Synthesis, Crystal Structure and NLO of a Pb(II) Coordination Compound Based on HO-H₂BDC

Abstract:

A new three-dimensional Pb(II) coordination polymer, [Pb₃(O-BDC)₂]_n (1) (HO-H₂BDC = 5-Hydroxy-1,3-benzenedicarboxylate), has been solvothermally synthesized from the reaction of HO-H₂BDC, Pb(NO₃)₂•6H₂O and NaAc. Single-crystal X-ray diffraction analysis reveal that polymer 1 exhibit a unprecedented 3D structure and ligand HO-H2BDC has been observed to exhibit a new coordination mode. The third-order nonlinear optical (NLO) properties in DMF solution have been studied by Z-scan technique using 8 ns laser at 532 nm. The results reveal that the new compound exhibits strong NLO absorption effect and self-focusing refractive performance (α₂ = 1.2 × 10^-10 mW^-1; n₂ = -2.4×10^-17 m²•W^-1).

• Periodical: Applied Mechanics and Materials (Volumes 184-185)
• Pages: 1311-1316
• DOI: https://doi.org/10.4028/www.scientific.net/AMM.184-185.1311
• Online since: June 2012
• Authors: Xi Hui Liu, Xin Zhuo, Li Zhang
• Keywords: 5-Hydroxyisophthalic Acid, Crystal Structure, Hydrothermal Synthesis, Lead Complex

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