Dielectric, Piezoelectric, Pyroelectric Properties and Polymorphic Phase Transition of 0.95 (KXNa1-X) NbO3-0.05LiSbO3 Lead-Free Ferroelectric Ceramics

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Abstract:

0.95 (KXNa1-X) NbO3-0.05 LiSbO3 (KNN-LS-X) (X=0.4-0.5) lead-free ceramics were prepared by conventional solid method. The effect of K/Na ratio on the dielectric, piezoelectric, pyroelectric and polymorphic phase transition was studied. The results show that the electrical properties strongly depend on the K/Na ratio. The KNN-LS-X(X=0.45) ceramics exhibit enhanced properties (εr=891.267, d33=222pC/N, Kp =0.43517, Qm=64.72, p=15×10-4C/m2K). Enhanced electrical properties of the KNN-LS-X (X=0.45) ceramics could be attributed to the effect of K/Na ratio modifying the polymorphic orthorhombic-tetragonal phase transition temperature to room temperature, which could make KNN-LS-X (X=0.45) ceramics use as a new ferroelectric sensor.

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August 2013

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