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Online since: January 2012
Authors: Wing Ying Kwong
By engineering the organic chemistry of polymers, material properties can be expanded beyond limits, to include optical, electrical and mechanical properties and heat resistance.
Organic polymers are structurally flexible materials that are readily formed into single-mode planar waveguide structures in integrated optical systems.
By tuning the molecular structure and the molecular weight, these polymers will have a high cross-linking density.
These polymers have a highly stable aromatic ring structures along the backbone of the polymer chain.
In addition, since there is a limited number of polymers tested for passive waveguides, there is no limit in using polymers that have similar building blocks and based on similar chemistry.
Organic polymers are structurally flexible materials that are readily formed into single-mode planar waveguide structures in integrated optical systems.
By tuning the molecular structure and the molecular weight, these polymers will have a high cross-linking density.
These polymers have a highly stable aromatic ring structures along the backbone of the polymer chain.
In addition, since there is a limited number of polymers tested for passive waveguides, there is no limit in using polymers that have similar building blocks and based on similar chemistry.
Online since: August 2016
Authors: Sankar P. Sanyal, Chandrabhan Makode, Mahendra Aynyas, Jagdeesh Pataiya
From present study it is found that AmN and AmP are stable in NaCl – type structure under ambient pressure.
In the NaCl structure the corresponding lattice parameters are 2.890 and 3.124 Å respectively.
For a given pressure, a stable structure is one for which enthalpy has lowest value and the transition pressure (Pt) is determined at which the enthalpies of two structures are the same.
Skriver, Electronic Structure of the Actinide Metals, J.
[8] PK Jha and SP Sanyal, High pressure behavior of NpSe and NpTe, Journal of Physics and Chemistry of Solids 64 (2003), 127-131
In the NaCl structure the corresponding lattice parameters are 2.890 and 3.124 Å respectively.
For a given pressure, a stable structure is one for which enthalpy has lowest value and the transition pressure (Pt) is determined at which the enthalpies of two structures are the same.
Skriver, Electronic Structure of the Actinide Metals, J.
[8] PK Jha and SP Sanyal, High pressure behavior of NpSe and NpTe, Journal of Physics and Chemistry of Solids 64 (2003), 127-131
Online since: November 2012
Authors: Z. Fekete, E. Holczer, P. Fürjes
Another possible surface activation method can be the silane chemistry, applying Amino-Silanes as 3-Aminopropyltriethoxysilane (APTES) [8] or Hexamethyldisilazane (HMDS).
Fabrication scheme of the SU-8 moulding replica and the PDMS structures are presented in Figure 1.
Fig. 2: Specific part (Herring-Bone type mixer structure) of the SU-8 moulding replica (a.)
Hydrodynamic behaviour of modified PDMS microfluidic structure In our work, the influence of TX-100 on the surface wettability and the non-specific protein binding of the PDMS was studied in details.
Koudelka-Hep, Hybrid microfluidic cartridge formed by irreversible bonding of SU-8 and PDMS for multi-layer flow applications, Procedia Chemistry 1 (2009) 381–384 [9.]
Fabrication scheme of the SU-8 moulding replica and the PDMS structures are presented in Figure 1.
Fig. 2: Specific part (Herring-Bone type mixer structure) of the SU-8 moulding replica (a.)
Hydrodynamic behaviour of modified PDMS microfluidic structure In our work, the influence of TX-100 on the surface wettability and the non-specific protein binding of the PDMS was studied in details.
Koudelka-Hep, Hybrid microfluidic cartridge formed by irreversible bonding of SU-8 and PDMS for multi-layer flow applications, Procedia Chemistry 1 (2009) 381–384 [9.]
Online since: August 2012
Authors: Wu Yi Zhou, Zhuo Hong Yang, Su Yao Xiao, Yong Cao, Fang Liu
Compared with TiO2 nano-membrane, the XRD analysis shows that no significant shift in the crystal structure is presented because of silver ion-doping.
The films heated to 400°C(Fig.1A-b) and 450°C(Fig.1A-c) with featureless pattern suggests an amorphous structure while three distinct crystalline peaks at 25.3°, 38.6°, 48.1°. 2θ observed in the samples heated up to 500°C(Fig.1A-a,d,e,f) attributed to anatase crystal structure (JCPDS 21-1272) which has the best photoactivity of all.
From the patterns, it can be told that silver ion-doping does not cause any significant shift in the crystal structure compared with pureTiO2, and nice anatase crystal structure with preferable photoactivity can be already obtained at 500°C. 2.2 FTIR determination The insights into TiO2 heated to 500°C and Ag/TiO2 heated to 400°C, 450°C, 500°C, 550°C respectively are provided by IR spectrum in Fig.1B.
Journal of Physics and Chemistry of Solids. 2011, 72: 1312-1586
Fabrication and optical study of Ag@SnO2 core-shell structure nanoparticle thin films[J].
The films heated to 400°C(Fig.1A-b) and 450°C(Fig.1A-c) with featureless pattern suggests an amorphous structure while three distinct crystalline peaks at 25.3°, 38.6°, 48.1°. 2θ observed in the samples heated up to 500°C(Fig.1A-a,d,e,f) attributed to anatase crystal structure (JCPDS 21-1272) which has the best photoactivity of all.
From the patterns, it can be told that silver ion-doping does not cause any significant shift in the crystal structure compared with pureTiO2, and nice anatase crystal structure with preferable photoactivity can be already obtained at 500°C. 2.2 FTIR determination The insights into TiO2 heated to 500°C and Ag/TiO2 heated to 400°C, 450°C, 500°C, 550°C respectively are provided by IR spectrum in Fig.1B.
Journal of Physics and Chemistry of Solids. 2011, 72: 1312-1586
Fabrication and optical study of Ag@SnO2 core-shell structure nanoparticle thin films[J].
Online since: November 2013
Authors: Nadras Othman, Ismail Hanafi, Nor Hasmaniza Husna Shuhaimi, Sreenivasan Sasidharan
This is due crystalline of SMR CV60 structure which induce more strain crystallization when stress was applied.
This is because of the bulky group (styrene) in SBR compounds which has given amorphous state to the SBR structure.
In addition, polymer chain structure has given more impact towards the mechanical properties of rubber materials.
Wright, Hevea brasiliensis: or para rubber, its botany, cultivation, chemistry and diseases, London: Maclaren & sons, 1908 [3] G.Y.
Koenig, A review of rubber oxidation, Rubber Chemistry and Technology, 78 (2005) 355-390
This is because of the bulky group (styrene) in SBR compounds which has given amorphous state to the SBR structure.
In addition, polymer chain structure has given more impact towards the mechanical properties of rubber materials.
Wright, Hevea brasiliensis: or para rubber, its botany, cultivation, chemistry and diseases, London: Maclaren & sons, 1908 [3] G.Y.
Koenig, A review of rubber oxidation, Rubber Chemistry and Technology, 78 (2005) 355-390
Online since: June 2012
Authors: Jun Hui Xiang, Fu Shi Zhang, Li Xing, Xiao Hong Liang, Li Jie Cui, Bo Song, Shi Wei Chen, Hua Zheng Sai, Zhen You Li, Chun Lin Zhao
Photoluminescence Enhancement of CdS Nanocrystals Fabricated on Dithiocarbamate Functionalized PET Substrates
Zhao Chunlin1, a, Xing Li1, Liang Xiaohong1, Xiang Junhui1, b, Zhang Fushi2,
Cui Lijie1, c, Song Bo1, Chen Shiwei1, Sai Huazheng1, and Li Zhenyou1
1 College of Chemistry and Chemical Engineering, Graduate University of the Chinese Academy of Sciences, Beijing 100049, China
2Department of chemistry, Tsinghua University, Beijing 100084, China
azhaochunlin09@mails.gucas.ac.cn, bxiangjh@gucas.ac.cn, cljcui@gucas.ac.cn
Keywords: CdS nanocrystals(NCs), dithiocarbamate ligand, biphase interface, PET substrates
Abstract.
Powder X-ray diffraction measurement revealed the hexagonal structure of CdS nanocrystals.
(b) The high-resolution TEM of the fine structure of the CdS NCs film.
The high-resolution TEM were employed to investigate the fine structure of the CdS NCs film (shown in Fig. 4b).
Chen, Multiple-structured nanocrystals towards bifunctional photoluminescent-superhydrophobic surfaces, J.
Powder X-ray diffraction measurement revealed the hexagonal structure of CdS nanocrystals.
(b) The high-resolution TEM of the fine structure of the CdS NCs film.
The high-resolution TEM were employed to investigate the fine structure of the CdS NCs film (shown in Fig. 4b).
Chen, Multiple-structured nanocrystals towards bifunctional photoluminescent-superhydrophobic surfaces, J.
Online since: June 2014
Authors: Xue Xue Song, Li Juan Li, Zhi Qi Liu
Hamerton, Recent developments in the chemistry of halogen-free flame retardant polymers, J.
Chemistry of Materials. 19 (2007) 5395-5403
Composite Structures. 62 (2003) 391-395
Industrial & Engineering Chemistry Research. 48 (2009) 763-768
Materials Chemistry and Physics. 112 (2008) 962-965
Chemistry of Materials. 19 (2007) 5395-5403
Composite Structures. 62 (2003) 391-395
Industrial & Engineering Chemistry Research. 48 (2009) 763-768
Materials Chemistry and Physics. 112 (2008) 962-965
Online since: June 2012
Authors: Zhong Feng Tang, Guo Jun Cheng, Xiu Hua Yu
The modified coal powder particles can be dispersed equally in rubber and form physical and chemical crosslinking structure with rubber.
Coal contains large amounts of aromatic structures, high carbon content and electrophilic active sites of aromatic structures can react as substituent, alkylation, acylation [1].
FTIR, TGA and CAMI were performed to characterize the structures and properties of M-coal and N-coal.
It is like due to interaction between the active chain or group of coupling agent and macromolecular chain of SBS form network structures [17].
Rubber & Plastics Resources Utilization Vol. 4(2010). p. 11 In Chinese [16] T Yasin: Radiation Physics and Chemistry Vol. 73(2005). p. 155 [17] Satyajit G, Praveen C: Industrial & Engineering Chemistry Research Vol. 50(2011). p. 6585
Coal contains large amounts of aromatic structures, high carbon content and electrophilic active sites of aromatic structures can react as substituent, alkylation, acylation [1].
FTIR, TGA and CAMI were performed to characterize the structures and properties of M-coal and N-coal.
It is like due to interaction between the active chain or group of coupling agent and macromolecular chain of SBS form network structures [17].
Rubber & Plastics Resources Utilization Vol. 4(2010). p. 11 In Chinese [16] T Yasin: Radiation Physics and Chemistry Vol. 73(2005). p. 155 [17] Satyajit G, Praveen C: Industrial & Engineering Chemistry Research Vol. 50(2011). p. 6585
Online since: February 2014
Authors: Xin Zhao, Wei Zou, Zong Qiang Zhu, Zong Lan Zhang, Yi Nian Zhu
The Characteristic Dissolution and Physical Chemistry Parameter of Synthetic Pyromorphite
Xin Zhao 1,2 a, Wei Zou 2, b*, Zonglan Zhang 3, c, Zongqiang Zhu 3,d and Yinian Zhu 3,e
1 College of Light Industry and Food Engineering, Guangxi University, Nanning, Guangxi 530004, China
2 Hainan Research Academy of Environmental Sciences,Haikou, Hainan 571126, China
3 Guangxi Scientific Experimental Centre for Mining, Metallurgy and Environment, Guilin University of Technology, Guilin, Guangxi 541004, China
azhaoxin@hainan.gov.cn, bzouwei@ hainan.gov.cn, c349709184@qq.com, dzhuzongqiang@glut.edu.cn, ezhuyinian@glut.edu.cn
*Corresponding authors.
The results of the Fourier transform infrared spectroscopy analyses indicated that the synthetic, microcrystalline pyromorphite with apatite structure used in the experiments has not changed after dissolution.
The results of the Fourier transform infrared spectroscopy analyses indicated that the synthetic, microcrystalline pyromorphite with apatite structure used in the experiments has not changed after dissolution.
Online since: August 2013
Authors: Wei Hu, Sheng Tian Huang, Shen Xin Li, Ying Wang, Song Wu
Hydrolysis of BNPP Catalyzed by the Dodecyliminodiacetate Nickel(II) and Copper(II) Complexes
Sheng-tian Huanga , Shen-xin Li b, Ying Wang c, Song Wu d, Wei Hue *
University Key Laboratory of Green Chemistry of Sichuan Institutes of Higher Education, Zi gong,
Sichuan, 643000, P.
The half-lives of the hydrolytic reactions of simple phosphate diesters are on the order of thousand years, although their spontaneous hydrolysis is thermodynamically favourable. [1-4] Because the natural enzymes is complex, expensive and of unstable structures.[5]Then, many researchers have already concentrated on the study of artificial enzymes.With complex and more stable chemical structure, these mimetic enzymes have similar catalytic function to natural enzymes.
Effects of the complex structure on the rate of PNPP catalytic hydrolysis Generally, the enzymatic catalytic activity and selectivity are correlated to the enzymatic structure.
The mimic hydrolase used in this paper shows similar effects of the structure to the natural hydrolase in the BNPP catalytic hydrolysis.
Coordination Chemistry Reviews Vol. 173(1998), p.133 [6] Li, J.
The half-lives of the hydrolytic reactions of simple phosphate diesters are on the order of thousand years, although their spontaneous hydrolysis is thermodynamically favourable. [1-4] Because the natural enzymes is complex, expensive and of unstable structures.[5]Then, many researchers have already concentrated on the study of artificial enzymes.With complex and more stable chemical structure, these mimetic enzymes have similar catalytic function to natural enzymes.
Effects of the complex structure on the rate of PNPP catalytic hydrolysis Generally, the enzymatic catalytic activity and selectivity are correlated to the enzymatic structure.
The mimic hydrolase used in this paper shows similar effects of the structure to the natural hydrolase in the BNPP catalytic hydrolysis.
Coordination Chemistry Reviews Vol. 173(1998), p.133 [6] Li, J.