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Online since: November 2011
Authors: Xu Duo Bai, Bin Li, Lin Zhang, Hai Jun Niu
Electrochemical synthesis of POT for electrochromic and solar cell materials
Bin Li, Haijun Niua *, Lin Zhang, Xuduo Baib *
Key Laboratory of Functional Inorganic Material Chemistry (Heilongjiang University), Ministry of Education, Key laboratory macromolecular chemistry, Heilongjiang University, Harbin, P R China
ahaijunniu@hotmail.com, bxuduobai@hotmail.com
*corresponding author
Keywords: POT, optoelectronics conversion, electrochromic, photocurrent.
This resulting polymer was used for the research on chemical structure and electrochromic properties.
Due to the effect of the acid protonation, the resonance structure formed, the electron density of the quinoid structure in the polymer chains descended, the character of C=N weakened, conjugation and the delocalization of electron in the polymer chains was enhanced.
This resulting polymer was used for the research on chemical structure and electrochromic properties.
Due to the effect of the acid protonation, the resonance structure formed, the electron density of the quinoid structure in the polymer chains descended, the character of C=N weakened, conjugation and the delocalization of electron in the polymer chains was enhanced.
Online since: August 2011
Authors: Guo Liang Pan, Chun Ying Guo, Li Xian Wang, Qiang Guo
Study on coloring protective composite oxide film on aluminum surface
WANG Li-xian1,2,a, GUO Qiang1, b,*,PAN Guo-liang1,c and GUO Chun-ying3, d
1School of Materials Science and Engineering, Shanghai University, Shanghai 201800, China
2School of Chemistry and Environment Engineering, Shanghai Institute of Technology, Shanghai 200235, China
3Institute of Chemistry, Hebei Normal University, Hebei 050091, China
awlx17602@yahoo.com.cn, b,*guoq@shu.edu.cn, cpangl @shu.edu.cn, dguochunying_0@163.com
Keywords: Aluminum; Anodizing oxide film; Coloring; Permanent protective property; Decoration
Abstract.
Furthermore, azobenzene malonyl arylamine colorant with a high symmetric structure [11] will be introduced to the surface of AAO film by in-situ synthesis.
Type of film Density (g·cm-3) Porosity (%) Thickness (µm) Traditional AAO film 2.52 36.4 >20 Composite AAO film 3.53 10.6 >20 Composition and structure of composite AAO film.
Composition and structure of colored AAO film.
Furthermore, azobenzene malonyl arylamine colorant with a high symmetric structure [11] will be introduced to the surface of AAO film by in-situ synthesis.
Type of film Density (g·cm-3) Porosity (%) Thickness (µm) Traditional AAO film 2.52 36.4 >20 Composite AAO film 3.53 10.6 >20 Composition and structure of composite AAO film.
Composition and structure of colored AAO film.
Online since: July 2011
Authors: Sheng Kui Zhong, Yue Bin Xu, Yan Wei Li, Chang Jiu Liu, Yan Hong Li
Synthesis and characterization of LiNi0.4Co0.2Mn0.4O2 cathode material via urea co-precipitation method
ZHONG Sheng-kui1,2,a, XU Yue-bin1,b, LI Yan-wei1,c,
LIU Chang-jiu1,d ,LI Yan-hong3,e
(1 College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, P.
The XRD, SEM and electrochemical measurements were used to examine the structure,morphology and electrochemical characteristics, respectively.
It’s hard to prepare LiNiO2 and the crystal structure will change during the charge-discharge process, resulting in much attenuation of its capacity[4].
LiMnO2 with layered structure has high theoretical specific capacity of 285 mAh·g-1.
However, during the process of charging and discharging, the structure easily change to the spinel structure, resulting in capacity’s fast attenuation[5].
The XRD, SEM and electrochemical measurements were used to examine the structure,morphology and electrochemical characteristics, respectively.
It’s hard to prepare LiNiO2 and the crystal structure will change during the charge-discharge process, resulting in much attenuation of its capacity[4].
LiMnO2 with layered structure has high theoretical specific capacity of 285 mAh·g-1.
However, during the process of charging and discharging, the structure easily change to the spinel structure, resulting in capacity’s fast attenuation[5].
Online since: May 2016
Authors: Ctislav Fiala, Petr Hájek, Antonín Lupíšek
(c) Dismountable structures: Precast concrete structures can be designed as dismountable enabling consequential utilization of structural elements.
Fig. 2 Experimental verification of waffle floor Fig. 3 Prototype of panel with lightening structure from HPC elements from recycled material Stered Timber-concrete Composite Structures The composite structures based on high performance silicates and wood represent the beneficial alternative to the timber floor structures.
Above-mentioned disadvantages of timber floor structures can be just effectively reduced by utilization timber-concrete composite floor structures.
References [1] Royal Society of Chemistry. 2008.
The concrete conundrum, Chemistry World, March 2008, pp. 62-66
Fig. 2 Experimental verification of waffle floor Fig. 3 Prototype of panel with lightening structure from HPC elements from recycled material Stered Timber-concrete Composite Structures The composite structures based on high performance silicates and wood represent the beneficial alternative to the timber floor structures.
Above-mentioned disadvantages of timber floor structures can be just effectively reduced by utilization timber-concrete composite floor structures.
References [1] Royal Society of Chemistry. 2008.
The concrete conundrum, Chemistry World, March 2008, pp. 62-66
Online since: March 2014
Authors: Chen Wang, Tong Xiang Liang, Li Min Dong, Jie Mo Tian, Han Lin
Structure and Properties of Irradiation Crosslinked UHMWPE
Han Lin1,a, Limin Dong2,b *, Chen Wang1, Tongxiang Liang2, Jiemo Tian2
1State Key Lab of New Ceramics and Fine Processing, Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China
2Beijing Key Lab of Fine Ceramics, Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China
a492174178@qq.com, bdonglm@mail.tsinghua.edu.cn
Keywords: UHMWPE, γ-rays, cross-link, mechanical properties
Abstract.
To analyze the structural change of UHMWPE, the author used Fourier infrared spectrum analyzer to test the nature of the samples and internal chemical combination, to analyze the samples of crosslinking, and to study the effect of structure on performance.
After irradiation, Macromolecular chain was interrupted into active free radicals; these free radicals form crosslinking with each other, which changed the UHMWPE to 3D mesh structure.
Conclusions With the increase of radiation doze, the impact properties decline gradually; which means UHMWPE become harder and more brittle.We can see that, through the infrared spectrum, chain structure of the material are destroyed and reform the mesh structure.
Nho, Radiation Physics and Chemistry. 60(2001) 79-87.
To analyze the structural change of UHMWPE, the author used Fourier infrared spectrum analyzer to test the nature of the samples and internal chemical combination, to analyze the samples of crosslinking, and to study the effect of structure on performance.
After irradiation, Macromolecular chain was interrupted into active free radicals; these free radicals form crosslinking with each other, which changed the UHMWPE to 3D mesh structure.
Conclusions With the increase of radiation doze, the impact properties decline gradually; which means UHMWPE become harder and more brittle.We can see that, through the infrared spectrum, chain structure of the material are destroyed and reform the mesh structure.
Nho, Radiation Physics and Chemistry. 60(2001) 79-87.
Online since: January 2007
Authors: Min Hye Kim, Young Uk Kwon, Ji Man Kim
Intimate Heterojunction Structure between Titania and
Polythiocyanogen and Its Photovoltaic Effect
Min-Hye Kima , Ji Man Kim
b and Young-Uk Kwon
c,*
Department of Chemistry and BK-21 School of Molecular Science, Sungkyunkwan University,
Suwon 440-746, Korea
a
morning204@skku.edu, bjimankim@skku.edu,
cywkwon@skku.edu
Keywords: mesoporous titania, electrodeposition, conducting polymer, heterojunction, solar cell,
thin film
Abstract A heterojunction structure between a cubic structured mesoporous titania thin film and
polythiocyanogen inside the pores was prepared by electrodeposition technique.
In addition, this heterojunction structure was fabricated into a photovoltaic cell and the cell performance was tested.
This appears to match well with the electronic structure of titania for conversion of photon into electricity.
Possible band structures of TiO2/poly Fig 6.
Each of the two semiconductor materials has 3D network structure of the length scale of 10nm, and they are interconnected to each other, providing a very large contact area, which may be advantageous for utilizing the heterojunction structure.
In addition, this heterojunction structure was fabricated into a photovoltaic cell and the cell performance was tested.
This appears to match well with the electronic structure of titania for conversion of photon into electricity.
Possible band structures of TiO2/poly Fig 6.
Each of the two semiconductor materials has 3D network structure of the length scale of 10nm, and they are interconnected to each other, providing a very large contact area, which may be advantageous for utilizing the heterojunction structure.
Online since: April 2008
Authors: Josef Jirák, Miroslav Vlček, Petr Mošner, Ladislav Koudelka
Study of Lithium-Lead Phosphate and Borophosphate Glasses
Petr Mošner a
, Ladislav Koudelkab, Josef Jirákc and Miroslav Vlčekd
Department of General and Inorganic Chemistry, Faculty of Chemical Technology,
University of Pardubice, 532 10 Pardubice, Czech Republic
a
petr.mosner@upce.cz, bladislav.koudelka@upce.cz, cjosef.jirak@student.upce.cz,
d
miroslav.vlcek@upce.cz
Keywords: glasses, phosphate, borophosphate, structure, properties.
The 31P MAS NMR and Raman spectra show that at all glass series with the replacement of PbO by Li2O the ratio of Q 2/Q 1 units, present in the structure, slightly increase.
Our recent studies of K2O-PbO-B2O3-P2O5 [1] and Na2O-PbO-B2O3-P2O5 [2] glasses revealed substantial changes in their structure and properties with compositional changes.
The reason for the decrease of VM is the gradual crosslinking of network structure by BO4 and BO3 borate groups interconnecting phosphate chains.
This shift gives evidence for the dominant function of Q 2 groups in the structure of 50Li2O-10B2O3- 40P2O5.glass.
The 31P MAS NMR and Raman spectra show that at all glass series with the replacement of PbO by Li2O the ratio of Q 2/Q 1 units, present in the structure, slightly increase.
Our recent studies of K2O-PbO-B2O3-P2O5 [1] and Na2O-PbO-B2O3-P2O5 [2] glasses revealed substantial changes in their structure and properties with compositional changes.
The reason for the decrease of VM is the gradual crosslinking of network structure by BO4 and BO3 borate groups interconnecting phosphate chains.
This shift gives evidence for the dominant function of Q 2 groups in the structure of 50Li2O-10B2O3- 40P2O5.glass.
Online since: February 2012
Authors: Ren Feng Li, Kun Zhao, Xue Bin Li, Jin Qing Jiang, San Hu Wang
The secondary structure analysis of TbpA protein.
It can perform many additional tasks, including de novo modeling of loops in protein structures, optimization of various models of protein structure with respect to a flexibly defined objective function, multiple alignments of protein sequences and/or structures, clustering, searching of sequence databases, comparison of protein structures.
Current Topics in Medicinal Chemistry 2001, 1(1): 7-30
Comparative protein structure modeling of genes and genomes [J].
Comparative Protein Structure Modeling With MODELLER [J].
It can perform many additional tasks, including de novo modeling of loops in protein structures, optimization of various models of protein structure with respect to a flexibly defined objective function, multiple alignments of protein sequences and/or structures, clustering, searching of sequence databases, comparison of protein structures.
Current Topics in Medicinal Chemistry 2001, 1(1): 7-30
Comparative protein structure modeling of genes and genomes [J].
Comparative Protein Structure Modeling With MODELLER [J].
Online since: January 2013
Authors: Yong Gang Wang, Ming Jun Yang, Xiao Feng Liu, Jing Wu
Lanzhou, China
*a email yangmj@lut.cn
b email 412316788@163.com
c email 18009400938@163.com
d email wujing@163.com
Keywords Paecilodepsipeptide A; Total synthesis; Anti-tumor
Abstract paecilodepsipeptide A was first synthesized by retrosynthesis methods. the structures were determined by Mass Spectrometry and NMR spectroscopy, and the anti-tumor activities on human hepatocellular carcinoma cell line (SMMC-7721) and human lymphoma cell line (Raji) were examined by MTT.
The structures of the synthesized product were identified by 1H NMR and 13C NMR spectra, which is identical to the natural product.
In this paper, Paecilodepsipeptide A was synthesized by retrosynthesis methods. the structures of the synthesized product were identified by 1H NMR and 13C NMR spectra. and the anti-tumor activities on human hepatocellular carcinoma cell line (SMMC-7721) and human lymphoma cell line (Raji) were examined by MTT [2].
Retrosynthetic analysis of Paecilodepsipeptide A Intermediate 3 was prepared efficiently according to literature procedures from dipeptide 5 and tripeptide 4, which were obtained by the standard peptide chemistry method[3] from amino acid fragments 7-11.
The structures of the synthesized product were identified by 1H NMR and 13C NMR spectra, which is identical to the natural product [1].
The structures of the synthesized product were identified by 1H NMR and 13C NMR spectra, which is identical to the natural product.
In this paper, Paecilodepsipeptide A was synthesized by retrosynthesis methods. the structures of the synthesized product were identified by 1H NMR and 13C NMR spectra. and the anti-tumor activities on human hepatocellular carcinoma cell line (SMMC-7721) and human lymphoma cell line (Raji) were examined by MTT [2].
Retrosynthetic analysis of Paecilodepsipeptide A Intermediate 3 was prepared efficiently according to literature procedures from dipeptide 5 and tripeptide 4, which were obtained by the standard peptide chemistry method[3] from amino acid fragments 7-11.
The structures of the synthesized product were identified by 1H NMR and 13C NMR spectra, which is identical to the natural product [1].
Online since: May 2025
Authors: Mudrik Alaydrus, Sunaryono Sunaryono, Ahmad Taufiq, Erfan Handoko, S.T. Ulfawanti Intan Subadra, Wida Agista, Davin Alana Putra, Nur Ezaan Khamsan
Based on the XRD data, the Fe3O4/MWCNT/TiO2 nanocomposite structure showed a cubic spinel structure, and Fe3O4 nanoparticles had a crystallite size of 14.26 nm.
Atomic structure and electronic properties of single-walled carbon nanotubes.
Materials Chemistry and Physics, 265, 124476. https://doi.org/10.1016/j.matchemphys.2021.124476 [57] Mamun, A. al, AlSaadi, M.
Materials Chemistry and Physics, 317, 129169. https://doi.org/10.1016/j.matchemphys.2024.129169 [63] P.K.
Self-healable ZnO@ multiwalled carbon nanotubes (MWCNTs) /DA-PDMS nanocomposite via Diels-Alder chemistry as microwave absorber: A novel multifunctional material.
Atomic structure and electronic properties of single-walled carbon nanotubes.
Materials Chemistry and Physics, 265, 124476. https://doi.org/10.1016/j.matchemphys.2021.124476 [57] Mamun, A. al, AlSaadi, M.
Materials Chemistry and Physics, 317, 129169. https://doi.org/10.1016/j.matchemphys.2024.129169 [63] P.K.
Self-healable ZnO@ multiwalled carbon nanotubes (MWCNTs) /DA-PDMS nanocomposite via Diels-Alder chemistry as microwave absorber: A novel multifunctional material.