Influence of Electrolytes and Humic Acid on Aggregation Behavior of C60 Nanoparticles in Aquatic System

Abstract:

The aggregation kinetics of C60 nanoparticles have been investigated over a wide range of monovalent and divalent electrolyte concentrations by employing time-resolved dynamic light scattering (DLS). The results showed that the presence of electrolyte made a dramatic decrease in the surface zeta potential and increase in the particle size. The aggregation kinetics of C60 nanoparticles exhibited reaction-limited and diffusion-limited regimes, which was found to be consistent with the classic Derjaguin-Landau-Verwey-Overbeek (DLVO) theory of colloidal stability. The critical coagulation concentration (CCC) values of C60 nanoparticles were estimated as 321mM Na⁺, 295mM K⁺, 9.6mM Ca²⁺ and 6.7mM Mg²⁺, which were far higher than the electrolyte concentrations in natural water. The enhanced C60 stability in the presence of humic acid was attributable to steric repulsion. Therefore C60 nanoparticles can be relatively stable in typical aquatic environments.

• Periodical: Applied Mechanics and Materials (Volumes 448-453)
• Pages: 48-51
• DOI: https://doi.org/10.4028/www.scientific.net/AMM.448-453.48
• Online since: October 2013
• Authors: Hua Fang*, Bing Bing Shen, Yu Xin Sun, Yuan Wang, Ji Lai Lu
• Keywords: Aggregation Kinetics, Electrolyte, Fullerene (C60), Humic Acid (HA), Nanoparticle

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