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Structure Studies on order Assemblage of Cobalt II Complexes
Abstract:
The cobaltII complex [Co (C9H9O3)2(H2O)2], Diaqua-bis (ethylvanillinato-O,O')-cobaltII, the CoII atom is located on a twofold axis and is coordinated by two ethylvanillinate anions and two water molecule in a distorted octahedral geometry . The ethylvanillinate ligand chelates to the CoII atom through its ethyl and hydroxy O atoms,with differing Co-O bond distances (2.282(2) Å and 1.9914(18) Å).Adjacent complex link to each other via hydrogen bonds forming the three-dimensional supramolecular structure.
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512-515
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Online since:
August 2013
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© 2013 Trans Tech Publications Ltd. All Rights Reserved
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