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HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vol. 319Microstructure and Oxidation Resistance of...

Microstructure and Oxidation Resistance of Muscovite-Glass Frits Loaded High Silica Cloth/Boron-Containing Phenol-Formaldehyde Resin-Based Ceramifying Composites

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Abstract:

The boron-containing phenol-formaldehyde resin-based ceramifying composites that used muscovite mica and glass frits loaded boron-containing phenol-formaldehyde resin (BPF) as matrix, high silica fiberglass fabric as reinforcements, were pyrolyzed into ceramic gradually in the air. Glass frits were fused into liquid phase and spread to the surface to make muscovite mica form compact mullite ceramic shell. The shell restrained oxygen into the internal effectively in order to reduce the thermo-oxidative degradation of BPF resin. X-ray diffraction analysis (XRD) showed that aluminium borate (Al₈B₄O₃₃) and mullite (Al₆Si₂O₁₃) crystalline phases after pyrolysis. SEM demonstrated the ceramifying progress of the microstructure of the composites, and EDS analyzed the micro-chemical composition.

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Chemical, Mechanical and Materials Engineering II

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Periodical:

Applied Mechanics and Materials (Volume 319)

Pages:

34-38

DOI:

https://doi.org/10.4028/www.scientific.net/AMM.319.34

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Online since:

May 2013

Authors:

Yan Qin, Jie Ding, Zhi Xiong Huang, Qi Lin Mei, Zhi Long Rao

Keywords:

Boron-Containing Phenol-Formaldehyde Resin, Ceramifying Composites, Oxidation Resistance

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] FANZhenxiang.,&CHENGHaifeng.(2005).Development of Thermal Protection Materials. Materials Review, 19,13-16.

[2] T.R. Crompton. (2010).Thermo-oxidative Degradation of Polymers. Lightning Source Inc.

[3] L.G. Hanu.,&G.P. Simon.(2006).Thermal stability and flammability of silicone polymer composites.Polymer Degradation&Stability,91,1373-1379.

DOI: 10.1016/j.polymdegradstab.2005.07.021

[4] L.G. Hanu.,&G.P. Simon.(2005).Preferential orientation of muscovite in ceramifying silicone composites. Materials science&engineering a,398,180-187.

DOI: 10.1016/j.msea.2005.03.022

[5] J.Mansouri.,&R.P. Burford.(2006).Pyrolysis behaviour of silicone-based ceramifying composites. Materials science&engineering a,425,7-14.

DOI: 10.1016/j.msea.2006.03.047

[6] Rimantas LEVINSKAS.,&Romualdas KEZELIS.(2011).High temperature ablation of composite material under plasma jet impact.M aterials science, Vol.17,No.4,ISSN 1392-1320.

DOI: 10.5755/j01.ms.17.4.781

[7] C.M. Bhuvaneswari.,&S.D. Kakade.(2008).Filled ethylene-propylene diene terpolymer elastomer as thermal insulator for case-bonded solid rocker motors.Defence science journal, Vol.58,No.1,94-102.

DOI: 10.14429/dsj.58.1628

[8] Jung-Hye Eom.,&Young-Wook Kim.(2010). Effect of additives on mechanical properties of macroporous silicon carbide ceramics.Met&Mater,Vol.16,No.3,399-405.

DOI: 10.1007/s12540-010-0609-3

[9] Gilberto Petraconi.,&Choyu Otani.(2010).Degradation of carbon-based materials under ablative conditions produced by a high enthalpy plasma jet.Journal of aerospace technology&Management, 33-40.

DOI: 10.5028/jatm.2010.02013340

[10] Qian-gang FU.,&Hui XUE.(2010). Anti-oxidation property of a multi-layer coating for carbon/carbon compositesin a wind tunnel at 1500℃.New Carbon Materials,25,279-284.

DOI: 10.1016/s1872-5805(09)60033-0

[11] Jigang Wang.,&Nan Jiang.(2006).Study on the structural evolution of modified phenol-formaldehyde resin adhesive for the high-temperature bonding of graphite.Journal of nuclear materials,348,108-113.

DOI: 10.1016/j.jnucmat.2005.09.008

[12] Kimberly A.Trick.,&Tony E.Saliba.(1995).Mechanisms of the pyrolysis of phenolic resin in a carbon/phenolic composite.Carbon,Vol.33,No.11,1509-1515.

DOI: 10.1016/0008-6223(95)00092-r

[13] R.Pailler.,&R.Naslain. (2002).Enhancement of the oxidation resistance of interfacial area in C/C composites.Journal of the European Ceramic Society22,1011-1021.

DOI: 10.1016/s0955-2219(01)00411-3

[14] Mohamed O. Abdalla.,&Adriane Ludwick.(2003).Boron-modified phenolic resins for high performance applications.Polymer,44,7353-7359.

DOI: 10.1016/j.polymer.2003.09.019

[15] S.Labruquere.,&H.Blanchard.(2002).Enhancement of the oxidation resistance of interfacial area in C/C composites.Journal of the European Ceramic Society22,1001-1009.