Luminescence of SrAl2O4:Eu2+, Dy3+ Ceramics Synthesized at Different Firing Condition

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The green SrAl2O4:Eu2+, Dy3+ phosphor is a well-known persistent material for a wide region of applications such as lighting, traffic signs, interior decoration and medical application. Double activated SrAl2O4:Eu2+, Dy3+ with improved properties has been synthesized through solid state route at different firing atmospheres (reduction, vacuum, oxygen and CO2 wet gas) and heating times (1 h to 8 h). At the beginning the powders were heat treated for 2 h with a heating rate of 10°C/min. The phosphor prepared at different firing atmospheres and heating times exhibited a different wavelength and intensity of PL spectra. The emission intensity becomes stronger as the heating times increases from 1 h to 4 h. The difference found from these spectra maxima is rationalized based on the presence of intermediate phases and also on the diffusion activities of activator and co-activator in the host matrices.

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284-288

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December 2012

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] Y. Lin, Z. Zhang, F. Zhang, Z. Tang and Q. Chen: Mater Chem Phys Vol. 65 (2000), pp.103-106.

Google Scholar

[2] V. Singh, J.J. Zhu, M. Tiwari, M. Soni, M. Aynayas, S.H. Hyun, R. Narayanan, M. Mohapatra and V. Natarajan: Journal of Non-Crystalline Solids Vol. 355 (2009), pp.2491-2495.

DOI: 10.1016/j.jnoncrysol.2009.08.027

Google Scholar

[3] H. Ryu and K. Bartwal: Physica B Vol. 404 (2009), pp.1714-1718.

Google Scholar

[4] M. AyvacIklI, A. Ege, S. Yerci and N. Can: J Lumin Vol. 131 (2011), pp.2432-2439.

Google Scholar

[5] S.D. Han, K.C. Singh, T.Y. Cho, H.S. Lee, D. Jakhar, J.P. Hulme, C.H. Han, J.D. Kim, I.S. Chun and J. Gwak: Journal of luminescence Vol. 128 (2008), pp.301-305.

DOI: 10.1016/j.jlumin.2007.07.017

Google Scholar

[6] T. Aitasalo, P. Dere, J. Holsa, H. Jungner, J.C. Krupa, M. Lastusaari, J. Legendziewicz, J. Niittykoski and W. Strk: J Solid State Chem Vol. 171 (2003), pp.114-122.

DOI: 10.1016/s0022-4596(02)00194-9

Google Scholar

[7] W. Minquan, D. Wang and L. Guanglie: Materials Science and Engineering: B Vol. 57 (1998), pp.18-23.

Google Scholar

[8] W. Xie, J. Quan, H. Wu, L. Shao, C. Zou, J. Zhang, X. Shi and Y. Wang: J Alloy Compd Vol. 514 (2012), pp.97-102.

Google Scholar

[9] S.J. Kim, H.I. Won, N. Hayk, C.W. Won, D.Y. Jeon and A.G. Kirakosyan: Mat Sci Eng B-Solid Vol. 176 (2011), pp.1521-1525.

Google Scholar

[10] X. Li, Y. Qu, X. Xie, Z. Wang and R. Li: Mater Lett Vol. 60 (2006), pp.3673-3677.

Google Scholar

[11] B. Mothudi, O. Ntwaeaborwa, J. Botha and H. Swart: Physica B Vol. 404 (2009), pp.4440-4444.

Google Scholar

[12] S. Nagamani and B.S. Panigrahi: J Am Ceram Soc Vol. 93 (2010), pp.3832-3836.

Google Scholar

[13] A. Lakshmanan: Vol. p.

Google Scholar

[14] C.R. Ronda, T. Justel and H. Nikol: Journal of Alloys and Compounds Vol. 275 (1998), pp.669-676.

Google Scholar

[15] R. Melendrez, O. Arellano-Tánori, M. Pedroza-Montero, W. Yen and M. Barboza-Flores: J Lumin Vol. 129 (2009), pp.679-685.

DOI: 10.1016/j.jlumin.2009.01.013

Google Scholar

[16] T. Aitasalo, J. Holsa, H. Jungner, J.C. Krupa, M. Lastusaari, J. Legendziewicz and J. Niittykoski: Radiat Meas Vol. 38 (2004), pp.727-730.

DOI: 10.1016/j.radmeas.2004.01.031

Google Scholar

[17] T. Peters and J. Baglio: J. Inorg. and Nuc. Chem. Vol. 32 (1970), pp.1089-1095.

Google Scholar

[18] D.A. Keszler and A. Diaz, Eu^ 2^+ Luminescence Color: A Structure-Property Relationship, Materials Research Society, 1997, pp.247-252.

Google Scholar