structure of ZnAl2O4.
Zhai: Journal of Physics and Chemistry of Solids Vol. 74 (2013), p. 1131
Online since: June 2022
Authors: Hui Wang, Yan Bai, Dong Xu Shao
Nano montmorillonite (MMT) is a kind of clay with unique layered one-dimensional nano-structure, with super large specific surface area and diameter/thickness ratio of more than 200.
According to the mechanism of MMT stabilizing Pickering emulsion, MMT can adsorb at the oil water interface to form a surface film under the action of surface hydrophilicity, and can be distributed in the continuous phase to form a three-dimensional network structure to prevent the agglomeration between droplets and maintain the stability of the emulsion.
In the Pickering emulsion, with the increase of MMT addition, the distribution of MMT at the oil-water interface of emulsion increased and MMT formed a more stable solid interfacial film and three-dimensional space network structure.
Food Chemistry, 306(2020):125628
According to the mechanism of MMT stabilizing Pickering emulsion, MMT can adsorb at the oil water interface to form a surface film under the action of surface hydrophilicity, and can be distributed in the continuous phase to form a three-dimensional network structure to prevent the agglomeration between droplets and maintain the stability of the emulsion.
In the Pickering emulsion, with the increase of MMT addition, the distribution of MMT at the oil-water interface of emulsion increased and MMT formed a more stable solid interfacial film and three-dimensional space network structure.
Food Chemistry, 306(2020):125628
Online since: May 2023
Authors: John Ryan C. Dizon, Ray Noel M. Delda, Juvy J. Monserate, Madelene V. Villablanca, Lina T. Cancino, Honelly Mae S. Cascolan
In case of failure in printing, the non-formation of the samples can be attributed to the changes in the viscosity of the resin that happens when it goes back to the steady-state value which means that a restructuring to the original disorganized structure of the nanoparticles has been initiated.
Likewise, 3D printing technology has great flexibility in terms of structure design in which the application of materials can be expanded significantly in different fields [25].
In Woodhead Publishing Series in Composites Science and Engineering, Structure and Properties of Additive Manufactured Polymer Components, Woodhead Publishing, Elsevier Inc., 2020
Sajjad et al., Study of the effect of the concentration, size and surface chemistry of zirconia and silica nanoparticle fillers within an epoxy resin on the bulk properties of the resulting nanocomposites, Polym.
Likewise, 3D printing technology has great flexibility in terms of structure design in which the application of materials can be expanded significantly in different fields [25].
In Woodhead Publishing Series in Composites Science and Engineering, Structure and Properties of Additive Manufactured Polymer Components, Woodhead Publishing, Elsevier Inc., 2020
Sajjad et al., Study of the effect of the concentration, size and surface chemistry of zirconia and silica nanoparticle fillers within an epoxy resin on the bulk properties of the resulting nanocomposites, Polym.
Online since: February 2024
Authors: Victor Sunday Aigbodion, Paul Amaechi Ozor, Nkiruka Eveth Nwobodo-Anyadiegwu
Results and Discussion
The AgNPs size and structure were determined via TEM examination.
The reduction in thermal conductivity with temperature can be attributed to the fact that temperature altered the original crystal structure of the materials and expose more free electrons and phonons to conduction.
Fig.5a. presents abundant evidence of large grain boundaries in the α-Al structure.
The Journal of Physical Chemistry B 105, (2001), 1157-1161 [7] C.O.
The reduction in thermal conductivity with temperature can be attributed to the fact that temperature altered the original crystal structure of the materials and expose more free electrons and phonons to conduction.
Fig.5a. presents abundant evidence of large grain boundaries in the α-Al structure.
The Journal of Physical Chemistry B 105, (2001), 1157-1161 [7] C.O.
Online since: October 2020
Authors: Kusmono Kusmono, Muhammad Waziz Wildan, Mochammad Noer Ilman, Dimas Abdillah Akbar
From Fig. 1, it can be seen that both ramie fiber before and after chemical treatment shows some of the same peaks at 3400, 2903, 2368, 1427, 1371, and 897 cm-1, that prove the extraction of NCCs with various acid concentration does not affect the chemical structure of cellulose [7].
The patterns of Fig 2 show a semi crystalline cellulose structure which is in the amorphous phase that is influenced by lignin and hemicellulose.
Chemical pretreatment and hydrolysis do not affect the chemical structure of the samples.
Bhardwaj, Characterization of Cellulose Nanocrystals Produced by Acid-Hydrolysis from Sugarcane Bagasse as Agro-Waste, Journal of Materials Physics and Chemistry 2.1, 2, 1-8 (2014)
The patterns of Fig 2 show a semi crystalline cellulose structure which is in the amorphous phase that is influenced by lignin and hemicellulose.
Chemical pretreatment and hydrolysis do not affect the chemical structure of the samples.
Bhardwaj, Characterization of Cellulose Nanocrystals Produced by Acid-Hydrolysis from Sugarcane Bagasse as Agro-Waste, Journal of Materials Physics and Chemistry 2.1, 2, 1-8 (2014)
Online since: November 2011
Authors: Wei Ping Zhang, Hai Da Liao, Xiao Ming Sun, Jin Fu Qin, Yong Duo Hang
Study on the Preparation and Performance of Epoxy Resin/AlOOH Nano-composite Materials
Liao Haidaa,Zhang Weiping,Sun Xiaoming, Qin Jinfu,Hang Yongduo
College of Chemistry and Ecology Engineering, Guangxi University for Nationalities, Nanning 530006, China
alhd21c@tom.com
Key words: epoxy resin; nano-scale AlOOH; direct blending method; performance of composite material
Abstract: Using laboratory-made nano-scale g–AlOOH as nanophase raw material, the compounding method characterized by direct solution-blending was adopted to prepare epoxy resin/AlOOH nano-composite material; the influences of various factors, such as the dispersion characteristics of nano-scale AlOOH and its content in composite material, on mechanical and flame retardant properties of composite material were studied.
However, due to its highly cross-linked structure, epoxy resin has such weaknesses as strong internal stress, low impact strength and poor toughness, which cannot satisfy the growing requirements of the development of science and technology [1].
This fact could be interpreted as follows: AlOOH could not only be well dispersed in but also had some interaction with the substrate to form the reticular cross linked structure, which to a certain extent inhibited and obstructed both the movement and the energy transmission of polymer chain of the substrate during its heat-induced degradation, improving the compactness and continuity of carbon layer of the remnants formed after the decomposition of composite material through heating.Therefore, the heat transfer was effectively obstructed, and the solid-phase flame retardant function of preventing the ambient air from entering the combustion system and preventing the escape of micro molecular products generated by the decomposition of polymer, with the combustibility of the composite materials being satisfactorily reduced [6].
Thus the remnants formed after the decomposition through heating had loose structure and poor surface continuity with more defects, and had poor blocking effect.
However, due to its highly cross-linked structure, epoxy resin has such weaknesses as strong internal stress, low impact strength and poor toughness, which cannot satisfy the growing requirements of the development of science and technology [1].
This fact could be interpreted as follows: AlOOH could not only be well dispersed in but also had some interaction with the substrate to form the reticular cross linked structure, which to a certain extent inhibited and obstructed both the movement and the energy transmission of polymer chain of the substrate during its heat-induced degradation, improving the compactness and continuity of carbon layer of the remnants formed after the decomposition of composite material through heating.Therefore, the heat transfer was effectively obstructed, and the solid-phase flame retardant function of preventing the ambient air from entering the combustion system and preventing the escape of micro molecular products generated by the decomposition of polymer, with the combustibility of the composite materials being satisfactorily reduced [6].
Thus the remnants formed after the decomposition through heating had loose structure and poor surface continuity with more defects, and had poor blocking effect.
Online since: May 2012
Authors: You Yi Zhu, Yi Zhang, Sheng Wen Wu, Shu Ying Wang
The structure of the TiO2-SnO2 active layer was characterized by SEM (S-570).
The crystalline structure of the electrode coating was determined by D/MAX-2200 X-ray diffractometer.
The characteristic mud-cracked structure is well defined by SEM (Fig. 4) for the Ce doping TiO2-SnO2 electrode prepared.
Materials Chemistry and Physics, 2005, 92(2-3): 559~564
The crystalline structure of the electrode coating was determined by D/MAX-2200 X-ray diffractometer.
The characteristic mud-cracked structure is well defined by SEM (Fig. 4) for the Ce doping TiO2-SnO2 electrode prepared.
Materials Chemistry and Physics, 2005, 92(2-3): 559~564
Functional Characterisations of Hybrid Nanocomposite Films Based on Polyaniline and Carbon Nanotubes
Online since: September 2012
Authors: Daniela Carbone, M. Federica de Riccardis, Paolo Rotolo, V. Martina
Moreover, a small amount of tubular structures, such as carbon nanotubes (CNTs), could assure a mesoporous network that allows an easier diffusion of ions.
The most affirmed theory on the functionalisation of CNTs by means of PANI sustains that theπ-bonded surface of the CNTs (acting as acceptors) interacts strongly with the conjugated structure of PANI (acting as donor), especially through the quinoid ring [8].
The peaks structure conforms to that already proven in literature [3].
Morphology and chemistry of its oxidation and reduction in aqueous electrolytes”, J.
The most affirmed theory on the functionalisation of CNTs by means of PANI sustains that theπ-bonded surface of the CNTs (acting as acceptors) interacts strongly with the conjugated structure of PANI (acting as donor), especially through the quinoid ring [8].
The peaks structure conforms to that already proven in literature [3].
Morphology and chemistry of its oxidation and reduction in aqueous electrolytes”, J.
Online since: June 2010
Authors: Melba Navarro, Josep A. Planell
Each of these components may be assembled in different proportions
creating two different architectural structures depending on the bone type and function.
the size, shape, topography, chemistry, physics and mechanics of the implant; (3) the surgical technique; and (4) systemic factors, e.g. age, sex, general health status.
These phosphate chains and rings may be broken by the incorporation of certain ions, generating non-bridging oxygens in the glass structure.
Knowles JC: Journal of Materials Chemistry Vol. 13 (2003), p. 2395 78.
Aranda: Journal of Materials Chemistry, Vol. 15, (2005), p.3650 124.
the size, shape, topography, chemistry, physics and mechanics of the implant; (3) the surgical technique; and (4) systemic factors, e.g. age, sex, general health status.
These phosphate chains and rings may be broken by the incorporation of certain ions, generating non-bridging oxygens in the glass structure.
Knowles JC: Journal of Materials Chemistry Vol. 13 (2003), p. 2395 78.
Aranda: Journal of Materials Chemistry, Vol. 15, (2005), p.3650 124.
Online since: October 2006
Authors: José Pedro Rino, Denílson S. Borges, Paulo S. Branício
It
should also be able to describe with some accuracy the structures and phases not included in the
fitting data base.
The static structure factor and its dependence with temperature were well described in agreement with experiments.
Sn ( q ) q ( Å -1 ) Figure 3: Neutron scattering static structure factor, Sn(q), of liquid CdTe.
Rhombohedral (RH) symmetry has never been considered as a possible stable structure for this system.
Pauling, The nature of the chemical bond and the structure of molecules and crystals; an introduction to modern structural chemistry (Cornell University Press;H.
The static structure factor and its dependence with temperature were well described in agreement with experiments.
Sn ( q ) q ( Å -1 ) Figure 3: Neutron scattering static structure factor, Sn(q), of liquid CdTe.
Rhombohedral (RH) symmetry has never been considered as a possible stable structure for this system.
Pauling, The nature of the chemical bond and the structure of molecules and crystals; an introduction to modern structural chemistry (Cornell University Press;H.