Synthesis of Polymers Containing C-N Bond Using Pd-Catalyst
Palladium catalysis cross-coupling reaction has been widely used and played an important role in medical, new material and other fields. In this paper, we take Pd2(dba)3 as catalyst and BINAP as ligand, formulate two poly(imino ketone)s (PIKs) by C-N Cross-coupling Polycondensation. The thermal property of PIKs were tested via thermogravimetric analysis (TGA), and the result showed that PIKs possessed high thermal decomposition temperature.
Huixuan Zhang, Ye Han, Fuxiao Chen and Jiuba Wen
W. W. Shan et al., "Synthesis of Polymers Containing C-N Bond Using Pd-Catalyst", Applied Mechanics and Materials, Vols. 117-119, pp. 1207-1210, 2012