Effect of Secondary Treatment on the Exothermic and Tensile Properties of Vacuum Hot-Pressed Ni/Al Energetic Structural Composites

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Abstract:

Ni/Al energetic structural materials were prepared by vacuum hot-pressing method and then treated by secondary treatment of cold rolling or cold isostatic pressing. The effects of secondary treatment on the surface morphology, the phase composition, density, exothermic properties and tensile properties of Ni/Al energetic structural materials were investigated. The results showed that the density, the reaction energy density and the sensitivity of energetic materials improved significantly by the secondary treatment of cold rolling or cold isostatic pressing. It was also found that, after cold rolling and cold isostatic pressing, the energy density increased from 780 J/g to 1089 J/g and 993 J/g, respectively, and the initial reaction temperature was advanced by 46 °C and 14°C simultaneously. This is related to the increased in the contact area between Al particles and Ni particles. Meanwhile, the tensile strength increased from 166.7 MPa to 254.8 MPa and 211.3 MPa, respectively.

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Materials Science Forum (Volume 1071)

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74-79

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October 2022

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© 2022 Trans Tech Publications Ltd. All Rights Reserved

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[1] ZHANG X F, ZHAO X N, Research progress of multifunctional energetic structural materials, Chinese Journal of Energetic Materials. 17(2009)731-739.

Google Scholar

[2] Chen Q C, Fu Q B, Chen L, Parametric Influences on the Sensitivity of Exploding Foil Initiators, Propellants Explosives Pyrotechnics. 39(2014)558-562.

DOI: 10.1002/prep.201300108

Google Scholar

[3] Shuck C E, Pauls J M, Mukasyan A S, Ni/Al energetic nanocomposites and the solid flame phenomenon, The Journal of Physical Chemistry C. 120(2016)27066-27078.

DOI: 10.1021/acs.jpcc.6b09754

Google Scholar

[4] Ji C, He Y, Wang C T, Shock-induced reaction characteristics of an Al/Ni composite processed via accumulative roll-bonding, Materials Science Forum. 879(2017)2044-2049.

DOI: 10.4028/www.scientific.net/msf.879.2044

Google Scholar

[5] Zhao H, Tan C, Yu X, et al. Enhanced reactivity of Ni-Al reactive material formed by cold spraying combined with cold-pack rolling, Journal of Alloys and Compounds. 741(2018):883-894.

DOI: 10.1016/j.jallcom.2018.01.170

Google Scholar

[6] Hunt E M, Pantoya M L, Ignition dynamics and activation energies of metallic thermites: From nano- to micron-scale particulate composites, Journal of Applied Physics. 98(2015)034909-8.

DOI: 10.1063/1.1990265

Google Scholar

[7] Yetter R A, Risha G A, Son S F, Metal particle combustion and nanotechnology, Proceedings of the Combustion Institute. 32(2009)1819-1838.

DOI: 10.1016/j.proci.2008.08.013

Google Scholar

[8] Bacciochini A, Bourdon-Lafleur S, Poupart C, Ni-Al Nanoscale Energetic Materials: Phenomena Involved During the Manufacturing of Bulk Samples by Cold Spray, Journal of Thermal Spray Technology. 23(2014)1142-1148.

DOI: 10.1007/s11666-014-0078-1

Google Scholar

[9] Manukyan K V, Mason B A, Groven L J, Tailored Reactivity of Ni+Al Nanocomposites: Microstructural Correlations, The Journal of Physical Chemistry C. 116(2012)21027-21038.

DOI: 10.1021/jp303407e

Google Scholar

[10] Herbold E B, Jordan J L, Thadhani N N, Effects of processing and powder size on microstructure and reactivity in arrested reactive milled Al+Ni, Acta Materialia. 59(2011)6717-6728.

DOI: 10.1016/j.actamat.2011.07.029

Google Scholar