Preparation, Characterization and Thermal Behavior of Copper(II) Complex with 1-(6-Hydroxynaphthalen-2-Yl)butane-1,3-Dione

Dun Jia Wang; Ben Po Xu; Yan Fang Kang

doi:10.4028/www.scientific.net/AMM.117-119.1370

Paper Titles

Strength Properties of Low Thermal Conductivity Fly Ash Bricks: Compressive and Flexural Strength Aspects
p.1352

Fair-Faced Light Weight Aggregate Concrete Preparation and Durability Research
p.1358

Cellulose Tris(3,5-Dimethylphenylcarbamate) Regioselectively Bonded to Small Pore Silica Gel as Chiral Stationary Phase for HPLC
p.1361

Evaluation on the Corrosion Resistance Improvement by Dipping to Inhibitor Solution of Galvanizing Steel
p.1365

Preparation, Characterization and Thermal Behavior of Copper(II) Complex with 1-(6-Hydroxynaphthalen-2-Yl)butane-1,3-Dione
p.1370

Preparation and Characterization of Konjac Glucomannan Gel
p.1374

Oxidation Behavior in Super-Plastic Microforming of Zr₆₅Cu_17.5Ni₁₀Al_7.5 Bulk Metallic Glass
p.1377

The Thickness Testing Technology of the Metal Base and Anticorrosion for Double Coating Corrugated Sheet Steel Beams for Guardrail
p.1383

The Relationship between the Free and the Bound Chloride in High Performance Concrete
p.1387

HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vols. 117-119Preparation, Characterization and Thermal Behavior...

Preparation, Characterization and Thermal Behavior of Copper(II) Complex with 1-(6-Hydroxynaphthalen-2-Yl)butane-1,3-Dione

Abstract:

A complex of Cu(II) with 1-(6-hydroxynaphthalen-2-yl) butane-1,3-dione (HNBD) was synthesized and characterized by elemental analysis, IR, UV and TG-DTA techniques. IR spectra as well as UV-visible absorption measurements indicated that Cu(II) ion was coordinated to the HNBD ligand. The TG-DTA curves showed that the thermal decomposition for Cu(II) complex was a three-steps process. At first, the complex had a mass loss of water molecules at temperature below 134°C, then the thermal decomposition of the anhydrous complex was a two-stage process, which corresponded to the loss of two naphthol molecules and the oxidative decomposition of other organic fragments of ligand. The final decomposition product of the complex was CuO.

You might also be interested in these eBooks

View Preview

Info:

Periodical:

Applied Mechanics and Materials (Volumes 117-119)

Pages:

1370-1373

DOI:

https://doi.org/10.4028/www.scientific.net/AMM.117-119.1370

Citation:

Cite this paper

Online since:

October 2011

Authors:

Dun Jia Wang, Ben Po Xu, Yan Fang Kang

Keywords:

1-(6-Hydroxynaphthalen-2-Yl)Butane-1, 3-Dione, Cu(II) Complex, Thermal Behavior

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

References

[1] H.Z. Song, Y.Z. Jiang, C.R. Xia and G.Y. Meng: J. Crystal Growth Vol. 250 (2003), p.423

Google Scholar

[2] D.J. Zhou, C.H. Huang, G.Q. Yao, J. Bai and T.K. Li: J. Alloys Comp. Vol. 235 (1996), p.156

Google Scholar

[3] J. D. Mark, K. B. Kulbinder, H. Seiichiro: J. Fluorine Chem. Vol.123 (2003), p.109

Google Scholar

[4] P. Sergej, G. H. Liliane and A. Adulfas: Polyhedron Vol.23 (2004), p.735

Google Scholar

[5] M. Kazuko, T. Yoshie and U. Tomonari: J. Chromatog. B Vol.773 (2002), p.135

Google Scholar

[6] G. Piao, K. Akagi and H. Shirakawa: Synth. Met. Vol.85 (1997), p.1669

Google Scholar

[7] S.T. Frey, M.L. Gong and W.D.W. Horrocks: Inorg. Chem. Vol.33 (1994), p.3229

Google Scholar

[8] Z.M. Chen, Y.Q. Wu, F.X. Huang, D.H. Gu and F.X. Gan: Spectrochim. Acta Part A Vol.66 (2007), p.1024

Google Scholar

[9] H.F. Brito, C.A.A. Carvalho and O.L. Malta: Spectrochim. Acta Part A Vol.55 (1999), p.2403

Google Scholar

[10] Y.Z. Jiang, H.Z. Song and L. J. Li: Crystal Growth Vol.267 (2004), p.256

Google Scholar

[11] C.R.S. Morais, A.G. Souza and P.A. Santa-Cruz: J. Alloys Comp. Vol.344 (2002), p.101

Google Scholar

[12] J.P. Li, B.Y. Tian and J. Ye: J. Hubei Univ. (Nat. Sci. Ed.) Vol.20 (1998), p.59

Google Scholar

[13] N. Kazuo, Translated by D.R. Huang and R.Q. Wang, Infrared and Raman Spectra of Inorganic and Coordination Compounds (in Chinese), Chemical Industry Press (1986), p.205

Google Scholar

[14] B.S. Garg and D.N. Kumar: Spectrochim. Acta Part A Vol.59 (2003), p.229

Google Scholar