Theory and Verify of Mensurate Cl- Ion by Flow Injection-Cathodic Potentiometric Stripping Analysis

Article Preview

Abstract:

In this paper, the theoretical equation of flow injection-cathodic potentiometric stripping analysis for Cl- ion determination was derived from theoretical analysis, and the experimental equation was summarized using multiple linear regression method. The result shows that the theoretical equation of flow injection-cathodic potentiometric stripping analysis for Cl- ion is: (dt/dE)max =K Ap r-1/2D2/3-1/6Vf1/2teCx-/is; that the experimental equation of multiple linear regression method is: (dt/dE)max Cl-1.86×1010Vf0.568 teC Cl-/is. The two results are similar on Vf-average flow rate, te-concentrate time, C Cl- -Cl- ion concentration and is constant current.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

1192-1195

Citation:

Online since:

August 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Samo B. Hocevar, Joseph Wang, Randhir P. Deo, and Bozidar Ogorevc. Electroanalysis[J], 2002, 14(2): 112 -115.

Google Scholar

[2] Joseph Wang, Abdel-Nasser, Eskil Sahlin, Conception Parrado, and Gustavo Rivas. Electroanalysis [J], 2000, 12(12): 917-920.

Google Scholar

[3] Karel Vytras, Ivan Svancara, Radovan Metelka . Electroanalysis[J], 2002, 14 (19-20): 1359-1364.

Google Scholar

[4] Emma Munoz, Susana Palmero. Electroanalysis[J], 2004, 16 (18): 1528-1535.

Google Scholar

[5] Jia Wenli, Li Tianhua, Zhang Jingjing, et al. Chem.J. Chinese Universities[J], 2006, 27(11): 2056- (2060).

Google Scholar

[6] Li Jiaqing, Li Luoping, Zheng Lei, et al. Chem.J. Chinese Universities[J], 2006, 26(10): 1808-1811.

Google Scholar

[7] Zhang Xingwang, Zhang Zhujun. Chem.J. Chinese Universities[J], 1999, 20(2): 209-213.

Google Scholar

[8] Song Junfeng, Zhao Chuan, Kang Xiaofeng, et, al. Chem.J. Chinese Universities[J], 2000, 21(4): 535-537.

Google Scholar

[9] T.E. Hu. Diss. Abstr[J], Int. B: 42, 1874(1981).

Google Scholar

[10] A. Hu, R.E. Dessy and A. Ganeli. Anal. Chem[J], 55, 320(1983).

Google Scholar

[11] G. Schulze. Mikrochim[J], Acta. I: 191(1984).

Google Scholar

[12] W. Frenzel. Anal. Chim. Acta[J]179, 389(1986).

Google Scholar

[13] Huang H.L. Talanta[J], 34, 539(1987).

Google Scholar

[14] Huang H.L. Anal. Chim. Acta[J], 193, 61(1987).

Google Scholar

[15] Li Zaiyuan, Zhang Shousong. Chinese J. Anal. Chem. [J], 1993, 21(3): 263~266.

Google Scholar

[16] ZhangZuxun, Wang Chunming. Nanking university transaction (natural science)[J], 1984, 1: 81- 90.

Google Scholar

[17] Davicl Mackoul, Dennisc, Johnson. Anal. Chem[J], 1984, 56: 436.

Google Scholar

[18] B.V. Ratna Kumar,S. Satnanarayana,J. Electroanal Chem[J], 1980, 112: 207.

Google Scholar

[19] Jin Liton. 4th Chinese electro analytical chemistry conference [C], EAC, Shanghai, 1990: 314.

Google Scholar

[20] Zhao Huijun, Zhang Shousong. Northeast university transaction[J], 1989, 58: 80.

Google Scholar