A Spiro [Fluorene-9, 9’-Xanthene]-Based Host Material for Efficient Green and Blue Phosphorescent OLED

Article Preview

Abstract:

A spiro [fluorene-9,9-xanthen-based host material SFX-PF, without possessing conventional hole-or electron-transporting units, has been demonstrated to be host material for efficient and low voltage green phosphorescent organic light-emitting device (PHOLED). This compound showed good thermal stability with high glass transition temperatures (Tg) at 172 °C. The green device exhibited a low turn-on voltage of 3 V, and maximum current efficiency, power efficiency, and external quantum efficiency (EQE) up to 47.9 cd/A, 45.4 lm/W, and 13.2%, respectively. At the luminance level of 1000 cd/m2, the driving voltages are still lower than 4 V with 15.9% roll-off in the EQE. In addition, SFX-PF can also host Fir6 with the blue device exhibiting a low turn-on voltage of 2.8 V and maximum current efficiency, power efficiency, and EQE up to 12.8 cd/A, 11.3 lm/W, and 7.5%, respectively. Based on our present and previous studies, it can be concluded that SFX could serve as a new building block for designing blue and green phosphorescent host materials.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

503-507

Citation:

Online since:

July 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] C.W. Tang, S.A. VanSlyke, Appl. Phys. Lett. Vol. 51 (1987), p.913

Google Scholar

[2] A. Kohler, J.S. Wilson, R.H. Friend, Adv. Mater. Vol. 14 (2002), p.701

Google Scholar

[3] a) H. Sasabe, T. Chiba, S.J. Su, Y.J. Pu, K.I. Nakayama, J. Kido, Chem. Commun. (2008), p.5821; b) Y. Tao, Q. Wang, C. Yang, C. Zhong, K. Zhang, J. Qin, D. Ma, Adv. Funct. Vol. 20 (2010), p.304

Google Scholar

[4] a) C. Adachi, M.A. Baldo, M.E. Thompson, S.R. Forrest, J. Appl. Phys. Vol. 90 (2001), p.5048; b) Y. Z. Li, W.J. Xu, G.Z. Ran, G.G. Qin, Appl. Phys. Lett. Vol. 95 (2009), p.033307. c) J. Kwak, Y.Y. Lyu, H. Lee, B. Choi, K. Char, C. Lee, J. Mater. Chem. Vol. 22 (2012), p.6351

Google Scholar

[5] C.H. Chien, F.M. Hsu, C.F. Shu, Y. Chi, Org. Electron. Vol. 10 (2009), p.871

Google Scholar

[6] L.X. Xiao, S.J Su, Y. Agata, H.L. Lan, J. Kido, Adv. Mater. Vol. 21 (2009), p.1271

Google Scholar

[7] N.J. Lee, D.H. Lee, D.W. Kim, J.H. Lee, S.H. Cho, W. S. Jeon, J.H. Kwon, M. C. Suh, Dyes and Pigments Vol. 95 (2012), p.221

Google Scholar

[8] M.A. Baldo, C. Adachi, S.R. Forrest, Phys. Rev. B Vol. 62 (2000), p.10967.

Google Scholar

[9] K.T. Kamtekar, A.P. Monkman, M.R. Bryce, Adv. Mater. Vol. 22 (2010), p.572

Google Scholar

[10] H.C Ting, Y.M Chen, H.W You, W.Y Hung, S.H Lin, A. Chaskar, S.H. Chou, Y. Chi, R.H. Liu, K.T. Wong, J. Mater. Chem. Vol. 22 (2012), p.8399

Google Scholar

[11] H.H. Chou, C.H. Cheng, Adv. Mater. Vol. 22 (2010), p.2468

Google Scholar

[12] H. Sasabe, N. Toyota, H. Nakanishi, T. Ishizaka, Y.J. Pu, J. Kido, Adv. Mater. Vol. 24 (2012), p.3212

Google Scholar

[13] J.S Chen, C.S Shi, Q. Fu, F.C Zhao, Y. Hu, Y.L Feng, D.G Ma, J. Mater. Chem. Vol. 22 (2012), p.15620

Google Scholar

[14] W.Y Hung, L.C Chi, W.J Chen, E. Mondal, S.H. Chou, K.T. Wong, Y. Chi, J. Mater. Chem. Vol. 21 (2011), p.19249

Google Scholar

[15] Y.J. Cho, J.Y. Lee, Adv. Mater. Vol. 23 (2011), p.4568

Google Scholar

[16] J. Zhao, G.H. Xie, C.R. Yin, L.H. Xie, C.M. Han, R.F. Chen, H. Xu, M.D. Yi, Z.P. Deng, S.F. Chen, Y. Zhao, S.Y. Liu, W. Huang, Chem. Mater. Vol. 23 (2011), p.5331

Google Scholar

[17] Y. Qian, G.H. Xie, S.F. Chen, Z.D. Liu, Y.R. Ni, X.H. Zhou, L.H. Xie, J.L. Liang, Y.Z. Zhao, M.D. Yi, Y. Zhao, W. Wei, W. Huang., Org Electron Vol. 13 (2012), p.2741

Google Scholar