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Online since: January 2009
Authors: Jing Feng Wang, Yao Bo Hu, Fu Sheng Pan
The results show that the TiO2 thin film is in monolayer with nanometer level, the deposition is the anatase structure.
Special physical chemical properties can be attained by a kind of specific group is adhibitted into interspace of the alkyl chains because the molecular structure and surface structure of group can be selected.
The TiO2 thin film calcined at 723 K for 2 h constructs with copoint or coedge tetrahedrons (Fig. 6) that its structure is analogous to that of anatase.
This characteristic can be explained by the structure of silane coupler [15].
Lin: Thin Solid Films Vol. 382 (2001), p. 153 [10] ZHANG Dekai, HU Xiaoyun, LI Ting, HUANG YANA, Ma Yiping and LI Lisha: Acta Photonica Sinica Vol. 33 (2004), p. 982 [11] HONG Guangyan, in: Inorganic solid chemistry, Science Press (2008)
Online since: April 2012
Authors: Fei Wang, Ming Ming Cheng, Lin Jing Ma, Chao Fan
In the structure of sepiolite, three forms of water exist, namely: adsorbed water, crystal water and hydroxyl water.
However, desorption of crystal water does not destroy the framework of sepiolite structure completely.
Gok: Journal of Molecular Structure, Vol. 1007(2012), p. 36 [17]L.
Olano:Food Chemistry, Vol.76(2002), p. 7 [19]M.
Olano: Food Chemistry, Vol. 66(1999), p. 301 [20]V.
Online since: July 2011
Authors: Xiao Qiu Yang, Wei Chang Ke, Yi Kun Chen, Xiang Hong Peng, Chao Zhu, Guo Xi Xiong
Synthesis and Characterization of the Water-Soluble Oleoyl Acetyl Chitosan Weichang, Ke1,a, Yikun,Chen1,b,Guoxi, Xiong1,c, Xianghong Peng2,a, Chao Zhu2,b, Xiaoqiu, Yang2,c 1 Technology Center of China Tobacco Industrial LLC, Wuhan 430040, China 2 College of Chemistry and Environmental Engineering, Jianghan University, Wuhan 430056, China 1a email: brouce434@sohu.com 2a email: pengxianghong103@163.com Keywords: Oleic acid, chitosan, synthesis, water soluble, thionyl dichloride.
The chemical structure of the OACh was characterized by FT-IR, 1H and 13C NMR.
Some progresses have been reported in the preparation of water-soluble chitosan derivatives, such as N-lauryl-N-methylene phosphonic chitosan, N-carboxymethylated chitosan, N-acetylchitosan, N-trimethyl chitosan chloride, N-methylated chitosans and N-phthaloylcarboxymethylchitosan. [3-6] As reported, long-chain fatty acids, including the oleic acid, linoleic acid and palmitic acid, have been used as a hydrophobic moiety for the formation of chitosan micelles.[7] Chitosan fatty acid conjugates can be formed the nanomicelles with a hydrophobic core and hydrophilic shell structure in aqueous solution.
The structure of oleoyl acetyl chitosan was characterized by FT-IR and NMR.
Online since: December 2014
Authors: Aleksandr S. Verevkin, Anatoly A. Popovich, Nikolay Razumov
The effect of the mechanical alloying and nitriding time on the structure and properties of Sm-Fe-N alloys were studied in the course of the research.
The investigation of the obtained alloys structure was carried out using the Mira Tescan scanning electron microscope.
In reference with the above, it should be noted that mechanical alloying modes were selected to obtain a powder with a partially amorphous structure (the shaded area).
It allowed getting almost a single-phase fine-grained structure Sm2Fe17 (Fig. 2b).
D Coey, Rare-earth Iron Permanent Magnets (Monographs on the Physics and Chemistry of Materials), Oxford University Press, 1996
Online since: May 2013
Authors: Abu Bakar Mohamad, Ali Salehabadi
More importantly, the rich intercalation chemistry of clay silicate can be used to facilitate exfoliation of silicate nanolayers into the polymer network.
The bulk structure of ENR-50 containing 3% MMT shows pore structure with aerogel appearance where the nanoclays have partially interacted with the ENR-50.
In the hybrid structure containing 3% MMT, a similar structure is observed, however the extent of exfoliation differs.
Pinnavaia, Hybrid Organic−Inorganic Nanocomposites Formed from an Epoxy Polymer and a Layered Silicic Acid (Magadiite), Chemistry of Materials. 8 (1996) 2200–2204
Pinnavaia, Hybrid Organic−Inorganic Nanocomposites:  Exfoliation of Magadiite Nanolayers in an Elastomeric Epoxy Polymer, Chemistry of Materials. 10 (1998) 1820–1826
Online since: March 2012
- Polymer nanocomposites are materials in which at least one of the phases has at least one dimension of the order of nanometers, or structures having nano-scale repeat distances between the different phases that make up the material.
Several researchers in fields of Polymer physic, chemistry and engineering show great interest for developing high-performance of polymer micro and nanocomposites systems i.e. : improved barrier properties, fire resistance, strength… The Conference on Multiphase Polymers and Polymer Composites Systems: Macro to Nano Scales was organized at Paris-Est Créteil University, France on June 7-10, 2011.
The content of the conference was unique since a particular attention was focused to the different length scales (macro, micro and nano) relevant for a deep understanding of the structure-property relationships of nanocomposite materials.
Online since: November 2014
Authors: Jian Huang, Ke Tang, Lin Jun Wang, Bing Ren, Hong Ze Yu, Jun Nan Wang, Yi Ming Yang
The special structures and properties of boron and boron-rich borides are attributed to their original three-center electron-deficient bonds.
It is useful and meaningful to investigate the effects of sputtering power on the structure and properties of B films.
Influence of sputtering power on structure, surface topography and chemical composition of B films were studied and discussed.
Donohue, The Structures of the Elements, Krieger, Malabar, New Jersey, 1982
[5] Zhongke Wan, Yoshiki Shimizu, et al., Fabrication of crystallized boron films by laser ablation, Journal of Solid State Chemistry. 177 (2004) 1639–1645
Online since: July 2020
Authors: Zulkarnain Zainal, Zainal Abdib Talib, Asla A. Al-Zahranil, Araa Mebdir Holi, Hong Ngee Lim
High-resolution transmission electron microscopy (HR-TEM) with selected area (SAED) and electron energy-loss spectroscopy (EELS) modes in Tecnai TF20 x-twin FEI system evaluated the structure, nature of the crystalline phase, lattice fringe and chemical structure.
The surface morphological structure of ZnO NRAs and Ag2S/ZnO NRAs/ITO annealed at different temperatures were investigated by FE-SEM.
Crystal structure of the representative sample (Ag2S/ZnO NRAs-400 ºC) and interplanar distances were determined for single Ag2S nanoparticles by HR-TEM analysis.
Journal of Materials Chemistry C, 7 (2019) 3988-4003
J., “Optical Properties and Electronic Structure of Amorphous Germanium,” phys. stat. sol., 15(1966) 627–637
Online since: March 2013
Authors: Xiao Wu Li, Guang Ping Zhang, Wen Yang, Yun Jiang, Hong Mei Ji
Li1,3* 1 Institute of Materials Physics and Chemistry, College of Sciences, Northeastern University, Shenyang 110004, P.R.
The outer layer presents a porous blocky structure for Clinocardium californiense shell and a layered structure for Veined rapa whelk shell.
In 1972, Taylor and Layman [1] divided the microstructures of shells into 8 main kinds with individual characteristics, including simple prismatic structure, composite prismatic structure, sheet nacreous structure, lenticular nacreous structure, foliated structure, crossed-lamellar structure, complex crossed-lamellar structure and homogeneous structure.
In short, the inner and middle layers of both shells exhibit a cross-lamellar structure, but there are some differences in the morphology and dimension between those structures, whereas the major difference in the structure of these two shells comes from the outer layer, i.e., a porous and blocky structure for Clinocardium californiense shell, and a layered structure for Veined rapa whelk shell.
(1) Both shells present a hierarchical structure, and their inner and middle layers exhibit cross-lamellar structures.
Online since: January 2013
Authors: Agus Haryono, Sri Budi Harmami, Dewi Sondari
Preparation of Magnetite Nanoparticles by Thermal Decomposition of Iron (III) Acetylacetonate with Oleic Acid as Capping Agent Agus Haryono1,a, Sri Budi Harmami1 and Dewi Sondari1 1Polymer Chemistry Group, Research Center for Chemistry Indonesian Institute of Sciences (LIPI) Kawasan Puspiptek Serpong, Tangerang 15314, INDONESIA Tel.: +62-21-7560929, Fax: +62-21-7560549 aharyonolipi@yahoo.com; agus.haryono@lipi.go.id Keywords: magnetite, nanoparticle, thermal decomposition, wastewater Abstract.
The morphology and chemical structure of the obtained magnetite nanoparticle was characterized by using of Transmition Electron Microscopy (TEM) and Fourier-Transformed Infrared (FTIR) spectroscopy.
The chemical structure of oleic acid molecules adsorbed on the nanoparticles surface was discussed and reviewed in order to evaluate the important developments in the application of magnetite nanoparticles for wastewater treatment.
The chemical structure of the oleic acid interaction on the magnetite nanoparticles, showed in Fig. 2.
Schwertmann, The Iron Oxide: Structure, Properties, Reaction, Occurrence and Used, second ed., VCH Publisher, Weinheim, 2003