Synthesis and Surface Photoelectric Properties of a Trinuclear Chromium(III) Complex

Abstract:

A trinuclear Chromium(III) complex [Cr3(μ3-O)(μ2-PCBA)6(CH3OH)3]NO3∙H2O∙CH3OH (HPCBA = 4-Chlorobenzoic acid) has been synthesized and characterized by single-crystal X-ray diffraction, IR spectra, UV-Vis absorption spectra and elemental analysis, which belongs to monoclinic, space group P21/c with a = 12.443 (3), b = 24.543 (5), c =22.094 (7)Å, α = 90°, β =115.76 (2) °, γ =90°, V = 6077 (3)Å3, Z = 4.The surface electron behavior of the chromium complex has been studied emphatically by surface photovoltage spectroscopy (SPS). Structural analyse indicate that the complex is molecular complex. The result of SPS show that there is positive photovoltage response bands within 300–800 nm, which indicate that it possess obvious photoelectric conversion properties. There was a good correlation between the SPS and UV-Vis absorption spectra.

• Periodical: Applied Mechanics and Materials (Volumes 275-277)
• Pages: 2010-2013
• DOI: https://doi.org/10.4028/www.scientific.net/AMM.275-277.2010
• Online since: January 2013
• Authors: Zhong Feng Shi, Jia Ming Li, Yan Zhen Yin, Li Zhang, Ni Huang, Rui Yun Feng
• Keywords: Structure, Surface Photoelectric Property, Synthesis, Trinuclear Chromium Complex

References

[1] A. Derwahl, F. Wasgestian, D.A. House, W.T. Robinson, Coord. Chem. Rev. Vol. 45 (2001), p.211.

[2] E.M. McGarrigle, D.G. Gilheany, Chem. Rev. Vol. 105 (2005), p.1563.

[3] B. Poljsak, I. Po´csi, P. Raspor, M. Pesti, J. Basic Microbiol., Vol. 50 (2010), p.21.

[4] Y.C. Tsai, P.Y. Wang, S.A. Chen, J.M. Chen, J. Am. Chem. Soc. Vol. 129 (2007), p.8066.

[5] Q. Zhu, A.M. Arif, L. O¨ hrstro¨m, J.S. Miller, J. Mol. Struct. Vol. 890 (2008), p.41.

[6] C. D. Beard, L. Carr, M. F. Davis, J. Evans, W. Levason, L. D. Norman, G. Reid, M. Webster. Eur. J. Inorg. Chem. (2006), p.4399.

[7] K. H. D. Ballem, V. Shetty, N. Etkin, B. O. Patrick, K. M. Smith. Dalton Trans. (2004), p.3431.

[8] M. Daszkiewicz, W. Bronowska, A. Pietraszko, Z. Staszak, M. Cies´lak-Golonka, J. Mol. Struct. Vol. 754 (2005), p.124.

[9] C. Gabriel, C.P. Raptopoulou, C. Drouza, N. Lalioti, A. Salifoglou, Polyhedron. Vol. 28 (2009), p.3209.

DOI: 10.1016/j.poly.2009.05.077

[10] M. Viciano-Chumillas, N. Marino, I. Sorribes, C. Vicent, F. Lloret, M. Julve, CrystEngComm, Vol. 12 (2010), p.122.

[11] L.P. Engelhardt, C.A. Muryn, R.G. Pritchard, G.A. Timco, F. Tuna, R.E.P. Winpenny, Angew. Chem. Int. Ed. Vol. 47 (2008), p.924.

DOI: 10.1002/anie.200704132

[12] J. Zhang, A. Li, T. S. Andy Hor. Dalton Trans. (2009), p.9327.

[13] K.J. Nelson, A.G. DiPasquale, A.L. Rheingold, M.C. Daniels, J.S. Miller, Inorg. Chem. Vol. 47 (2008), p.7768.

[14] D.Y. Rao, B. Li, R. Zhang, H. Wang, X.B. Lu, Inorg. Chem. Vol. 48 (2009), p.2830.

[15] Y. Lin, D. Wang, Q. Zhao, M. Yang, Q. Zhang. J. Phys. Chem. B. Vol. 108 (2004), p.3202.

[16] M. Yu, W. Zhang, Y. Fan, W. Jian, G, Liu. J. Phys. Org. Chem. Vol. 20 (2007), p.229.

[17] Y. Zidon, Y. Shapira, H. Shaim, Th. Dittrich. Appl. Surf. Sci. Vol. 254 (2008), p.3255.

[18] A. Figuerola, V. Tangoulis, J. Ribas, H. Hartl, I. Bru1dgam, M. Maestro, and C. Diaz. Inorganic Chemistry, Vol. 46, (2007), P. 11017.

[19] G.M. Sheldrick, SHELXS-97, Program for Crystal Structure Solution (University of Go¨ttingen, Germany, 1997).

[20] G.M. Sheldrick, SHELXL-97, Program for Structure Refinement (University of Go¨ttingen, Germany, 1997).