Humidity Sensing Property of Al-Doped Mesoporous Silica

Article Preview

Abstract:

In order to study the humidity sensing property and sensing mechanism of Al-doped mesoporous silica SBA-15 (Al-SBA-15), Al-SBA-15 was prepared by a simple grind method following a heat-treatment process. Its structure and morphology was characterized by X-ray diffraction (XRD), Infrared (IR), scanning electron microscope (SEM). Humidity sensing response was studied and the results indicated that Al-SBA-15 displayed better sensing property when the frequency was 100 Hz. The impedance of Al-SBA-15 changes three orders of magnitude when relative humidity changes from 11% to 95%. Complex impedance spectra, the corresponding equivalent circuit under different relative humidity are carefully analyzed to explore the humidity sensing mechanism of this material. This material can be used as a promising humidity sensing material.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

992-997

Citation:

Online since:

December 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] P.G. Su, Y.L. Sun, C.C. Lin, Humidity sensor based on PMMA simultaneously doped with two different salts, Sens. Actuators B 113(2006)883–886.

DOI: 10.1016/j.snb.2005.03.052

Google Scholar

[2] Y. Li, B.Y. Ying, L.J. Hong, M.J. Yang, Water-soluble polyaniline and its composite with poly(vinyl alcohol) for humidity sensing, Synthetic Metals 160 (2010) 455–461.

DOI: 10.1016/j.synthmet.2009.11.031

Google Scholar

[3] M. S Gong, J.U. Kim, J.G. Kim, Preparation of water-durable humidity sensor by attachment of polyelectrolyte membrane to electrode substrate by photochemical crosslinking reaction, Sens. Actuators B 147 (2010)539-547.

DOI: 10.1016/j.snb.2010.04.017

Google Scholar

[4] K.P. Yoo, L.T. Lim, N.K. Min, M.J. Lee, C.J. Lee, C.W. Park,  Novel resistive-type humidity sensor based on multiwall carbon nanotube/polyimide composite films, Sens. Actuators B 145(2010) 120-125.

DOI: 10.1016/j.snb.2009.11.041

Google Scholar

[5] J. H. Kim, J. H. Moon, S.Y. Lee, J. Park, Biologically inspired humidity sensor based on three-dimensional photonic crystals, Appl. Phys. Lett. 97(2010) 103701.

DOI: 10.1063/1.3486115

Google Scholar

[6] M. M. Hawkeye, M. J. Brett, Optimized Colorimetric Photonic-Crystal Humidity Sensor Fabricated Using Glancing Angle Deposition, Adv. Funct. Mater. 21(2011) 3652-3658.

DOI: 10.1002/adfm.201100893

Google Scholar

[7] X. L Hu, J.M. Gong, L.Z. Zhang, J.C. Yu, Continuous Size Tuning of Monodisperse ZnO Colloidal Nanocrystal Clusters by a Microwave-Polyol Process and Their Application for Humidity Sensing, Adv. Mater. 20(2008) 4845–4850.

DOI: 10.1002/adma.200801433

Google Scholar

[8] Z.Y. Li, H.N. Zhang, W. Zheng, W. Wang, H.M. Huang, C. Wang, A.G. MacDiarmid, Y. Wei, Highly sensitive and stable humidity nanosensors based on LiCl doped TiO2 electrospun nanofibers, J. Am. Chem. Soc. 130(2008)5036-5037.

DOI: 10.1021/ja800176s

Google Scholar

[9] S.M. Hu, G. Fu, Humidity-sensitive properties based on liquid state LiZnVO4-doped SnO2, Sensors and Actuators A 163(2010) 481–485.

DOI: 10.1016/j.sna.2010.08.030

Google Scholar

[10] S.H. Feng, M. Greenblatt, Proton Conductivity and Humidity-Sensing Properties at High Temperature of the NASICON-Based Composite Material HZr2P3O12·ZrP2O7, . Chem. Mater. 5 (1993) 1277-1282.

DOI: 10.1021/cm00033a016

Google Scholar

[11] S.H. Feng, M.T. Tsai, M. Greenblatt, Preparation, Ionic Conductivity, and Humidity-Sensing Property of Novel, Crystalline Microporous Germanates, Na3HGe, 016*xH20 x, = 0. 6-1., Chem. Mater. 4(1992) 388-393.

DOI: 10.1021/cm00020a029

Google Scholar

[12] Q. Yuan, N. Li, J.C. Tu, X.T. Li, R. Wang, T. Zhang, C.L. Shao, Preparation and humidity sensitive property of mesoporous ZnO–SiO2 composite, Sens. Actuators B 149(2010) 413-419.

DOI: 10.1016/j.snb.2010.06.036

Google Scholar

[13] J. Liu, F.X. Sun, F. Zhang, Z. Wang, R. Zhang, C. Wang, S.L. Qiu, In situ growth of continuous thin metal–organic framework film for capacitive humidity sensing, J. Mater. Chem. 21 (2011) 3672-3676.

DOI: 10.1039/c0jm03123b

Google Scholar

[14] C.T. Kresge, M.E. Leonowicz, W.J. Roth, Ordered Mesoporous Molecular Sieves Synthesized by a Liquid-crystal Template Mechanism, Nature 359(1992) 710-712.

DOI: 10.1038/359710a0

Google Scholar

[15] A. Bearzotti, J.M. Bertolo, P. Innocenzi, P. Falcaro, E. Traversa, Relative humidity and alcohol sensors based on mesoporous silica thin films synthesized from block copolymers, Sens. Actuators B 95(2003) 107–110.

DOI: 10.1016/s0925-4005(03)00416-7

Google Scholar

[16] T. Zhang, R. Wang, W.C. Geng, X.T. Li , Q. Qi, Y. He, S.J. Wang, Study on humidity sensing properties based on composite materials of Li-doped mesoporous silica A-SBA-15, Sens. Actuators B 128(2008) 482–487.

DOI: 10.1016/j.snb.2007.07.012

Google Scholar

[17] J.C. Tu, R. Wang, W.C. Geng, X.Y. Lai, T. Zhang, N. Li , N.L. Yue, X.T. Li, Humidity sensitive property of Li-doped 3D periodic mesoporous silica SBA-16, Sens. Actuators B 136(2009) 392–398.

DOI: 10.1016/j.snb.2008.12.006

Google Scholar

[18] Q. Yuan, W.C. Geng, N. Li, J.C. Tu, R. Wang, T. Zhang , X.T. Li, Study on humidity sensitive property of K2CO3-SBA-15 composites, Applied Surface Science 256 (2009) 280-283.

DOI: 10.1016/j.apsusc.2009.08.016

Google Scholar

[19] Y.H. Zhu, H. Li, J.Q. Xu, H. Yuan, J.J. Wang, X.X. Li, Monodispersed mesoporous SBA-15 with novel morphologies: controllable synthesis and morphology dependence of humidity sensing, Cryst. En. g. Comm. 13(2011) 402-405.

DOI: 10.1039/c0ce00570c

Google Scholar

[20] W. C. Geng, R. Wang, X. T. Li, Y. C. Zou, T. Zhang, J. C. Tu , Y. He , N. Li, Humidity sensitive property of Li-doped mesoporous silica SBA-15, Sens. Actuators B 127(2007) 323-329.

DOI: 10.1016/j.snb.2007.04.021

Google Scholar

[21] K. C. Mouli, K. Soni, A. Dalai, J. Adjaye, Effect of pore diameter of Ni–Mo/Al-SBA-15 catalysts on the hydrotreating of heavy gas oil, Applied Catalysis A: General 404 (2011) 21–29.

DOI: 10.1016/j.apcata.2011.07.001

Google Scholar

[22] C.T. Wang, C.L. Wu, Electrical sensing properties of silica aerogel thin films to humidity,. Thin Solid Films 496 (2006) 658 – 664.

DOI: 10.1016/j.tsf.2005.09.001

Google Scholar

[23] P. Bhange , D. S. Bhange, S. Pradhan, V. Ramaswamy. Direct synthesis of well-ordered mesoporous Al-SBA-15 and its correlation with the catalytic activity, Applied Catalysis A: General 400 (2011) 176–184.

DOI: 10.1016/j.apcata.2011.04.031

Google Scholar

[24] J.H. Anderson, G.A. Parks, The electrical conductivity of silica gel in the presence of adsorbed water ,J. Phys. Chem. 72(1968) 3662–3668.

DOI: 10.1021/j100856a051

Google Scholar