Synthesis and Characterization of Polyacrylate Latex Containing Fluorine and Silicon

Xiao Hui Gao; Yu Feng Li; Hong Chao Wang

doi:10.4028/www.scientific.net/AMM.151.392

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HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vol. 151Synthesis and Characterization of Polyacrylate...

Synthesis and Characterization of Polyacrylate Latex Containing Fluorine and Silicon

Abstract:

Polyacrylate latex containing fluorine and silicon was successfully synthesized by semi-continuous seed emulsion polymerization, using organic silicon(OSi) monomer, fluorocarbon(FC), methacrylic acid(MAA), and butyl acrylate(BA) as raw materials. Transmission electron microscope(TEM) characterization indicated that the latex particles were form uniform analogous core-shell structure. Dynamic light scattering(DLS) show a narrow size distribution. The results of X-ray photoelectron spectroscopy(XPS) revealed the fluorine and silicon transfer to the film-air interface. The reaction was evaluated using fourier transform infrared(FT-IR) spectrum. The thermal stability of the latex films which analysed by thermogravimetric(TG) was improved due to the join of OSi and FC.

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Periodical:

Applied Mechanics and Materials (Volume 151)

Pages:

392-395

DOI:

https://doi.org/10.4028/www.scientific.net/AMM.151.392

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Online since:

January 2012

Authors:

Xiao Hui Gao, Yu Feng Li, Hong Chao Wang

Keywords:

Emulsion Polymerization, Fluorine, Polyacrylate Latex, Silicon

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References

[1] A. L. Qu, X. F. Wen, P. H. Pi, et al. Synthesis of composite particles through emulsion polymerization based on silica/fluoroacrylate-siloxane using anionic reactive and nonionic surfactants, Journal of Colloid and Interface Science. 317 (2008).

DOI: 10.1016/j.jcis.2007.09.038

Google Scholar

[2] A. Q. Hou, J. B. Yu, Y. Q. Shi, Preparation and surface properties of the polysiloxane material modified with fluorocarbon side chains, European Polymer Journal. 44 (2008) 1696-1700.

DOI: 10.1016/j.eurpolymj.2008.03.026

Google Scholar

[3] R. G. A. Carlos, M. B. Pablo, R. Jose, et al. Structure and properties of self-assembled fluorocarbon-silica nanocomposites, Journal of Non-Crystalline Solids. 354 (2008) 1074-1079.

DOI: 10.1016/j.jnoncrysol.2007.08.003

Google Scholar

[4] K. G. Arun, S. Orla, P. Frank, et al. Factors influencing adhesion of fluorocarbon thin film on silicon substrate, Thin Solid Films. 516 (2008) 5673-5680.

DOI: 10.1016/j.tsf.2007.07.124

Google Scholar

[5] P. T. Xiong, D. P. Lu, P. Z. Chen, et al. Preparation and surface properties of latexes with fluorine enriched in the shell by silicon monomer crosslinking, European Polymer Journal. 43 (2007) 2117-2126.

DOI: 10.1016/j.eurpolymj.2006.12.040

Google Scholar

[6] X. J. Cui, S. L. Zhong, H. Y. Wang, Emulsifier-free core-shell polyacrylate latex nan-oparticles containing fluorine and silicon in shell, Polymer. 48 (2007) 7241-7248.

DOI: 10.1016/j.polymer.2007.10.019

Google Scholar

[7] J. Y. Liang, L. He, and W. D. Li, Synthesis and analysis of properties of a new core-shell silicon-containing fluoroacrylate latex, Polym Int. 58 (2009) 1283-1290.

DOI: 10.1002/pi.2660

Google Scholar

[8] A. L. Qu, X. F. Wen, P. H. Pi, et al. Synthesis and characterization of hybrid fluoro-emulsion based on silica/copolymer composite particles, Polym Int. 57 (2008) 1287-1294.

DOI: 10.1002/pi.2477

Google Scholar