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Online since: April 2012
Authors: Jin He Jiang
The Synthesis and Ion-exchange Property of Inorganic Material Mg2Mn0.5Ti0.5O4
Jinhe Jiang
MicroScale Science Institute , Department of Chemistry and Chemical Engineering ,Weifang University, Weifang, 261061,China
Corresponding author.
The structure of compound metal oxideMg2Mn0.5Ti0.5O4 crystallized at 900℃ was much perfect.
As shown, the structure of MgMnTi-900(H) is nearly constant, which is spinel oxide type too.
The reaction of H+ in ion-exchanger with alkali metal ions in solution as follows(example for Li+): (2) Fig.4 Distribution coefficient of MgMnTi-900(H)for alkali ions Conclusions The comprehensive results indicate that the Mg2Mn0.5Ti0.5O4 show a capacity extraction/insertion of Li+ in the aqueous phase, mainly by an ion-exchange mechanism. lithium-ion sieve which was prepared is the spinel-type structure.
Chemistry Online. 1997,(12),11-16
The structure of compound metal oxideMg2Mn0.5Ti0.5O4 crystallized at 900℃ was much perfect.
As shown, the structure of MgMnTi-900(H) is nearly constant, which is spinel oxide type too.
The reaction of H+ in ion-exchanger with alkali metal ions in solution as follows(example for Li+): (2) Fig.4 Distribution coefficient of MgMnTi-900(H)for alkali ions Conclusions The comprehensive results indicate that the Mg2Mn0.5Ti0.5O4 show a capacity extraction/insertion of Li+ in the aqueous phase, mainly by an ion-exchange mechanism. lithium-ion sieve which was prepared is the spinel-type structure.
Chemistry Online. 1997,(12),11-16
Online since: June 2015
Authors: M.R. Sahar, Sib Krishna Ghoshal, Siti Aishah Jupri
The introduction of Eu3+ in the glass network breaks the regular structure of lithium and tellurite to form more NBOs.
The formation of NBO played an important role in the alteration of glass network structures.
Culea, Journal of Molecular Structure 924-926 (2009) 214-220
Culea, Journal of Physics and Chemistry of Solids 74 (2013) 1235-1239
Lim, C.K Jayasankar, Material Chemistry and Physics 141 (2013) 903-911
The formation of NBO played an important role in the alteration of glass network structures.
Culea, Journal of Molecular Structure 924-926 (2009) 214-220
Culea, Journal of Physics and Chemistry of Solids 74 (2013) 1235-1239
Lim, C.K Jayasankar, Material Chemistry and Physics 141 (2013) 903-911
Online since: February 2012
Authors: Heng Li
Li+ Extraction/Insertion Reaction with MgMn0.25Ti0.75O3 Spinel in the Aqueous Phase
JinHe Jiang
MicroScale Science Institute , Department of Chemistry and Chemical Engineering ,Weifang University, Weifang, 261061,China
Corresponding author.
In this paper, the coprecipitation/thermal crystallization method was used to synthesize the MgMn0.25Ti0.75O3 of inverse spinel-type oxide, whose composition and structure are different from those in literature[3-4], The experimental result have proved that the inorganic material has better selectivity and higher capacity of exchange for Li+ in the solution removed Li+ previously.
The structure of compound metal oxide MgMn0.25Ti0.75O3 crystallized at 900℃ was much perfect.
As shown, the structure of MgMnTi-900(H) is nearly constant, which is spinel oxide type too.
Synthesis of Li4Mn0.5Ti0.5O4 and its selectivity to Li+ exchange, J.Chinese Journal of Applied Chemistry.2006,23(4),357
In this paper, the coprecipitation/thermal crystallization method was used to synthesize the MgMn0.25Ti0.75O3 of inverse spinel-type oxide, whose composition and structure are different from those in literature[3-4], The experimental result have proved that the inorganic material has better selectivity and higher capacity of exchange for Li+ in the solution removed Li+ previously.
The structure of compound metal oxide MgMn0.25Ti0.75O3 crystallized at 900℃ was much perfect.
As shown, the structure of MgMnTi-900(H) is nearly constant, which is spinel oxide type too.
Synthesis of Li4Mn0.5Ti0.5O4 and its selectivity to Li+ exchange, J.Chinese Journal of Applied Chemistry.2006,23(4),357
Online since: September 2007
Authors: In Seok Yoon, Eddy A.B. Koenders
Critical chloride content for corrosion initiation is a crucial parameter in
determining the durability and integrity of reinforced concrete structures.
Relative humidity (%) [Cl]cr (% by cement wt.) 0.4 50 (Low corrosion) 85 (High corrosion) 100 (Low corrosion) Non-carbonated concrete Carbonated concrete Figure 1 [Cl]cr of (non)carbonated concrete(CEB[7]) Pore Water Chemistry.
Andrade: Synthetic Concrete Pore Solution Chemistry and Rebar Corrosion Rate in the Presence of Chlorides, Cement and Concrete Research Vol.20 (1990), p.525-539
[5] K. van Breugel: Simulation of Hydration and Formation of Structures in Hardening Cement-Based Materials (1991), Ph.D Dissertation, TU Delft, the Netherlands
[7] CEB: Durable Concrete Structures: Design Guide (1992) 2nd Edition, Thomas Telford, London
Relative humidity (%) [Cl]cr (% by cement wt.) 0.4 50 (Low corrosion) 85 (High corrosion) 100 (Low corrosion) Non-carbonated concrete Carbonated concrete Figure 1 [Cl]cr of (non)carbonated concrete(CEB[7]) Pore Water Chemistry.
Andrade: Synthetic Concrete Pore Solution Chemistry and Rebar Corrosion Rate in the Presence of Chlorides, Cement and Concrete Research Vol.20 (1990), p.525-539
[5] K. van Breugel: Simulation of Hydration and Formation of Structures in Hardening Cement-Based Materials (1991), Ph.D Dissertation, TU Delft, the Netherlands
[7] CEB: Durable Concrete Structures: Design Guide (1992) 2nd Edition, Thomas Telford, London
Online since: May 2012
Authors: Sheng Lai Guo, Chang Lu, Cong Ma, Xin Yang Guo, Da Qian Zhang
.%
CaO
45.61
Al2O3
25.74
SiO2
8.76
P2O5
12.6
Fe2O3
3.02
MgO
2.61
Specific density [kg/L]
3.25
d50 value [μm]
8.5
Citric Acid
Sodium Hydrogen Phosphate
Sodium Ethylenediamine Tetra Methylene Phosphate
Fig. 1 Chemical structures of retarder samples used in this study
Fig. 1 shows chemical structures of three retarders.
Chemical structures of the retarders used in this study (citric acid, sodium hydrogen phosphate and sodium ethylenediamine tetra methylene phosphate) are shown in Figure 1.
Oilfield Chemistry, 2008
Paper SPE 28957 presented at the 1995 SPE International Symposium on Oilfield Chemistry held in San Antonio, TX, 14-17 Februay
Chemical structures of the retarders used in this study (citric acid, sodium hydrogen phosphate and sodium ethylenediamine tetra methylene phosphate) are shown in Figure 1.
Oilfield Chemistry, 2008
Paper SPE 28957 presented at the 1995 SPE International Symposium on Oilfield Chemistry held in San Antonio, TX, 14-17 Februay
Online since: May 2015
Authors: Gang Huang, Yu Xin Li, Li Qian, Qi Li
Introduction
Biosensor based on micro-machined resonator is a new bio-chemical analysis method, which relates to the MEMS, Materials, Bio-chemistry, Mechanical and other cross-disciplinary subjects.
However, the Q-factor is rapidly decayed in liquid due to the large damping, which makes some resonant structure not suitable to work in liquid.
This paper presents a paddle structure working in the torsional mode, by which the resonator can achieve higher Q-factor.
Block diagram of the system circuitry Fig.6 (a) output of the sensor in pure water Fig.6 (b) output of the sensor in pure ethanol Conclusions A pendulous resonant MEMS biosensor for liquid detection with differential structures is presented with several key design aspects analyzed.
Hierlemann, Liquid-phase chemical and biochemical detection using fully integrated magnetically actuated complementary metal oxide semiconductor resonant cantilever sensor systems, Analytical Chemistry. 79(2007) 1646-1654
However, the Q-factor is rapidly decayed in liquid due to the large damping, which makes some resonant structure not suitable to work in liquid.
This paper presents a paddle structure working in the torsional mode, by which the resonator can achieve higher Q-factor.
Block diagram of the system circuitry Fig.6 (a) output of the sensor in pure water Fig.6 (b) output of the sensor in pure ethanol Conclusions A pendulous resonant MEMS biosensor for liquid detection with differential structures is presented with several key design aspects analyzed.
Hierlemann, Liquid-phase chemical and biochemical detection using fully integrated magnetically actuated complementary metal oxide semiconductor resonant cantilever sensor systems, Analytical Chemistry. 79(2007) 1646-1654
Online since: July 2012
Authors: Min Fang Chen, Rong Zhen Shen, De Bao Liu, Chen You
In biomimetic process, the biological systems store and process information at the molecular level, and the chemical co-precipitation process [3,4] creates the organized nanocomposite structure.
Because polyamide is similar to collagen protein in chemical structure and active group, it is biocompatible and tough. [6] Accordingly, polyamide 66 (PA66) was selected to prepare n-HA/pa66 composite.In 1991, Kokubo et al. [7] proposed that the essential requirement for an artificial implant to bond to living bone was the formation of bonelike apatite on it’s surface.
The change of a2-crystal at 2θ=23.88° means a highly possible change of the PA66 crystal structure in the compositeIt is known that the crystallinity of PA depends on its hydrogen bonds.
[3] Chang M C, Ko C C and William H, Biomaterials, Vol. 24 (2003), p. 2853 [4] Huang M and Li Y B, J Mater Sci.: Mater in Med, Vol. 14 (2003), p. 655 [5] Chen M F and Tan J J, Applied Surface Science, Vol. 254 (2008), p. 2730 [6] Wei Jie and Li Yubao, European Polymer Journal, Vol. 40 (2004), p. 509 [7] Kokubo T and Takadama H, Biomaterials, Vol. 27 (2006), p. 2907 [8] Wu G, Su B, Zhang W G, Wang C, Materials Chemistry and Physics, Vol. 107 (2008), p. 364 [9] Shen R Z, Chen M F, Liu D B, Jounal of Inorganic Chemistry, Vol25(2009), p. 236
Because polyamide is similar to collagen protein in chemical structure and active group, it is biocompatible and tough. [6] Accordingly, polyamide 66 (PA66) was selected to prepare n-HA/pa66 composite.In 1991, Kokubo et al. [7] proposed that the essential requirement for an artificial implant to bond to living bone was the formation of bonelike apatite on it’s surface.
The change of a2-crystal at 2θ=23.88° means a highly possible change of the PA66 crystal structure in the compositeIt is known that the crystallinity of PA depends on its hydrogen bonds.
[3] Chang M C, Ko C C and William H, Biomaterials, Vol. 24 (2003), p. 2853 [4] Huang M and Li Y B, J Mater Sci.: Mater in Med, Vol. 14 (2003), p. 655 [5] Chen M F and Tan J J, Applied Surface Science, Vol. 254 (2008), p. 2730 [6] Wei Jie and Li Yubao, European Polymer Journal, Vol. 40 (2004), p. 509 [7] Kokubo T and Takadama H, Biomaterials, Vol. 27 (2006), p. 2907 [8] Wu G, Su B, Zhang W G, Wang C, Materials Chemistry and Physics, Vol. 107 (2008), p. 364 [9] Shen R Z, Chen M F, Liu D B, Jounal of Inorganic Chemistry, Vol25(2009), p. 236
Online since: January 2013
Authors: Gui Hua Peng, Zhen Hua Liang, Chang Cheng Liu, Xiao Bao Han, Xia Wang
Hollow Spherical CaMoO4:Eu3+, Li+ Phosphors Prepared by Spray Pyrolysis
Xia Wanga, Chang-cheng Liub, Zhen-hua Liangc, Gui-hua Pengd,
Xiao-bao Hane
State Key Laboratory Cultivation Base for the Chemistry and Molecular Engineering of Medicinal Resources, Ministry of Science and Technology of China, School of Chemistry & Chemical Engineering of Guangxi Normal University, Guilin, Guangxi, 541004, China
a409145367@qq.com, b1084184056@qq.com, cliangzh@mailbox.gxnu.edu.cn, dpengguihua164@163.com, e313457758@qq.com
Keywords: Spray Pyrolysis, Hollow Spheres, CaMoO4:Eu3+, Li+, Red Phosphor.
All the data of XRD patterns can be indexed to JCPDS 29-0351 for CaMoO4, suggesting the sample has a scheelite structure, of which the crystal group is I41/a.
From Fig.2, the particles had a spherical shape with hollow inner structures and fairly smooth surface with some holes on them, which were estimated from the morphologies of the fractured particles in the SEM photographs.
The obtained particles have a spherical shape with hollow inner structures and fairly smooth surface with some holes on them.
All the data of XRD patterns can be indexed to JCPDS 29-0351 for CaMoO4, suggesting the sample has a scheelite structure, of which the crystal group is I41/a.
From Fig.2, the particles had a spherical shape with hollow inner structures and fairly smooth surface with some holes on them, which were estimated from the morphologies of the fractured particles in the SEM photographs.
The obtained particles have a spherical shape with hollow inner structures and fairly smooth surface with some holes on them.
Online since: August 2014
Authors: Lian Jiang Tan, Ting Ting Zhao, Jing Juan Lu
Synthesis and Applications of Gold Nanoparticles
Tingting Zhao, Jingjuan Lu*, Lianjiang Tan*
School of Chemistry and Chemical Engineering,
Shanghai Jiao Tong University, Shanghai 200240, China
* Corresponding author.
Self-conversion of hydroxyphenols to quinones is responsible for the generation of gold nanoparticles with different surface structures. 2.2 Template method and nano architectonics Ordered arrays of gold nanoparticles play an important role in nanoelectronic and nanophotonic applications.
Moreover, another metal can be added to the AuNPs, leading to a core-shell structure with controllable dimensions.
The MIS structure has an excellent memory effect and high retention time up to 20000 s.
For example, how combine the gold nanoparticels with the green chemistry and how to apply gold nanoparticles to biomedical.
Self-conversion of hydroxyphenols to quinones is responsible for the generation of gold nanoparticles with different surface structures. 2.2 Template method and nano architectonics Ordered arrays of gold nanoparticles play an important role in nanoelectronic and nanophotonic applications.
Moreover, another metal can be added to the AuNPs, leading to a core-shell structure with controllable dimensions.
The MIS structure has an excellent memory effect and high retention time up to 20000 s.
For example, how combine the gold nanoparticels with the green chemistry and how to apply gold nanoparticles to biomedical.
Online since: March 2015
Authors: Hong Fu Fan, Yi Dan Wang
When the surfactant concentration above the critical micelle concentration (CMC) in the VES fluid, the micellar structures entangles and forms a three-dimensional grid structure.
Because of these structures, clean fracturing fluid can still carry proppant at low viscosities [1-4].
Wang: Oilfield Chemistry Vol. 18 (2001), p. 273 (in Chinese with English abstract) [2] F.
Hao and A.Q.Yang: Oilfield Chemistry Vol. 32 (2010), p. 112 (in Chinese with English abstract) [12] S.C.
Because of these structures, clean fracturing fluid can still carry proppant at low viscosities [1-4].
Wang: Oilfield Chemistry Vol. 18 (2001), p. 273 (in Chinese with English abstract) [2] F.
Hao and A.Q.Yang: Oilfield Chemistry Vol. 32 (2010), p. 112 (in Chinese with English abstract) [12] S.C.