Hydrolysis of BNPP Catalyzed by the Dodecyliminodiacetate Nickel(II) and Copper(II) Complexes

Abstract:

Two novel dodecyliminodiacetate nickel (II) and copper (II) complexes were synthesized and characterized, and these complexes were used as mimic hydrolytic in catalytic hydrolysis of bis (p-nitrophenyl) phosphate (BNPP). The analysis of specific absorption spectra of the hydrolytic reaction systems indicated that the catalytic hydrolysis involved the key intermediates formed by BNPP with nickel (II) complexes. The kinetic parameter of BNPP catalytic hydrolysis has been calculated and the temperature effect of reaction system and structure effect of the complexes on the rate of BNPP hydrolysis catalyzed by the complexes have been discussed.

• Periodical: Advanced Materials Research (Volume 749)
• Pages: 507-511
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.749.507
• Online since: August 2013
• Authors: Sheng Tian Huang, Shen Xin Li, Ying Wang, Song Wu, Wei Hu
• Keywords: Dodecyliminodiacetate Complexes, Mimic Hydrolase, Phosphate Esters Hydrolysis

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