Synthesis, Characterization, DNA-Binding Study of C15H12O4N2 and its Lanthanide Complexes

Chao Chao Song; Xiang Rong Liu; Shun Sheng Zhao; Jun Wang; Jing Wen Ren; Kan She Li

doi:10.4028/www.scientific.net/AMR.749.516

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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 749Synthesis, Characterization, DNA-Binding Study of...

Synthesis, Characterization, DNA-Binding Study of C₁₅H₁₂O₄N₂ and its Lanthanide Complexes

Abstract:

A new series complexes of Ln nitrate with H₂L, where Ln stands for La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Yb, and H₂L is 2-carboxybenzaldehyde- (4-hydroxy) benzoylhydrazone, were synthesized. Elemental analysis and IR spectroscopy were used to characterize and found that the complexes were Ln (HL)₂(NO₃)·4EtOH·4H₂O type. The binding mode of complexes with CTDNA was investigated by UV-Vis titration and emission titration, suggesting that the complexes bind with CTDNA in a non-covalent groove binding mode.

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Advanced Materials Research (Volume 749)

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516-520

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.749.516

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Online since:

August 2013

Authors:

Chao Chao Song, Xiang Rong Liu, Shun Sheng Zhao, Jun Wang, Jing Wen Ren, Kan She Li

Keywords:

Characterization, DNA-Binding, Groove Binding, Synthesis

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