Preparation and Performance of Bio-Adhesive Based on Acorn Starch Graft Glycidyl Methacrylate

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For improving the performance of acorn starch (AS) based bio-adhesive, AS graft glycidyl methacrylate (AS-g-GMA) adhesive was prepared in this paper. The properties of the AS-g-GMA adhesive were studied by Fourier transform infrared spectroscopy (FTIR) and differential scanning calorimetry (DSC) measurement. The bonding strength of the plywood bonded by AS-g-GMA adhesive was measured according to Chinese National Standards methods to evaluate its water resistant. FTIR results indicated that GMA was grafted on the AS successfully. The bonding strength of the plywood bonded by AS-g-GMA adhesive showed lower curing temperature, better bonding strength, and water resistance comparing with that of control. The water resistant could reach type II grade (63°C water bath 3h) plywood requirement when the glycidyl methacrylate adding amount was 6% based on AS.

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293-296

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October 2011

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] China State Bureau of Technical Supervision. GB 18580-2001 (Indoor decorating and refurbishing materials-Limit of formaldehyde emission of wood based panels and finishing products. Beijing: Standards Press of China, (1999).

Google Scholar

[2] Huang J, Li K C, in: A new soy flour-based adhesive for making interior type II plywood. Journal of the American Oil Chemists Society. Vol. 85(2008), pp.63-70.

DOI: 10.1007/s11746-007-1162-1

Google Scholar

[3] Khosravi S, Khabbaz F, Nordqvist P, Johansson M, in: Protein-based adhesives for particleboards. Industrial Crops and Products. Vol. 32(2010), pp.275-283.

DOI: 10.1016/j.indcrop.2010.05.001

Google Scholar

[4] Amaral-Labat G A, Pizzi A, Goncalves A R, Celzard A, Rigolet S, Rocha G J M, in: Environment-friendly soy flour-based resins without formaldehyde. Journal of Applied Polymer Science. Vol. 108(2008), pp.624-632.

DOI: 10.1002/app.27692

Google Scholar

[5] Li F, Li X P, Wang W H, in: Soy flour adhesive modified with urea, citric acid and boric acid. Pigment & Resin Technology. Vol. 39(2010), pp.223-227.

DOI: 10.1108/03699421011055536

Google Scholar

[6] Moubarik A, Allal A, Pizzi A, Charrier F, Charrier B, in: Characterization of a formaldehyde-free cornstarch-tannin wood adhesive for interior plywood. European Journal of Wood and Wood Products. 68(2010), pp.427-433.

DOI: 10.1007/s00107-009-0379-0

Google Scholar

[7] Moubarik A, Charrier B, Allal A, Charrier F, Pizzi A, in: Development and optimization of a new formaldehyde-free cornstarch and tannin wood adhesive. European Journal of Wood and Wood Products. Vol. 68(2010), pp.167-177.

DOI: 10.1007/s00107-009-0357-6

Google Scholar

[8] Pan Z L, Cathcart A, Wang D H, in: Thermal and chemical treatments to improve adhesive property of rice bran. Industrial Crops and Products. Vol. 22(2005), pp.233-240.

DOI: 10.1016/j.indcrop.2005.01.003

Google Scholar

[9] Xiao H W, Yu F Y, Yu Y, Huang S Q, in: Grafting of glycidyl methylacrylate onto chlorinated polypropylene and its bonding to aluminum flake. Journal of Applied Polymer Science. Vol. 104(2007), pp.2515-2521.

DOI: 10.1002/app.25819

Google Scholar