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Online since: April 2009
Authors: S.V. Demishev, E.A. Goodilin, N.A. Samarin, V.V. Glushkov, N.E. Sluchanko, A.L. Chernobrovkin, A.V. Semeno, A.V. Grigorieva
In Fig. 1, the fine structure of
individual nanotubes is demonstrated.
It is visible that the tubular structure of these particles is noticeably defective as long as the V-O layers are not closed concentrically.
The SEM image of VOx-NTs (general view) and the fine structure of individual VOx-NTs.
Grigorieva, A.V.Anikina, A.B.Tarasov, E.A.Goodilin, A.V.Knot'ko, V.V.Volkov, K.A.Dembo, and Yu.D.Tretyakov: Doklady Chemistry, Vol. 410(2) (2006), p. 165 [6] V.L.
Kuznetsov: Russian Journal of Inorganic Chemistry, Vol.49(6)(2004), p. 805 [7] S.V.
It is visible that the tubular structure of these particles is noticeably defective as long as the V-O layers are not closed concentrically.
The SEM image of VOx-NTs (general view) and the fine structure of individual VOx-NTs.
Grigorieva, A.V.Anikina, A.B.Tarasov, E.A.Goodilin, A.V.Knot'ko, V.V.Volkov, K.A.Dembo, and Yu.D.Tretyakov: Doklady Chemistry, Vol. 410(2) (2006), p. 165 [6] V.L.
Kuznetsov: Russian Journal of Inorganic Chemistry, Vol.49(6)(2004), p. 805 [7] S.V.
Online since: February 2008
Authors: B.N. Zaitsev, Natalia I. Baklanova, Tatyana Zima, Anatoly Titov
Interfacial Coatings on Inorganic Fibers for High Temperature Ceramic
Matrix Composites
Natalia Baklanova1,a, Tatyana Zima
1, Anatoly Titov
2 and Boris Zaitsev
3
1
Institute of Solid State Chemistry and Mechanochemistry SB RAS, Novosibirsk 630128, Russian
Federation
2
General Institute of Geology, Geophysics and Mineralogy SB RAS, Novosibirsk 630090 Russian
Federation
3
State Scientific Center "Vector", Novosibirsk region 630559 Russian Federation
a
baklanova@solid.nsc.ru
Key words: Carbon fiber, SiC fiber, Interphase, Sol-gel, CVD
Abstract.
The behavior of coated fibers is governed by the chemistry, procedure for coating fabrication, nanostructural factors.
The electronic structure of coatings was characterized by XPS using a VG ESCALAB spectrometer equipped with facilities to obtain the surface depth profile.
The behavior of coated fibers is governed by the chemistry, procedure for coating fabrication, nanostructural factors.
The electronic structure of coatings was characterized by XPS using a VG ESCALAB spectrometer equipped with facilities to obtain the surface depth profile.
Online since: March 2026
Authors: Abdullah Uysal, Solen Kinayyigit, Lutfullah M. Dogdu, Sule Gozonunde
However, their strong interlayer bonding limits efficient exfoliation into few-layer structures.
A typical hexagonal structure corresponding to hBN was clearly visible in Figure 1.
Coleman, Graphene dispersion and exfoliation in low boiling point solvents, Journal of Physical Chemistry C 115 (2011). https://doi.org/10.1021/jp110942e
Connell, Defect functionalization of hexagonal boron nitride nanosheets, Journal of Physical Chemistry C 114 (2010). https://doi.org/10.1021/jp105454w
Optical properties and electronic structure of amorphous germanium.
A typical hexagonal structure corresponding to hBN was clearly visible in Figure 1.
Coleman, Graphene dispersion and exfoliation in low boiling point solvents, Journal of Physical Chemistry C 115 (2011). https://doi.org/10.1021/jp110942e
Connell, Defect functionalization of hexagonal boron nitride nanosheets, Journal of Physical Chemistry C 114 (2010). https://doi.org/10.1021/jp105454w
Optical properties and electronic structure of amorphous germanium.
Online since: January 2004
Authors: K.H.J. Buschow, Wolfgang Schäfer
Neutron diffraction on Er5Mg24 and Tm5Mg24 is aimed at both crystal structure refinements and
magnetic structure determinations.
The compounds have the Ti5Re24-type structure which is a derivative of the �-Mn structure.
The room temperature diffraction patterns (Fig. 1) were used for crystal structure refinements based on the earlier structure determination by X-ray photography by Kripyakevich et al. [10].
The refined structure parameters are compiled in Table 1 together with the list of interatomic R Mg distances representing the large number of intermetallic connections within this structure.
Palenzona: in Handbook on the Physics and Chemistry of the Rare Earths (North Holland Publ.
The compounds have the Ti5Re24-type structure which is a derivative of the �-Mn structure.
The room temperature diffraction patterns (Fig. 1) were used for crystal structure refinements based on the earlier structure determination by X-ray photography by Kripyakevich et al. [10].
The refined structure parameters are compiled in Table 1 together with the list of interatomic R Mg distances representing the large number of intermetallic connections within this structure.
Palenzona: in Handbook on the Physics and Chemistry of the Rare Earths (North Holland Publ.
Online since: November 2011
Authors: Xiao Di Niu, Can Can Sun, Jing Long Tang, Hong Su Wang
HCNO originates primarily from the oxidation of acetylene.[1-11]
As a result, the subsequent chemistry of HCNO is of great interest in the overall NO-reburning mechanism.
Several photolysis products are energetically possible at a 248 nm photolysis wavelength [15] Information on the relative quantum efficiencies of these products is not available, but it is apparent that the products observed upon photolysis of a HCNO/SF6 mixture may be formed either directly by photolysis or by further chemistry of radicals formed in reaction 11 with HCNO itself.
The potential energy surface (PES) involving the main structures of the OH + HCNO reaction calculated at the CCSD(T)/6-311G(d,p)//B3LYP/6-311G(d,p)+ZPVE level is shown in Fig. 3 (a). 3.1 The scanned procedure for the starting step R → a1 and R → a3 In Figure 3 (a), the step R→ a1 and R → a3 are taken as the common starting step for some pathways in the reaction NH + HCNO.
Our B3LYP/6-311G(d,p) IRC calculations starting at the d1 indicate that the HC(O)NNH goes to a (Cs) structure of d2, d3 in one direction and to a (C1) structure of d4 in the other direction.
Several photolysis products are energetically possible at a 248 nm photolysis wavelength [15] Information on the relative quantum efficiencies of these products is not available, but it is apparent that the products observed upon photolysis of a HCNO/SF6 mixture may be formed either directly by photolysis or by further chemistry of radicals formed in reaction 11 with HCNO itself.
The potential energy surface (PES) involving the main structures of the OH + HCNO reaction calculated at the CCSD(T)/6-311G(d,p)//B3LYP/6-311G(d,p)+ZPVE level is shown in Fig. 3 (a). 3.1 The scanned procedure for the starting step R → a1 and R → a3 In Figure 3 (a), the step R→ a1 and R → a3 are taken as the common starting step for some pathways in the reaction NH + HCNO.
Our B3LYP/6-311G(d,p) IRC calculations starting at the d1 indicate that the HC(O)NNH goes to a (Cs) structure of d2, d3 in one direction and to a (C1) structure of d4 in the other direction.
Online since: December 2012
Authors: Amirhossein Fallah, Davood Kordestani, Abdolhamid Alizadeh, Salasiah Endud
Supported Palladium Catalysis using a Biguanide N-donor Motif on Mesoporous silica for Suzuki–Miyaura Coupling Reaction
AMIRHOSSEIN FALLAH1, a, DAVOOD KORDESTANI2,b
ABDOLHAMID ALIZADEH2,3,c , and SALASIAH ENDUD1,d
1Department of Chemistry, Faculty of Science, Universiti Teknologi Malaysia, 81310 UTM Skudai, Johor Bharu, Malaysia
2 Chemistry Department, and 3Nanoscience & Nanotechnology Research Center (NNRC), Razi University, Kermanshah 67149, Iran
aamir_fallah@hotmail.com, bdavood_k82@yahoo.com, cahalizadeh2@hotmail.com, dsalasiah@kimia.fs.utm.my
Keywords: Heterogeneous catalysts, Mesoporous SBA-15, Suzuki coupling, Biguanides
Abstract.
The SEM micrographs of Pd@SBA-15/Met reveal that the metformin-functionalized structure consists of short rod-shaped particles of 1500-2000 nm in length and 450–550 nm in diameter.
The illustrated isotherms for all materials were Type IV with a H1 hysteresis loop and a steep increase in adsorption at relative pressures of 0.6-0.8 for SBA-15 samples attributed to capillary nitrogen condensation according to IUPAC classification, which is typical for mesoporous materials with ordered pore structures [19].
Table 1, Pore structure parameters of SBA-15 and Pd@SBA-15/Met.
The SEM micrographs of Pd@SBA-15/Met reveal that the metformin-functionalized structure consists of short rod-shaped particles of 1500-2000 nm in length and 450–550 nm in diameter.
The illustrated isotherms for all materials were Type IV with a H1 hysteresis loop and a steep increase in adsorption at relative pressures of 0.6-0.8 for SBA-15 samples attributed to capillary nitrogen condensation according to IUPAC classification, which is typical for mesoporous materials with ordered pore structures [19].
Table 1, Pore structure parameters of SBA-15 and Pd@SBA-15/Met.
Online since: August 2013
Authors: Mostafa Fakharifar, Zhi Bin Lin, Cheng Lin Wu, Shruti Mahadik-Khanolkar, Nicholas Leventis, Gen Da Chen
Microstructural Characteristics of Polyurea and Polyurethanexerogels for Concrete Confinement with FRP System
Mostafa Fakharifar1,a, Zhibin Lin1,b,Chenglin Wu1,c, ShrutiMahadik-Khanolkar2,d, Nicholas Leventis2,e and Genda Chen1,f
1Department of Civil, Architectural, and Environmental Engineering, Missouri University of Science and Technology, Rolla, MO 65409-0030
2Department of Chemistry, Missouri University of Science and Technology, Rolla, MO 65401 USA.
Such materials, including those based on polyurea [5] and polyurethane [6]can provide the durability and flexibility, and prevent the brittle failure of certain core structures.
Stress-strain curves of PUAxerogelswith various bulk densities I)initial II) 50% strain III) 80% strain a) Compression of a typical polymer xerogel b) Initial pore structure (0.22 g cm-3) c) at 50% strain d) at 80% strain Fig. 3.
Closure of pore structures under compression is responsible for such low transverse strains, as observed from a series of SEM micrographs in Figs. 3(b) through 3(d).
Scherer: The Physics and Chemistry of Sol-Gel Processing(Academic Press, New York1990)
Such materials, including those based on polyurea [5] and polyurethane [6]can provide the durability and flexibility, and prevent the brittle failure of certain core structures.
Stress-strain curves of PUAxerogelswith various bulk densities I)initial II) 50% strain III) 80% strain a) Compression of a typical polymer xerogel b) Initial pore structure (0.22 g cm-3) c) at 50% strain d) at 80% strain Fig. 3.
Closure of pore structures under compression is responsible for such low transverse strains, as observed from a series of SEM micrographs in Figs. 3(b) through 3(d).
Scherer: The Physics and Chemistry of Sol-Gel Processing(Academic Press, New York1990)
Online since: February 2013
Authors: Hai Feng Wang, Yu Bing Ma, Yan Feng Lao, Meng Chen Lu
The Process Condition Research of SrAl2O4: Eu2+, Dy3+ Luminous Powder by Microwave Method
Haifeng Wang1, a *, Yubing Ma2, b, Yanfeng Lao1, c and Mengchen Lu1, d
1*College of Materials Science and Engineering, Donghua University, 2999 North Renmin Road, Songjiang, Shanghai 201620, China
2College of chemistry, chemical Engineering and biotechnology, Donghua University, 2999 North Renmin Road, Songjiang, Shanghai 201620, China
awhf2008@dhu.edu.cn, bxuexiuye@sina.com, c1083483276@qq.com, dkirstenlmc@hotmail.com
Keywords: Rare earth, Luminescent material, Microwave method.
It was found that the composition and structure of the powders are similar in this experiment.
It can be inferred that the SrAl2O4 crystal structure is little affected by the rare earth active ions.
So the structure of crystallization and the center of luminescence are good.
Holsa, et al., Persistent luminescence phenomena in materials doped with rare earth ions, Journal of Solid State Chemistry. 171 (2003) 114-122
It was found that the composition and structure of the powders are similar in this experiment.
It can be inferred that the SrAl2O4 crystal structure is little affected by the rare earth active ions.
So the structure of crystallization and the center of luminescence are good.
Holsa, et al., Persistent luminescence phenomena in materials doped with rare earth ions, Journal of Solid State Chemistry. 171 (2003) 114-122
Online since: September 2013
Authors: Qi Xing Zhou, Meng Meng Wang
These functions of biochar are believed to attribute to its porous structure, an increase of the nutrient use efficiency and apparent stability.
Biochar has stable aromatic structures.
The result can be explained by weakening of nitrification and the change of microbial community structure leaded by biochar.
:Journal of Environmental Chemistry.Vol. 30(2011), p.11 [29]Aijun L, Xuhong Z, etal.
:Environmental Chemistry.Vol. 31(2012), p.64-68 [31]Oleszczuk P, Hale S, Lehmann J, et al.
Biochar has stable aromatic structures.
The result can be explained by weakening of nitrification and the change of microbial community structure leaded by biochar.
:Journal of Environmental Chemistry.Vol. 30(2011), p.11 [29]Aijun L, Xuhong Z, etal.
:Environmental Chemistry.Vol. 31(2012), p.64-68 [31]Oleszczuk P, Hale S, Lehmann J, et al.
Online since: April 2010
Authors: Karin Larsson, D. Siche, Rositza Yakimova, Mikael Syväjärvi, Chariya Virojanadara, Daniela Gogova, Leif I. Johansson
Johansson
1,g
1
Dept. of Physics, Chemistry and Biology, Linkoping University, SE-581 83 Linköping, Sweden
2
Leibniz Institute for Crystal Growth, 12 489 Berlin, Germany
3
Dept. of Materials Chemistry, Uppsala University, Box 538, 751 21, Uppsala, Sweden
a
roy@ifm.liu.se, bchavi@ifm.liu.se, cgogova@ikz-berlin.de, dmsy@ifm.liu.se,
e
siche@ikz-berlin.de, fkarin.larsson@mkem.uu.se, glejoh@ifm.liu.se
Keywords: sublimation, high temperature, Ar pressure, ARPES, LEEM, DFT
Abstract.
Moreover, SiC is a good template because of the similar hexagonal structure and the possibility to decompose SiC by leaving C to reside on the substrate.
Under heating the formation of surface phases on Si-terminated SiC (0001) surface is well known to undergo the following modifications: from Si rich (3x3) structure - through the intermediate (1x1) and (√3 x√3) - R30 o structures, to the C-rich (6√3 x 6√3) phase, and finally epitaxial graphene.
Moreover, SiC is a good template because of the similar hexagonal structure and the possibility to decompose SiC by leaving C to reside on the substrate.
Under heating the formation of surface phases on Si-terminated SiC (0001) surface is well known to undergo the following modifications: from Si rich (3x3) structure - through the intermediate (1x1) and (√3 x√3) - R30 o structures, to the C-rich (6√3 x 6√3) phase, and finally epitaxial graphene.