Preparation and Characterization of Polyaniline Nanotubes Doped with Different Acid

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Abstract:

Polyaniline (PANI) nanotubes were synthesized separately using amino acetic acid (AA), ethylenediamine tetraacetic acid (EDTA), oxalic acid (OA) as dopant and ammonium persulfate (APS) as oxidant by a self-assembly method. SEM, TEM,FTIR and X-ray diffraction (XRD) and applying the 4 probes method characterized the morphology, structure and property of the product. It was found that nanotubes morphology were synthesized when the [Aci/[A ratio is 1:2.The room template conductivity of the products were studied.

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663-666

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September 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] W. P. Fu, R. A. Weiss In situ polymerization of anmiline within lightly sulfonated polystrene, Synth. Metals. 849(1997) 129-130.

DOI: 10.1016/s0379-6779(97)80679-0

Google Scholar

[2] S.W. Ng, K.G. Neoh, J.T. Sampanthar, E.T. Kang, K.L. Tan, J. Phys. Chem. B 105 (2001) 5618-5621.

Google Scholar

[3] X.S. Du, M. Xiao, Y.Z. Meng Synthesis and characterization of polyaniline/graphite conducting nanocomposites, J. Polym. Sci: Part B: Polym. Phys. 42(2004) 1972-(1978).

DOI: 10.1002/polb.20102

Google Scholar

[4] M.X. Wan, J.C. Li, Formation Mechanism of Polyaniline Microtubules Synthesized by a Template-Free Method, J. Polym. Sci: Part A: Polym. Chem. 38 (2000) 2359-2364.

DOI: 10.1002/1099-0518(20000701)38:13<2359::aid-pola80>3.0.co;2-z

Google Scholar

[5] Li, J. Z.; Yun, Z. L.; Zhao, J. C.; Mei, X. W. The Effect of Hydrogen Bonding on Self-Assembled Polyaniline Nanostructures , Adv. Mater. 14(2004) 693-698.

DOI: 10.1002/adfm.200305020

Google Scholar

[6] L. J. Zhang, M. X. Wan. Self-assembly of polyaniline-from nanotubes to hollow microspheres, Adv. Funct. Mater. 13(2003) 815-820.

DOI: 10.1002/adfm.200304458

Google Scholar

[7] Stejskal J, Kratochvil P, Radhakrishnan N. Polyaniline disperisions 2. UV-vis absorption spectra, Synth. Met. 61 (1993) 225-231.

DOI: 10.1016/0379-6779(93)91266-5

Google Scholar

[8] L. J. Zhang, Y. Z. Long, Z. J. Chen, The effect of hydrogen bonding on self-assembled polyaniline nanostructures, Adv. Mater. 14(2004) 693-698.

DOI: 10.1002/adfm.200305020

Google Scholar

[9] J.S. Tang, X. B. Jing, B. C. Wang, Infrared Spectra of Soluble Polyaniline, J. Synth. Met. 24 (1988) 231-238.

Google Scholar

[10] J.C. Xu, W.M. Min, H.L. Li, Titanium dioxide doped polyaniline, J. Mater. Sci. and Engi C 25(2005) 444-447.

Google Scholar

[11] J.P. Pouget, M.E. Jozefowicz, A.J. Epstein, X. Tang, A.G. MacDiarmid, X-ray structure of polyaniline, Macromolecules. 24 (1991) 79-86.

DOI: 10.1021/ma00003a022

Google Scholar

[12] Z.X. Wei, Z.M. Zhang, M.X. Wan, Formation Mechanism of Self-Assembled Polyaniline Micro/Nanotubes, Langmuir. 18 (2002) 917-921.

DOI: 10.1021/la0155799

Google Scholar