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Online since: January 2012
Authors: Sheng Hua Lv, Gong Rui, Jing Hu
Meanwhile, the chemistry structure of modified starch was characterized by FTIR, 1H-NMR, 13C-NMR
Introduction
The environmental pollution produced by chrome tannage has been a main problem of restricting of the development of leather industry in recent decades.
The chemical structures of modified starch were characterized by NMR and FTIR.
This hints that the optimizing chemical structure of modified starch was obtained at 85°C.
The structure characterization of modified starch FTIR of modified starch are shown in Fig. 4.
Corke, “Physical properties of octenyl succinic anhydride modified rice, wheat, and potato starches”, Journal of Agricultural and Food Chemistry, vol. 51, no.10, pp. 2283-2287, Novmber 2003
The chemical structures of modified starch were characterized by NMR and FTIR.
This hints that the optimizing chemical structure of modified starch was obtained at 85°C.
The structure characterization of modified starch FTIR of modified starch are shown in Fig. 4.
Corke, “Physical properties of octenyl succinic anhydride modified rice, wheat, and potato starches”, Journal of Agricultural and Food Chemistry, vol. 51, no.10, pp. 2283-2287, Novmber 2003
Online since: April 2014
Authors: Jing Li, Feng Du, Xian Li Liu, Cheng Yu Xu, Hua Dong Yu
SEM Images ((a) grid-like structure and (b) corresponding Magnified structure) of the Lower Surface of the Lotus Leaf
Figure2.
Such micro-sized uniformly distributed granule structure can be regarded to be similar to the surface unitary structure observed on the lower surface of lotus leaves.
Such unitary structure surface shows feeblish hydrophobicity.
Liu, Biomimic from the superhydrophobic plant leaves in nature: binary structure and unitary structure, Plant.
[11] Z G Guo, W M Liu, Progress in Biomimicing of Super-Hydrophobic Surface, Progress in Chemistry. 18(2006)721-726
Such micro-sized uniformly distributed granule structure can be regarded to be similar to the surface unitary structure observed on the lower surface of lotus leaves.
Such unitary structure surface shows feeblish hydrophobicity.
Liu, Biomimic from the superhydrophobic plant leaves in nature: binary structure and unitary structure, Plant.
[11] Z G Guo, W M Liu, Progress in Biomimicing of Super-Hydrophobic Surface, Progress in Chemistry. 18(2006)721-726
Online since: March 2012
Authors: Datchanee Kraisiri, Nuanphun Chantarasiri, Vimolvan Pimpan
Fluorescent compounds generally compose of the chemical structure having conjugated double bond such as aromatic ring.
These results indicate the difference in the chemical structures of the monomer and its macromer.
The chemical structure of this molecule was characterized by 1H-NMR spectroscopy and the spectra of the monomer and its macromer are shown in Figure 3.
The number of protons present in the macromer structure was determined by comparing well-defined peak integrals between those assigned to the monomer and its macromer.
Two monomer radicals then combine to form the following dimeric structure.
These results indicate the difference in the chemical structures of the monomer and its macromer.
The chemical structure of this molecule was characterized by 1H-NMR spectroscopy and the spectra of the monomer and its macromer are shown in Figure 3.
The number of protons present in the macromer structure was determined by comparing well-defined peak integrals between those assigned to the monomer and its macromer.
Two monomer radicals then combine to form the following dimeric structure.
Online since: June 2025
Authors: Thitiphan Chimsook
Beta-Cyclodextrin-Maltodextrin Inclusion Complex of Lavender Oil: Preparation and Physical Properties
T Chimsook1
1Faculty of Science, Program of Chemistry, Program of Applied Chemistry, Maejo University, Chiang Mai, Thailand 50290
Corresponding author: pitiporn@mju.ac.th
Keywords: Lavender oil, Inclusion complexes, Cyclodextrin
Abstract.
Moreover, changes in crystal structure before and after microencapsulation were assessed using X-ray diffraction (XRD) with Cu-K𝛼 radiation at 40 kV and 40 mA.
All the diffraction lines could be indexed to beta cyclodextrin decahydrate (JCPDS card 00-054-1476) with a monoclinic structure.
This indicated a structural transition in 𝛽-CD from a cage-type to a channel-type structure during microencapsulation.
Acknowledgement The authors would like to thank Thailand Science Research and Innovation and Fundamental Fund, Agri Inno., Program of Applied Chemistry, Chemistry, Faculty of Science, Maejo University for scholarship, financial support and facilities.
Moreover, changes in crystal structure before and after microencapsulation were assessed using X-ray diffraction (XRD) with Cu-K𝛼 radiation at 40 kV and 40 mA.
All the diffraction lines could be indexed to beta cyclodextrin decahydrate (JCPDS card 00-054-1476) with a monoclinic structure.
This indicated a structural transition in 𝛽-CD from a cage-type to a channel-type structure during microencapsulation.
Acknowledgement The authors would like to thank Thailand Science Research and Innovation and Fundamental Fund, Agri Inno., Program of Applied Chemistry, Chemistry, Faculty of Science, Maejo University for scholarship, financial support and facilities.
Online since: March 2013
Authors: Lin Zhang, Jin Feng Xia, Cai Xia Li, Qiang Li, Danyu Jiang, Jun Guo
Layered structures of these compounds have their peculiarities, which are of a special kind of nano-structured, thus, they provide a new way of thinking for the synthesis of new nano-layered structure of compounds.
The detailed structure of FeOCl was reported by Lind,' confirming the earlier work of Goldsztaub., The unit cell parameters are a = 378.0, b = 791.7, and c = 330.2 pm.
The structure consists of a corrugated (in two dimensions) iron-oxygen framework sandwiched between planes of chlorine atoms to form one layer of the lamellar material.
Structure Characteristics.
Renzhi, Colloidal unilamellar layers of tantalum oxide with open channels,Inorganic Chemistry. 46(2007)4787-4789
The detailed structure of FeOCl was reported by Lind,' confirming the earlier work of Goldsztaub., The unit cell parameters are a = 378.0, b = 791.7, and c = 330.2 pm.
The structure consists of a corrugated (in two dimensions) iron-oxygen framework sandwiched between planes of chlorine atoms to form one layer of the lamellar material.
Structure Characteristics.
Renzhi, Colloidal unilamellar layers of tantalum oxide with open channels,Inorganic Chemistry. 46(2007)4787-4789
Online since: January 2012
Authors: Dun Wan, Li Fu Liao, Ying Wu Lin
Impacts of Uranyl Ion on the Structure and Function of Cytochrome b5 His39Ser Mutant
Dun Wan, Li-fu Liao and Ying-Wu Lin*
School of Chemistry and Chemical Engineering, University of South China, Hengyang 421001, China
linlinying@hotmail.com
Keywords: Uranium; Heme proteins; Metal-binding site; modeling; Toxicity.
Molecular modeling study The structure of cyt b5 H39S was modeled based on the crystal structure of bovine liver microsomal cyt b5 (PDB entry 1CYO) [12], using a procedure similar to previous modeling cyt c axial mutants [13].
The modeling structure was analyzed using VMD 1.8.7 (Visual Molecular Dynamics) [16].
“Uranium(VI) bio-coordination chemistry from biochemical, solution and protein structural data”, Coord.
“The structure, function and evolution of cytochromes”, Prog.
Molecular modeling study The structure of cyt b5 H39S was modeled based on the crystal structure of bovine liver microsomal cyt b5 (PDB entry 1CYO) [12], using a procedure similar to previous modeling cyt c axial mutants [13].
The modeling structure was analyzed using VMD 1.8.7 (Visual Molecular Dynamics) [16].
“Uranium(VI) bio-coordination chemistry from biochemical, solution and protein structural data”, Coord.
“The structure, function and evolution of cytochromes”, Prog.
Online since: June 2014
Authors: Jun Shen, Jia Wen Wu, Lan Fang Yao, Guo Qing Zu, Fang Wang
The structure and properties of the magnesium-based aerogels were featured by TEM, XRD and BET.
These nanoscale materials exhibit unusual surface chemistry and catalytic properties and, compared to other MgO samples, are more chemically reactive.
Because it will destroy Mg(OH)2 aerogel’s porous structure.
After 500℃ heat treatment by 4 hours, the magnesium aerogel remains its interconnected network structure.
Effects of Toluene on Gel Structure and Gel Chemistry, Chem.
These nanoscale materials exhibit unusual surface chemistry and catalytic properties and, compared to other MgO samples, are more chemically reactive.
Because it will destroy Mg(OH)2 aerogel’s porous structure.
After 500℃ heat treatment by 4 hours, the magnesium aerogel remains its interconnected network structure.
Effects of Toluene on Gel Structure and Gel Chemistry, Chem.
Online since: August 2012
Authors: Jing Yin Gao, Jian Gong Cai, Pin Lu, Ze Min Chen
It showed the crystalline structure in the scanning electron microscope, then preliminary analysis the mechanism on this based.
Fig.1(b) was the blackening film morphology map which was amplified 30000×, and we can see that the blackening film has reticular structure, dispersed.
XRD spectra of the blackening films In order to determine the phase of the blackening films structure, use TD-3000 X-ray diffraction to analysis.
Fig.3 XRD of the blackening film The XRD patterns in Fig.3 showed that the the blackening film was polycrystalline composite coating, which were composited with face-centered lattice structure of elemental antimony that was deposited on the metal surface and a small amount of body-centered cubic lattice structure of Al2O3·2SiO2·3H2O.
The analysis of the blackening film by SEM, XPS, XRD showed that the conversion film was composite crystalline film which was formed by elemental antimony (face centered orthorhombic lattice structure) and a small amount of Al2O3·2SiO2·3H2O (body-centered cubic lattice structure).
Fig.1(b) was the blackening film morphology map which was amplified 30000×, and we can see that the blackening film has reticular structure, dispersed.
XRD spectra of the blackening films In order to determine the phase of the blackening films structure, use TD-3000 X-ray diffraction to analysis.
Fig.3 XRD of the blackening film The XRD patterns in Fig.3 showed that the the blackening film was polycrystalline composite coating, which were composited with face-centered lattice structure of elemental antimony that was deposited on the metal surface and a small amount of body-centered cubic lattice structure of Al2O3·2SiO2·3H2O.
The analysis of the blackening film by SEM, XPS, XRD showed that the conversion film was composite crystalline film which was formed by elemental antimony (face centered orthorhombic lattice structure) and a small amount of Al2O3·2SiO2·3H2O (body-centered cubic lattice structure).
Online since: January 2005
Authors: Yong Gang Luo, Linda Zou, Eric Hu
Pellets of about 1 mm were selected and
used in the characterization of the pore structure of the solids.
Reaction temperatures too low or too high both were not good for the formation of the porous pore structure.
O'Neill, Thick titanium dioxide films for semiconductor photocatalysis, Journal of Photochemistry and Photobiology A: Chemistry, Volume 160, Issue 3, 21 August 2003, Pages 185-194
Chemistry Materials, 1994, (6): 2070-2082 [13] Bull L.
Su, Effects of templates on the structure, stability and photocatalytic activity of mesostructured TiO2, Journal of Photochemistry and Photobiology A: Chemistry, Volume 148, Issues 1-3, 31 May 2002, Pages 295-301
Reaction temperatures too low or too high both were not good for the formation of the porous pore structure.
O'Neill, Thick titanium dioxide films for semiconductor photocatalysis, Journal of Photochemistry and Photobiology A: Chemistry, Volume 160, Issue 3, 21 August 2003, Pages 185-194
Chemistry Materials, 1994, (6): 2070-2082 [13] Bull L.
Su, Effects of templates on the structure, stability and photocatalytic activity of mesostructured TiO2, Journal of Photochemistry and Photobiology A: Chemistry, Volume 148, Issues 1-3, 31 May 2002, Pages 295-301
Online since: February 2014
Authors: Zhi Yang, Fu Ting Xia, Wen Yi Li, Hua Zhu
B3LYP/6-31++G(d,p)-optimized structures (in Å) of the stationary points of hydrolysis of diethyl p-chlorophenyl phosphate in the gas phase.
B3LYP/6-31++G(d,p)-optimized structures (in Å) of the stationary points of hydrolysis of triethyl phosphate in the gas phase.
It demonstrates that the difference of structure between O-TS2phcl and O-INTphcl is not large.
Tarrat: Journal of Molecular Structure: THEOCHEM, 941 (2010) 56-60
Zhu: Computational and Theoretical Chemistry. 1017 (2013) 60-71
B3LYP/6-31++G(d,p)-optimized structures (in Å) of the stationary points of hydrolysis of triethyl phosphate in the gas phase.
It demonstrates that the difference of structure between O-TS2phcl and O-INTphcl is not large.
Tarrat: Journal of Molecular Structure: THEOCHEM, 941 (2010) 56-60
Zhu: Computational and Theoretical Chemistry. 1017 (2013) 60-71