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Online since: September 2019
Authors: Adel Saoudi, Farida Khamouli, Kaltoum Digheche, Mosbah Zidani, L'Hadi Atoui, Hend Moussi
The chemistry of weld metal is always governed by the electrochemical changes at the weld pool flux interface [1-6].
Some papers found also even small changes in the flux or coating chemistry could lead to substantial variations in the metallurgical behavior of the obtained systems [17,18].
The CaMgSi2O7 phase has a melting temperature below 1000°C and a tetragonal crystalline structure [41].
Bailey, Evidence from inclusion chemistry of element transfer during submerged arc welding, Weld.
Gupta, Effect of submerged arc welding parameters and fluxes on element transfer behaviour and weld-metal chemistry.
Some papers found also even small changes in the flux or coating chemistry could lead to substantial variations in the metallurgical behavior of the obtained systems [17,18].
The CaMgSi2O7 phase has a melting temperature below 1000°C and a tetragonal crystalline structure [41].
Bailey, Evidence from inclusion chemistry of element transfer during submerged arc welding, Weld.
Gupta, Effect of submerged arc welding parameters and fluxes on element transfer behaviour and weld-metal chemistry.
Online since: September 2011
Authors: Ting Sheng Weng, Meng Hui Hsu
On the study of Non-engineering Students Applied Open Source for Learning Graphic Design Skills of Dynamic 3D Motocross Suspension Mechanism
Ting-Sheng Weng 1, a, Meng-Hui Hsu 2, b
1 Department of Business Administration, National Chiayi University, Chiayi City, Taiwan
2 Department of Mechanical Engineering, Kun Shan University, Tainan, Taiwan
a politeweng@mail.ncyu.edu.tw, b mhhsu@mail.ksu.edu.tw, corresponding author
Keywords: open source, interactive graphic, dynamic digital, interdisciplinary science, topological structure, suspension mechanism.
As results, the students can transform visual information of the topological structure of a suspension mechanism to the dynamic digital interactive graphic.
Importance of interdisciplinary technique and education Chatzitheodoridis showed that Apart from the conventional approach of teaching courses from basic sciences (physics, chemistry, and biology), engineering and information sciences, we would also need courses on psychology and public awareness, environmental and anthropological sciences, etc. [3].
Based on design concept of existing devices, the design methodology can generate all possible topological structures of mechanical devices that perform the same or similar tasks as available existing designs, and subject to certain design requirements and constraints.
The topological structure of this mechanism includes six members and seven joints.
As results, the students can transform visual information of the topological structure of a suspension mechanism to the dynamic digital interactive graphic.
Importance of interdisciplinary technique and education Chatzitheodoridis showed that Apart from the conventional approach of teaching courses from basic sciences (physics, chemistry, and biology), engineering and information sciences, we would also need courses on psychology and public awareness, environmental and anthropological sciences, etc. [3].
Based on design concept of existing devices, the design methodology can generate all possible topological structures of mechanical devices that perform the same or similar tasks as available existing designs, and subject to certain design requirements and constraints.
The topological structure of this mechanism includes six members and seven joints.
Online since: May 2019
Authors: Shuang Quan Liao, Jie Guan, Wan Na Bai, Fuchun Zhao
The dynamic evolution of accelerated storage properties and molecular structure of natural rubber have been investigated.
Bonfils, New insights on Natural Rubber microgel structure thanks to a new method for microaggregates extraction, Eur.
Bateman, chemistry and physics of rubber-like substances, Maclaren, Wiley, New York 1963, pp. 168
Sakdapipanich, Molecular structure and storage hardening of natural rubber: Insight into the reactions between hydroxylamine and phospholipids linked to natural rubber molecule, J.
Li, Study on variation of structure and properties of natural rubber during accelerated storage, J.
Bonfils, New insights on Natural Rubber microgel structure thanks to a new method for microaggregates extraction, Eur.
Bateman, chemistry and physics of rubber-like substances, Maclaren, Wiley, New York 1963, pp. 168
Sakdapipanich, Molecular structure and storage hardening of natural rubber: Insight into the reactions between hydroxylamine and phospholipids linked to natural rubber molecule, J.
Li, Study on variation of structure and properties of natural rubber during accelerated storage, J.
Online since: October 2022
Authors: Qing Yun Ding, Peng Shen, Dan Ma, Yu Tang, Xi Li, Chao Qun Ma
. , Nanjing 210012, China
adqy19951009@163.com, bmadan@fiberglasschina.com, ctangyu@fiberglasschina.com, dlixi@fiberglasschina.com, emachaoqun@fiberglasschina.com, fshenpeng@fiberglasschina.com
Keywords: Ni/Al energetic structure material; secondary treatment; cold rolling; cold isostatic pressing; exothermic property; mechanical property
Abstract.
The vacuum hot-pressed Ni/Al energetic structure material is numbered as 1# energetic material, and the materials obtained after the secondary treatment of cold rolling and cold isostatic pressing are numbered as 2# and 3# energetic material respectively.
[3] Shuck C E, Pauls J M, Mukasyan A S, Ni/Al energetic nanocomposites and the solid flame phenomenon, The Journal of Physical Chemistry C. 120(2016)27066-27078
[9] Manukyan K V, Mason B A, Groven L J, Tailored Reactivity of Ni+Al Nanocomposites: Microstructural Correlations, The Journal of Physical Chemistry C. 116(2012)21027-21038
The vacuum hot-pressed Ni/Al energetic structure material is numbered as 1# energetic material, and the materials obtained after the secondary treatment of cold rolling and cold isostatic pressing are numbered as 2# and 3# energetic material respectively.
[3] Shuck C E, Pauls J M, Mukasyan A S, Ni/Al energetic nanocomposites and the solid flame phenomenon, The Journal of Physical Chemistry C. 120(2016)27066-27078
[9] Manukyan K V, Mason B A, Groven L J, Tailored Reactivity of Ni+Al Nanocomposites: Microstructural Correlations, The Journal of Physical Chemistry C. 116(2012)21027-21038
Online since: October 2014
Authors: Wen Yi Li, Xiao Ping Wang, Hui Li, Ming Tian, Xia Wang, Yi Zhou
The results indicated that the nanocomposites with uniform core-shell structure exhibited higher thermal stability than neat poly(phenylene vinylene).
These results showed clearly the nanocomposites with good core-shell structures had been prepared successfully.
MWCNTs Chemical Structure The typical FT–IR spectra of neat PPV and coaxial nanocomposite containing 10 wt.
SEM observation indicated as–prepared nanocomposites exhibited good core–shell structure.
[5] Li L, Qin ZY, Liang X, Fan QQ, Lu YQ, Wu WH, Zhu MF, Facile Fabrication of uniform Core–shell Structured carbon nanotube–polyaniline nanocomposites, The Journal of Physical Chemistry C, 2009, 113(14): 5502–5507
These results showed clearly the nanocomposites with good core-shell structures had been prepared successfully.
MWCNTs Chemical Structure The typical FT–IR spectra of neat PPV and coaxial nanocomposite containing 10 wt.
SEM observation indicated as–prepared nanocomposites exhibited good core–shell structure.
[5] Li L, Qin ZY, Liang X, Fan QQ, Lu YQ, Wu WH, Zhu MF, Facile Fabrication of uniform Core–shell Structured carbon nanotube–polyaniline nanocomposites, The Journal of Physical Chemistry C, 2009, 113(14): 5502–5507
Online since: November 2010
Authors: Jun Sai Sun, Cun Ying Xu
Introduction
Room-temperature ionic liquids (RTILs) are a new class of solvents, which have received much attention in many fields of chemistry owing to their unique physicochemical properties, such as high fluidity, high thermal stability, extended temperature range in the liquid state, low toxicity, high ionic conductivity and others [1-2].
For these reasons, ionic liquids are actively being explored as environmentally benign solvents in organic synthesis and catalysis [3], but they have been utilized little in the areas of synthetic coordination chemistry.
Only in recent years, the use of ionic liquids in the synthesis of coordination structure field has been gradually explored [4-8].
Li et al. [8] have synthesized of the coordination polymer [Cu(I)(bpp)]BF4 in 1-butyl-3-methylimidazolium tetrafluoroborate ionic liquid and found that BF4- anions entered the final structure as a charge-compensating species.
For these reasons, ionic liquids are actively being explored as environmentally benign solvents in organic synthesis and catalysis [3], but they have been utilized little in the areas of synthetic coordination chemistry.
Only in recent years, the use of ionic liquids in the synthesis of coordination structure field has been gradually explored [4-8].
Li et al. [8] have synthesized of the coordination polymer [Cu(I)(bpp)]BF4 in 1-butyl-3-methylimidazolium tetrafluoroborate ionic liquid and found that BF4- anions entered the final structure as a charge-compensating species.
Online since: September 2013
Authors: Xiao Li Wang, Feng Quan Liu, Bin Dong
Synthesis and Characterization of Vinyl Substituted
2,2-Bisferrocenylpropane and Corresponding Polymers
Bin Dong 1, a, Xiaoli Wang 2,b and Fengquan Liu 1,c
1 School of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing 100083, China
2 Inner Mongolia Chemical Engineering Professional College, Huhhot 010010, China
adongbin@ustb.edu.cn, b1070887184@qq.com, c1561852495@qq.com
Keywords: 6-vinyl bisferrocenylpropane; 6,6'-divinyl bisferrocenylpropane; homopolymer; copolymer; thermal stability
Abstract The homopolymer of 6-vinyl bisferrocenylpropane and copolymer of 6-vinyl bisferrocenylpropane and 6,6'-divinyl bisferrocenylpropane were obtained from ferrocene and acetone via a series of reactions.
Introduction Studies of organometallic polymer chemistry developed rapidly since Arimoto and Haven reported the vinyl radical polymerization of ferrocene in 1955[1].
Because the space environments of protons with similar structures in polymer I are just slightly different, the absorption peaks with similar chemical shifts overlay each other and form broad multiple peaks.
There is only one vinyl group in the monomer I, which leads to the linear structure of the polymer I.
Introduction Studies of organometallic polymer chemistry developed rapidly since Arimoto and Haven reported the vinyl radical polymerization of ferrocene in 1955[1].
Because the space environments of protons with similar structures in polymer I are just slightly different, the absorption peaks with similar chemical shifts overlay each other and form broad multiple peaks.
There is only one vinyl group in the monomer I, which leads to the linear structure of the polymer I.
Online since: January 2014
Authors: Kun Yuan, Liu Liu, Yuan Cheng Zhu
Density functional (B3LYP) and the second–order Møller–Plesset (MP2) theoretical method investigate the geometric configurations of the D…CO (D=He, Ne, Ar, Kr and Xe) complexes
Yuan Kun1, 2,a, Zhu Yuancheng1, 2, b, Liu Liu1, 2, c
1 College of Life-science and Chemistry, Tianshui Normal University, Tianshui, 741001, China
2 Key Laboratory for New Molecule Materials Design and Function of Gansu Education Department, Tianshui, 741001, China
E-mail: a tsnuyk@163.com, b zhuyuancheng@tsnc.edu.cn, c liuliu@tsnc.edu.cn
Keywords: Density functional; The second–order Møller–Plesset; Geometric configurations; van der Waals complexes
Abstract.
Introduction In recent years, noncovalent intermolecular interaction has been implicated as an important type of interaction in many different types of physical systems and is especially of great interest within the fields of biochemistry [1, 2], material and crystal science [3, 4], and atmospheric chemistry [5, 6].
Harmonic frequency analyses were performed at the same levels to confirm that these structures were local minima on the potential energy surfaces.
Harmonic frequency analyses were performed at the same levels to confirm that these structures were local minima on the potential energy surfaces.
Introduction In recent years, noncovalent intermolecular interaction has been implicated as an important type of interaction in many different types of physical systems and is especially of great interest within the fields of biochemistry [1, 2], material and crystal science [3, 4], and atmospheric chemistry [5, 6].
Harmonic frequency analyses were performed at the same levels to confirm that these structures were local minima on the potential energy surfaces.
Harmonic frequency analyses were performed at the same levels to confirm that these structures were local minima on the potential energy surfaces.
Online since: June 2014
Authors: Jitlada Chumee, P. Khemmakama
Khemmakama1
1Department of Chemistry, Faculty of Science and Technology, Suan Sunandha Rajabhat University, Bangkok, 10300, Thailand
ajitlada.ch@ssru.ac.th, jitladachumee@yahoo.com
Keywords: Pineapple peel; Carboxymethyl cellulose; Biopolymer; Bioplastic
Abstract.
Cellulose is natural polymer, consists of glucose units with uniform chain structure.
By the way, the side reaction will be occured as showed in Eq(4) and Eq(5) [4, 5] CLL -OH + NaOH ® CLL-ONa + H2O (1) (cellulose) CLL-ONa + Cl-CH2-CO-OH ® CLL-O-CH2-COOH + NaCl (2) (cholroacetic acid) (carboxymethyl cellulose) CLL-ONa + Cl-CH2-CO-ONa ® CLL-O-CH2-COONa + NaCl (3) (sodium chloroacetate) (carboxymethyl cellulose) NaOH + Cl-CH2-CO-OH ® HO-CH2-CO-OH + NaCl (4) (cholroacetic acid) (glycolic acid) NaOH + Cl-CH2-CO-ONa ® HO-CH2-CO-ONa + NaCl (5) (sodium chloroacetate) (sodium glycolate) The CMC is a solubility biopolymer, the degree of solubility depend on substitution of a carboxymethyl group instead the hydroxyl groups in cellulose structure.
Holler, Fundamentals of Analytical Chemistry, seventh ed., Sanuders College, New York, 1996.
Cellulose is natural polymer, consists of glucose units with uniform chain structure.
By the way, the side reaction will be occured as showed in Eq(4) and Eq(5) [4, 5] CLL -OH + NaOH ® CLL-ONa + H2O (1) (cellulose) CLL-ONa + Cl-CH2-CO-OH ® CLL-O-CH2-COOH + NaCl (2) (cholroacetic acid) (carboxymethyl cellulose) CLL-ONa + Cl-CH2-CO-ONa ® CLL-O-CH2-COONa + NaCl (3) (sodium chloroacetate) (carboxymethyl cellulose) NaOH + Cl-CH2-CO-OH ® HO-CH2-CO-OH + NaCl (4) (cholroacetic acid) (glycolic acid) NaOH + Cl-CH2-CO-ONa ® HO-CH2-CO-ONa + NaCl (5) (sodium chloroacetate) (sodium glycolate) The CMC is a solubility biopolymer, the degree of solubility depend on substitution of a carboxymethyl group instead the hydroxyl groups in cellulose structure.
Holler, Fundamentals of Analytical Chemistry, seventh ed., Sanuders College, New York, 1996.
Online since: May 2011
Authors: Guo Sheng Wang, Kang Jun Wang, Jia Hou, Yu Feng Xu
The crystal structure and microstructure of the products was identified via X-ray diffraction (XRD, D/max–rA, with Cu Ka radiation).
It can be seen that all the diffraction peaks can be indexed to the phase of orthorhombic structure of single-crystalline aluminum borate Al4B2O9 with the calculated lattice parameters of a ) 1.471, b ) 1.513, and c ) 0.545 nm after calcining at 850˚C and 950˚C for 3h (Fig.1a, Fig 1b).
Tang et. al., synthesis of aluminum borate nanowires via a novel flux method[J], Materials Chemistry and Physics Vol 101(2007), p. 499 [7] Yuming Liu, Qunqing Li, Shoushan Fan, Self-catalytic growth of aluminum borate nanowires[J], Chemical Physics Letters Vol 375(2003), p. 632 [8] Xinyong Tao, Xinnan Wang, Xiaodong Li.
Chang, Synthesis and characterization of aluminum borate (Al18B4O33, Al4B2O9 ) nanowires and nanotubes, materials chemistry and physics Vol 7 (2006), p. 23 [10] Renzhi Ma, Yoshio Bando, Tadao Sato, et.al., single-crystal Al18B4O33 microtubes, J.
It can be seen that all the diffraction peaks can be indexed to the phase of orthorhombic structure of single-crystalline aluminum borate Al4B2O9 with the calculated lattice parameters of a ) 1.471, b ) 1.513, and c ) 0.545 nm after calcining at 850˚C and 950˚C for 3h (Fig.1a, Fig 1b).
Tang et. al., synthesis of aluminum borate nanowires via a novel flux method[J], Materials Chemistry and Physics Vol 101(2007), p. 499 [7] Yuming Liu, Qunqing Li, Shoushan Fan, Self-catalytic growth of aluminum borate nanowires[J], Chemical Physics Letters Vol 375(2003), p. 632 [8] Xinyong Tao, Xinnan Wang, Xiaodong Li.
Chang, Synthesis and characterization of aluminum borate (Al18B4O33, Al4B2O9 ) nanowires and nanotubes, materials chemistry and physics Vol 7 (2006), p. 23 [10] Renzhi Ma, Yoshio Bando, Tadao Sato, et.al., single-crystal Al18B4O33 microtubes, J.