In Vitro Compatibility of Hydroxyapatite Nanoparticles (HAp-NPs) for Restoration Purposes of Archaeological Lime-Based Plasters

Article Preview

Abstract:

For a number of years, nanomaterials have been considered as a perfect solution to maintain the stability of different cultural heritage materials. In the present trial, hydroxyapatite nanoparticles (HAp-NPs) have been synthesized via the wet chemical reaction of calcium nitrate and ammonium hydroxide. Then, the possible efficiency of HAp-nanoparticles was evaluated to improve restoration formulas for some archaeological lime-based plasters. A broad series of analytical methods, namely OM, FE-SEM, TEM, AFM, XRD and BET surface area-pore size analysis, was selected for characterizing the archaeological samples and to rate the experimental tests. Further, the physical-mechanical behavior of samples was measured. The emulated modifications induced by the HAp-NPs treatment have been evaluated and discussed.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

162-173

Citation:

Online since:

November 2019

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2019 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] K.R. Dotter, B. Smith, J. McAlister, J. Curran, Sacrifice and rebirth: the history of lime mortar in the north of Ireland, Proceedings of the 3rd International Congress on Construction History (eds. Kurrer, K.E., W. Lorenz, W., Wetzk, V), Brandenburg University of Technology of Cottbus, Germany, (2009), pp.499-506.

Google Scholar

[2] Ö. A. Özkaya, H. Böke, Properties of Roman bricks and mortars used in Serapis temple in the city of Pergamon, Mater. Charact. 60 (2009) 995-1000.

DOI: 10.1016/j.matchar.2009.04.003

Google Scholar

[3] S. Sánchez-Moral, L. Luque, J.-C. Cañaveras, V. Soler, J. Garcia-Guinea, A. Aparicio, Lime pozzolana mortars in Roman catacombs: composition, structures and restoration, Cem. Concr. Res. 35 (2005) 1555-65.

DOI: 10.1016/j.cemconres.2004.08.009

Google Scholar

[4] M.L. Franquelo, M. D. Robador, V. Ramírez-Valle, A. Durán, M.C. Jiménez de Haro, J.L. Pérez-Rodríguez, Roman ceramics of hydraulic mortars used to build the Mithraeum house of Mérida (Spain), J. Thermal Anal. Calorim. 92 (1) (2008) 331-335.

DOI: 10.1007/s10973-007-8810-4

Google Scholar

[5] M. Stefanidou, E. Pavlidou, Scanning Mortars to Understand the Past and Plan the Future for the Maintenance of Monuments, Scanning 1 (18) (2018).  https://doi.org/10.1155/2018/7838502.

DOI: 10.1155/2018/7838502

Google Scholar

[6] C. Nunes, Z. Slížková, D. Krivánková, Lime-based mortars with linseed oil: Sodium chloride resistance assessment and characterization of the degraded material, Period. Mineral. 82 (3) (2013) 411-427.

Google Scholar

[7] R.J. Turner, J.C. Renshaw, A. Hamilton, Biogenic Hydroxyapatite: A New Material for the Preservation and Restoration of the Built Environment, ACS Appl. Mater. Interfaces 9 (37) (2017) 31401-31410.

DOI: 10.1021/acsami.7b07927

Google Scholar

[8] E. Sassoni, Phosphate-based treatments for conservation of stone, RILEM Technical Letters 2 (2017) 14-19.

DOI: 10.21809/rilemtechlett.2017.34

Google Scholar

[9] P. Baglioni, R. Giorgi, Soft and hard nanomaterials for restoration and conservation of cultural heritage, J. Soft Matter. 4 (2006) 293-303.

DOI: 10.1039/b516442g

Google Scholar

[10] J. Otero, V. Starinieri, A. E. Charola, Nanolime for the consolidation of lime mortars: A comparison of three available products, Const. Build. Mater. 181 (2018) 394-407.

DOI: 10.1016/j.conbuildmat.2018.06.055

Google Scholar

[11] A. M. Barberena-Fernández, M. T. Blanco-Varela, P. M. Carmona-Quiroga, Use of nanosilica-or nanolime-additioned TEOS to consolidate cementitious materials in heritage structures: Physical and mechanical properties of mortars, Cem. Concr. Comp. 95 (2019) 271-276.

DOI: 10.1016/j.cemconcomp.2018.09.011

Google Scholar

[12] G. Taglieri, V. Daniele, L. Macera, A. Mignemi, Innovative and green nanolime treatment tailored to consolidate the original mortar of the façade of a medieval building in L'aquila (Italy), Const. Build. Mater. 221 (2019) 643-650.

DOI: 10.1016/j.conbuildmat.2019.06.110

Google Scholar

[13] M.F. La Russa, S. A. Ruffolo, N. Rovella, C. M. Belfiore, A. M. Palermo, M.T. Guzzi, G. M.Crisci, Multifunctional TiO2 coatings for Cultural Heritage, Prog. Org. Coat. 74 (1) (2012) 186-191.

DOI: 10.1016/j.porgcoat.2011.12.008

Google Scholar

[14] L. D'Orazio, A. Grippo, A water dispersed Titanium dioxide/poly(carbonate urethane) nanocomposite for protecting cultural heritage: Preparation and properties, Prog. Org. Coat. 74 (2015) 1-7.

DOI: 10.1016/j.porgcoat.2014.09.017

Google Scholar

[15] V. Crupi, B. Fazio, A. Gessini, Z. Kis, M. F. La Russa, D. Majolino, C. Masciovecchio, M. Ricca, B. Rossi, S. A. Ruffolo, V. Venuti, TiO2–SiO2–PDMS nanocomposite coating with self-cleaning effect for stone material: Finding the optimal amount of TiO2, Const. Build. Mater. 166 (2018) 464-471.

DOI: 10.1016/j.conbuildmat.2018.01.172

Google Scholar

[16] R-M. Ion, D. Turcanu-Carutiu, R-C. Fierascu, I. Fietascu, Chalk stone restoration with Hydroxyapatite-based nanoparticles, The Scientific Bulletin of Valahia University -Materials and Mechanics 9 (12) (2014) 1-5.

Google Scholar

[17] E. Sassoni, Hydroxyapatite and other calcium phosphates for the conservation of cultural heritage: A review, Materials 11 (4) (2018) 557.

DOI: 10.3390/ma11040557

Google Scholar

[18] E. Sassoni, E.  D'Amen, N.  Roveri, G.W.  Scherer, E. Franzoni, Durable Self-Cleaning Coatings for Architectural Surfaces by Incorporation of TiO2 Nano-Particles into Hydroxyapatite Films, Materials 11 (177) (2018),.

DOI: 10.3390/ma11020177

Google Scholar

[19] A. Górniak, J.W. Łukaszewicz, B. Wiśniewska, The use of Hydroxyapatite for consolidation of calcareous stones: light limestone Pińczów and Gotland sandstone (Part I), The 13th International Congress on the Deterioration and Conservation of Stone, University of West Scotland, (2016).

Google Scholar

[20] L. Yubao, K. de Groot, J. de Wijn, K. Cpat, S.V.D. Meer, Morphology and composition of nanograde calcium phosphate needle-like crystals formed by simple hydrothermal treatment, J. Mater. Sci.: Mater. Med. 5 (326) (1994) 331-337.

DOI: 10.1007/bf00058956

Google Scholar

[21] A. Paz, D.  Guadarrama, M.  López, J.E. González, N. Brizuela, A.  Aragón, A comparative study ofb hydroxyapatite nanoparticles synthesized by different routes, Química Nova 35 (9) (2012) 1724-1727.

DOI: 10.1590/s0100-40422012000900004

Google Scholar

[22] Sh.V.Ganachari, A.A. Bevinakatti, J.S.  Yaradoddi, N.R. Banapurmath, A.M. Hunashyal, A.S. Shettar, Rapid synthesis, characterization, and studies of hydroxyapatite nanoparticles, Adv Mater. Sci Res. 1 (1) (2016) 9-13.

Google Scholar

[23] M. Manoj, R. Subbiah, D. Mangalaraj, N. Ponpandian, Ch.  Viswanathan, K. Park, Influence of Growth Parameters on the Formation of Hydroxyapatite (HAp) Nanostructures and Their Cell Viability Studies, Nanobiomedicine 2 (2) (2015) 1-11.

DOI: 10.5772/60116

Google Scholar

[24] RILEM., Tests Defining the Structure, Materials and Construction, 13, (1980).

Google Scholar

[25] S. Pavía, S. Caro, An Investigation of Roman mortar technology through the petrographic analysis of archaeological material, Constr. Build. Mater. 22 (2008) 1807-1811.

DOI: 10.1016/j.conbuildmat.2007.05.003

Google Scholar

[26] P. D'Armada, E. Hirst, Nano-Lime for Consolidation of Plaster and Stone, J. Arch. Cons. 18 (1) (2012) 63-80.

Google Scholar

[27] D. Chelazzi, R. Camerini, R. Giorgi, Nanomaterials for the Consolidation of Stone Artifacts, Advanced Materials for the Conservation of Stone (eds. Hosseini, M, Karapanagiotis, I) Springer, Cham (2018), pp.151-173.

DOI: 10.1007/978-3-319-72260-3_7

Google Scholar

[28] E. Sassoni, S. Naidu, G.W. Scherer, The use of hydroxyapatite as a new inorganic consolidant for damaged carbonate stones, J. Cult. Herit. 12 (2011) 346-355.

DOI: 10.1016/j.culher.2011.02.005

Google Scholar

[29] P.N. Manoudis, A. Tsakalof, I. Karapanagiotis, I. Zuburtikudis, C. Panayiotou, Fabrication of super-hydrophobic surfaces for enhanced stone protection, Surf. Coat. Technol. 203 (2009) 1322-1328.

DOI: 10.1016/j.surfcoat.2008.10.041

Google Scholar

[30] M. L. Weththimuni, M. Licchellia, M. Malagodi, N. Rovella, M. La Russa, Consolidation of bio-calcarenite stone by treatment based on diammonium hydrogenphosphate and calcium hydroxide nanoparticles, Measurement 127 (2018) 396-405.

DOI: 10.1016/j.measurement.2018.06.007

Google Scholar

[31] J. Tokarskýa, P. Martinec, K.M. Kutláková, H. Ovčačíková, S. Študentová, J. Ščučka, Photoactive and hydrophobic nano-ZnO/poly(alkyl siloxane) coating for the protection of sandstone, Const. Build. Mater. 199 (2019) 549-559.

DOI: 10.1016/j.conbuildmat.2018.12.045

Google Scholar

[32] R-M. Ion, R-C. Fierascu, M. Leahu, M. L. Ion, D. Turcanu-Carutiu, Nanomaterials for conservation and preservation of historical monuments, Proceedings of the 3rd European Workshop on Cultural Heritage Preservation- EWCHP, Bozen/Bolzano, Italy, (2013), pp.97-103.

DOI: 10.1007/978-3-319-09408-3_97

Google Scholar