Degradation of Metal-Supported SOFC and One Powerful Investigation Method: Multi-Scale Modeling and Simulation

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Metal-supported solid oxide fuel cell (SOFC) has a varieties of potential advantages compared to the traditional ceramic supported SOFC. However, degradation issue of metal-supported SOFC is seriously impeding its further development, in particular, the inter-diffusion and interaction of iron, chromium and nickel at substrate/anode interface is known to be a key issue responsible for cell rapid degradation. With respect to the complexity and nonlinearity of degradation mechanism, multi-scale modeling and simulation is regarded as one powerful method to gain a deep insight on degradation mechanism. In present work, multi-scale models were presented to investigate multi-scale physicochemical phenomena happening at interface of anode/substrate, with the attempt to reveal degradation mechanism. The research procedure for the above goal was addressed in detail as well.

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3376-3381

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October 2011

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] B. Borglum, Cell and Stack Development at Versa Power Systems, 10th Annual SECA Workshop, Pittsburgh, PA, July 15, (2009).

Google Scholar

[2] M.C. Tucker, Progress in metal-supported solid oxide fuel cells: A review, J. Power Sources, Vol. 195, pp.4570-4582, (2010).

DOI: 10.1016/j.jpowsour.2010.02.035

Google Scholar

[3] M.C. Tucker, T.Z. Sholklapper, and G.Y. Lau, Progress of metal-supported SOFCs, 216th ECS meeting, Australia, Vol. 25, pp.673-680, (2009).

DOI: 10.1149/1.3205581

Google Scholar

[4] C. Lee, and J. Bae, Fabrication and characterization of metal-supported solid oxide fuel cells, J. Power Sources, Vol. 176, pp.62-69, (2008).

DOI: 10.1016/j.jpowsour.2007.10.067

Google Scholar

[5] J. Joo, and G. Choi, Simple fabrication of micro-solid oxide fuel cell supported on metal substrate, J. Power Sources, Vol. 2, pp.589-593, (2008).

DOI: 10.1016/j.jpowsour.2008.03.089

Google Scholar

[6] Q.A. Huang, J. Oberste-Berghaus, and R. Hui et al., Polarization analysis for metal-supported SOFCs from different fabrication processes, J. Power Sources, Vol. 177, pp.339-347, (2008).

DOI: 10.1016/j.jpowsour.2007.11.092

Google Scholar

[7] R. Hui, J. Berghaus, C. Decès-Petit, W. Qu, S. Yicka, J. Legoux, and C. Moreau, High performance metal-supported solid oxide fuel cells fabricated by thermal spray, J. Power Sources, Vol. 191, pp.371-376, (2009).

DOI: 10.1016/j.jpowsour.2009.02.067

Google Scholar

[8] N.P. Brandon, D. Corcoran, and D. Cummins et al., Development of metal supported solid oxide fuel cells for operation at 500-600℃, Journal of Materials Engineering and Performance, Vol. 13, pp.253-256, (2004).

DOI: 10.1361/10599490419135

Google Scholar

[9] P. Huczkowski, N. Christiansen, and V. Shemet et al., Oxidation limited life times of chromia forming ferritic steels, Materials and Corrosion, Vol. 55, pp.825-830, (2004).

DOI: 10.1002/maco.200303798

Google Scholar

[10] M. Brandner, M. Bram, J. Froitzheim, H. P. Buchkremer, and D. Stover, Electrically Conductive Diffusion barrier layers for Metal-Supported SOFC, Solid State Ionics, Vol. 27-32, pp.1501-1504, (2008).

DOI: 10.1016/j.ssi.2008.03.002

Google Scholar

[11] D.M. England, and AV Virkar, Oxidation kinetics of some nickel-based superalloy foils in humidified hydrogen and electronic resistance of the oxide scale formed: part II, J. Electrochem. Soc. , Vol. 148, pp. A330-A338, (2001).

DOI: 10.1149/1.1354611

Google Scholar

[12] Z.G. Yang, G.G. Xia, and M.S. Walker et al., High temperature oxidation/corrosion behavior of metals and alloys under a hydrogen gradient, International Journal of Hydrogen Energy, Vol. 32, pp.3770-3777, (2007).

DOI: 10.1016/j.ijhydene.2006.08.056

Google Scholar

[13] Y.B. Matusa, L.C. Jonghe De, and C.P. Jacobsonb et al., Metal-supported solid oxide fuel cell membranes for rapid thermal cycling, Solid State Ionics, Vol. 176, pp.443-449, (2005).

DOI: 10.1016/j.ssi.2004.09.056

Google Scholar

[14] I. Antepara, I Villarreal, and LM Rodríguez-Martínez et al., Evaluation of ferritic steels for use as interconnects and porous metal supports in IT-SOFCs, J. Power Sources, Vol. 151, pp.103-107, (2005).

DOI: 10.1016/j.jpowsour.2005.02.084

Google Scholar

[15] M.C. Tucker, G. Lau, C. Jacobson, L. DeJonghe, and S. Visco, Performance of metal-supported SOFCs with infiltrated electrodes, J. Power Sources, Vol. 171, pp.477-482, (2007).

DOI: 10.1016/j.jpowsour.2007.06.076

Google Scholar

[16] Y.H. Kong, B. Hua, J. Pu, B. Chi, and J. Li, A cost-effective process for fabrication of metal-supported solid oxide fuel cells, International Journal of Hydrogen Energy, Vol. 35, pp.4592-4596, (2010).

DOI: 10.1016/j.ijhydene.2010.02.106

Google Scholar

[17] M. Mantina, Y. Wang, R. Arroyave, L. Q. Chen, and Z. K. Liu, First-Principles Calculation of Self-Diffusion Coefficients, Physical Review Letter, Vol. 100, pp.21590-21593, (2008).

DOI: 10.1103/physrevlett.100.215901

Google Scholar