Preparation and Methylene Blue Adsorption Characteristics of Highly Mesoporous Rice Husk Active Carbon Prepared by an Alkali-Saving and Equipment-Friendly Method

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Highly mesoporous active carbon for removing methylene blue (MB) from aqueous solution was prepared from pyrolyzed rice husk by combination of CO2 activation and NaOH-solution boiling. The preparation method was found to be alkali-saving and equipment-friendly. The prepared active carbon exhibited high mesoporosity (79.1%), with mesopore volume and specific surface area up to 0.619 mL/g and 899 m2/g, respectively. At initial MB concentrations of 240-380 mg/L, the MB removal efficiency of the prepared active carbon ranged from 92% to more than 99%, fairly comparable to that of the highly mesoporous commercial active carbon used for reference. The adsorption of MB onto the prepared active carbon well followed the pseudo second-order kinetic model and Langmuir isotherm. This study indicated that highly mesoporous active carbon with large dye removal efficiency could be prepared from rice husk by an alkali-saving and equipment-friendly process.

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182-187

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October 2013

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] I.A.W. Tan, A.L. Ahmad and B.H. Hameed: J. Hazard. Mater. Vol. 154 (2008), p.337.

Google Scholar

[2] D. Ghosh and K.G. Bhattacharyya: Appl. Clay Sci. Vol. 20 (2002), p.295.

Google Scholar

[3] I.A.W. Tan, B.H. Hameed and A.L. Ahmad: Chem. Eng. J. Vol. 127 (2007), p.111.

Google Scholar

[4] L.B. Khalil: Adsorpt. Sci. Technol. Vol. 13 (1996), p.317.

Google Scholar

[5] Y.C. Sharma, Uma and S.N. Upadhyay: Can. J. Chem. Eng. Vol. 89 (2011), p.377.

Google Scholar

[6] M.M. El-Halwany: Desalination Vol. 250 (2010), p.208.

Google Scholar

[7] K.Y. Foo and B.H. Hameed: Bioresour. Technol. Vol. 102 (2011), p.9814.

Google Scholar

[8] R.P. Han, Y.F. Wang, W.H. Yu, W.H. Zou, H. Shi and H.M. Liu: J. Hazard. Mater. Vol. 141 (2007), p.713.

Google Scholar

[9] S. Chandrasekhar and P.N. Pramada: Adsorption Vol. 12 (2006), p.27.

Google Scholar

[10] P. Sharma, R. Kaur, C. Baskar and W.J. Chung: Desalination Vol. 259 (2010), p.249.

Google Scholar

[11] A. Bacaoui, A. Yaacoubi, A. Dahbi, C. Bennouna, R.P.T. Luu, F.J. Maldonado-Hodar, J. Rivera-Utrilla and C. Moreno-Castilla: Carbon Vol. 39 (2001), p.425.

DOI: 10.1016/s0008-6223(00)00135-4

Google Scholar

[12] Y.P. Guo, K.F. Yu, Z.C. Wang and H.D. Xu: Carbon Vol. 41 (2003), p.1645.

Google Scholar

[13] Y.P. Guo, S.F. Yang, J.Z. Zhao and M.Y. Zhao: Chem. J. Chinese U. Vol. 21 (2000), p.335.

Google Scholar

[14] P.M. Yeletsky, V.A. Yakovlev, M.S. Mel'gunov and V.N. Parmon: Microporous Mesoporous Mater. Vol. 121 (2009), p.34.

Google Scholar

[15] L. Qiang, Y. Xu-Lai and Z. Xi-Feng: J. Anal. Appl. Pyrolysis Vol. 82 (2008), p.191.

Google Scholar

[16] Y.C. Sharma: J. Chem. Eng. Data Vol. 55 (2010), p.435.

Google Scholar

[17] D.K. Singh and B. Srivastava: Indian J. Chem. Technol. Vol. 8 (2001), p.133.

Google Scholar

[18] Z.H. Hu, M.P. Srinivasan and Y.M. Ni: Carbon Vol. 39 (2001), p.877.

Google Scholar

[19] P. Ariyadejwanich, W. Tanthapanichakoon, K. Nakagawa, S.R. Mukai and H. Tamon: Carbon Vol. 41 (2003), p.157.

DOI: 10.1016/s0008-6223(02)00267-1

Google Scholar

[20] C.T. Hsieh and H.S. Teng: Carbon Vol. 38 (2000), p.863.

Google Scholar

[21] A. Aworn, P. Thiravetyan and W. Nakbanpote: J. Anal. Appl. Pyrolysis Vol. 82 (2008), p.279.

Google Scholar

[22] L.H. Wartelle, W.E. Marshall and M.M. Johns: J. Chromatogr. A Vol. 879 (2000), p.169.

Google Scholar

[23] K. Mohanty, J.T. Naidu and M.N. Biswas: Ind. Eng. Chem. Res. Vol. 45 (2006), p.5165.

Google Scholar

[24] A.A.M. Daifullah, S.M. Yakout and S.A. Elreefy: J. Hazard. Mater. Vol. 147 (2007), p.633.

Google Scholar

[25] D. Ozer, G. Dursun and A. Ozer: J. Hazard. Mater. Vol. 144 (2007), p.171.

Google Scholar

[26] V.S. Mane, I.D. Mall and V.C. Srivastava: J. Environ. Manage. Vol. 84 (2007), p.390.

Google Scholar

[27] V.C. Taty-Costodes, H. Fauduet and A. Delacroix: J. Hazard. Mater. Vol. 105 (2003), p.121.

Google Scholar